Occurrence of methane hydrate in saturated and unsaturated solutions of sodium chloride and water in dependence of temperature and pressure

AIChE Journal ◽  
1983 ◽  
Vol 29 (4) ◽  
pp. 651-657 ◽  
Author(s):  
J. L. De Roo ◽  
C. J. Peters ◽  
R. N. Lichtenthaler ◽  
G. A. M. Diepen
2019 ◽  
Vol 64 (2) ◽  
pp. 632-639 ◽  
Author(s):  
Tao Lv ◽  
Xiaosen Li ◽  
Zhaoyang Chen ◽  
Chungang Xu ◽  
Yu Zhang ◽  
...  

1995 ◽  
Vol 29 (5) ◽  
pp. 325-329 ◽  
Author(s):  
Tatsuo Maekawa ◽  
Shiro Itoh ◽  
Susumu Sakata ◽  
Shun-ichiro Igari ◽  
Noboru Imai

2006 ◽  
Vol 912 (1) ◽  
pp. 502-514 ◽  
Author(s):  
M. M. MOOIJER-van den HEUVEL ◽  
M. REUVERS ◽  
R. M. De DEUGD ◽  
C. J. PETERS ◽  
J. De SWAAN ARONS

2016 ◽  
Vol 10 (3) ◽  
pp. 337-341
Author(s):  
Oleg Yurchenko ◽  
◽  
Olga Kalinenko ◽  
Olexandr Baklanov ◽  
Larisa Baklanova ◽  
...  

The use of ultrasound (US) in the preparation of pharmaceutical grade (PG) sodium chloride by the sampling of final product from a vacuum evaporator during the process of obtaining the “Extra” class table salt at the crystallization stage of the sodium chloride has been investigated. The US had been used: 1) for the content control of the base matter - sodium chloride in the stock – natural brine (sonoluminescent spectroscopy method). It is necessary to create the appropriate crystallization conditions by the control of the vacuum evaporator parameters - temperature and pressure; 2) at the crystallization stage of the sodium chloride to reduce the co-crystallization between the sodium chloride and the sulfate ions. It has been shown that the use of US allows reducing the sulfate ions content in the final product and getting sodium chloride PG satisfying the requirements of pharmacopoeia standard (PS) 42-2572-88.


2012 ◽  
Vol 85 (4) ◽  
pp. 045707 ◽  
Author(s):  
X W Sun ◽  
Z J Liu ◽  
T Song ◽  
Z R Zhang ◽  
B Kong ◽  
...  

2017 ◽  
Vol 105 ◽  
pp. 5026-5033 ◽  
Author(s):  
Nilesh Choudhary ◽  
Omkar Singh Kushwaha ◽  
Gaurav Bhattacharjee ◽  
Suman Chakrabarty ◽  
Rajnish Kumar

Author(s):  
RAVIL ZHDANOV ◽  
OLEG SUBBOTIN ◽  
LI-JEN CHEN ◽  
VLADIMIR BELOSLUDOV

Theoretical approach was developed for description of clathrate hydrates stability area at low and modestly high temperatures on molecular level. The approach permits to account for interactions between guest molecules and dependence of unit cell structure upon guest's sort, temperature and pressure. Non-ideality of the gas phase was accounted using Van-der-Waals equation of state. Within this approach, methane hydrate calculations have been performed both for low temperature and low pressure region (in equilibrium with ice Ih) and for modestly high temperatures and pressures (in equilibrium with liquid pure water). Calculations show the notable dependence of hydrates thermodynamic properties upon the guest-guest interactions. For methane hydrates, the guest-guest interaction energy can reach 10% of the guest-host value. The results of calculations are in good agreement with available experimental data. This method is applicable for accurate prediction of clathrate hydrate stability in a wide range of P–T conditions.


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