Diffusion kinetics of CO 2 in amine‐impregnated MIL‐101, alumina, and silica adsorbents

AIChE Journal ◽  
2019 ◽  
Vol 66 (1) ◽  
Author(s):  
Teresa Gelles ◽  
Fateme Rezaei
Keyword(s):  
Diffusion Kinetics ◽  
Silica Adsorbents ◽  
Kinetics Of

Kinetics of Methane-Oxidizing Biofilms for Degradation of Toxic Organics

1988 ◽  
Vol 20 (11-12) ◽  
pp. 167-173 ◽  
Author(s):  
S. E. Strand ◽  
R. M. Seamons ◽  
M. D. Bjelland ◽  
H. D. Stensel
Keyword(s):  
Chlorinated Hydrocarbons ◽  
Enzymatic Oxidation ◽  
Diffusion Kinetics ◽  
Toxic Compound ◽  
Biofilm Model ◽  
Uptake Rates ◽  
Substrate Diffusion ◽  
Toxic Organics ◽  
Competitive Substrate ◽  
Kinetics Of

The kinetics of methane-oxidizing bioreactors for the degradation of toxic organics are modeled. Calculations of the fluxes of methane and toxic chlorinated hydrocarbons were made using a biofilm model. The model simulated the effects of competition by toxics and mediane on their enzymatic oxidation by the methane monooxygenase. Dual-competitive-substrate/diffusion kinetics were used to model biofilm co-metabolism, integrating equations of the following form:where S1 and S2 are the local concentrations of methane and toxic compound, respectively, and r and K are the maximum uptake rates and Monod coefficients, and x is the distance into the biofilm.

Elastic Properties of Steps at Interphase Boundaries

1991 ◽  
Vol 238 ◽  
Author(s):  
G. J. Shiflet
Keyword(s):  
Energy Density ◽  
Elastic Properties ◽  
Mathematical Analysis ◽  
Strain Energy ◽  
Chemical Processes ◽  
Diffusion Kinetics ◽  
Interphase Boundaries ◽  
Kinetics Of ◽  
Maximum Stresses

ABSTRACTStresses are introduced in crystals at interphase boundaries where steps improve the registry of atoms. A model and mathematical analysis based on an approach previously taken by van der Merwe and Shiflet1–4 of the problem incorporating a coherent step are presented. Computed distributions of stresses, strains, dilatation and energy density in the form of contours and nets are given for a coherent monatomic step. It is concluded that the maximum stresses are quite large and the fields decay fairly rapidly with distance from the steps, the gradient of dilatation around steps will significantly affect diffusion kinetics of impurities and the strain energy seems too low to significantly enhance chemical processes.

Diffusion kinetics of li loss from the surface of an Al-Li base alloy at 573 to 873 K

1986 ◽  
Vol 14 (4) ◽  
pp. 393-396
Author(s):  
W.J. Tomlinson ◽  
S.J. Kenney ◽  
N. Richards
Keyword(s):  
Base Alloy ◽  
Diffusion Kinetics ◽  
Kinetics Of

Revisiting graphene–polymer nanocomposite for enhancing anticorrosion performance: a new insight into interface chemistry and diffusion model

Nanoscale ◽  
2018 ◽  
Vol 10 (26) ◽  
pp. 12612-12624 ◽  
Author(s):  
Dipak Dutta ◽  
Andita Nataria Fitri Ganda ◽  
Jui-Kung Chih ◽  
Cheng-Chun Huang ◽  
Chung-Jen Tseng ◽  
...  
Keyword(s):  
Galvanic Corrosion ◽  
Polymer Nanocomposite ◽  
Diffusion Kinetics ◽  
Interfacial Chemistry ◽  
Interface Chemistry ◽  
Graphene Nanocomposite ◽  
Kinetics Of ◽  
And Diffusion ◽  
Insight Into ◽  
Percolation Network

The interfacial chemistry and diffusion kinetics of a polymer–graphene nanocomposite anticorrosion coating were studied to minimize galvanic corrosion facilitated by the formation of an interconnected graphene percolation network.

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