Ion pair formation model for sea salt solutions

AIChE Journal ◽  
1975 ◽  
Vol 21 (3) ◽  
pp. 600-601 ◽  
Author(s):  
Parthasarathi Ray ◽  
Leroy A. Bromley
2015 ◽  
Vol 44 (1) ◽  
pp. 295-305 ◽  
Author(s):  
Wolfram W. Rudolph ◽  
Gert Irmer

Left hand side: Raman spectrum of a 0.622 mol L−1La(ClO4)3(aq). Weak, polarized band at 343 cm−1assigned to symmetric La–O stretch of [La(OH2)9]3+. Bands at 463 and 630 cm−1due to ClO4−(aq). The inset shows the isotropic band in more detail. Right hand side: Structure of [La(OH2)9]3+(symmetryD3).


2015 ◽  
Vol 44 (42) ◽  
pp. 18492-18505 ◽  
Author(s):  
Wolfram W. Rudolph ◽  
Gert Irmer

LHS: Raman spectrum of Y(ClO4)3(aq) at 0.640 mol L−1. The weak, polarized band at 384 cm−1 is assigned to the symmetric Y–O stretch of [Y(OH2)8]3+. Bands at 460 and 628 cm−1 are deformation modes of ClO4−(aq). The inset shows the isotropic band in detail. RHS: Structure of [Y(OH2)8]3+).


1969 ◽  
Vol 24 (4) ◽  
pp. 573-577 ◽  
Author(s):  
P. Nehmiz ◽  
M. Stockhausen

Abstract The mean esr linewidth of hfs components of aqueous mangenese salt solutions has been measured a t 9 GHz and room temperature from small to medium concentrations, also with added diamagnetic salts. In all cases the linewidth depends on the viscosity of the solutions. Further, already at very small concentrations a specific anion dependend line broadening has been observed, evidently resulting from ion pair formation. Roughly spoken, in the whole concentration range two anion families exist. Nitrate and halides show smaller line broadening, they form ion pairs with long lifetime. Sulfate, acetate and formiate show larger line broadening; they form ion pairs with short lifetime.


1985 ◽  
Vol 178 ◽  
pp. 189-195 ◽  
Author(s):  
M. Puttemans ◽  
L. Dryon ◽  
D.L. Massart

1988 ◽  
Vol 92 (7) ◽  
pp. 1703-1705 ◽  
Author(s):  
R. J. Locke ◽  
Steve H. Modiano ◽  
E. C. Lim

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