Oxygen transport kinetics of MIEC membranes coated with different catalysts

AIChE Journal ◽  
2016 ◽  
Vol 62 (8) ◽  
pp. 2803-2812 ◽  
Author(s):  
Yan Liu ◽  
Yue Zhu ◽  
Mingrun Li ◽  
Xuefeng Zhu ◽  
Weishen Yang
Keyword(s):  
Oxygen Transport ◽  
Transport Kinetics ◽  
Kinetics Of

A permeation model study of oxygen transport kinetics of Ba x Sr 1‐x Co 0 . 8 Fe 0 . 2 O 3 ‐δ

AIChE Journal ◽  
2020 ◽  
Vol 66 (9) ◽  
Author(s):  
Yue Zhu ◽  
Lili Cai ◽  
Wenping Li ◽  
Zhongwei Cao ◽  
Hongbo Li ◽  
...  
Keyword(s):  
Oxygen Transport ◽  
Transport Kinetics ◽  
Model Study ◽  
Kinetics Of

Oxygen transport kinetics of the misfit layered oxide Ca3Co4O9+δ

2014 ◽  
Vol 2 (46) ◽  
pp. 19717-19725 ◽  
Author(s):  
V. Thoréton ◽  
Y. Hu ◽  
C. Pirovano ◽  
E. Capoen ◽  
N. Nuns ◽  
...  
Keyword(s):  
Oxygen Transport ◽  
Oxygen Exchange ◽  
Solid Oxide ◽  
Transport Kinetics ◽  
Air Electrode ◽  
Layered Oxide ◽  
Exchange Kinetics ◽  
Kinetics Of

Ca3Co4O9+δ exhibits fast oxygen exchange kinetics rendering it a promising electrode for application as an air electrode in solid oxide cells.

Influence of annealing at intermediate temperature on oxygen transport kinetics of Pr2NiO4+δ

2018 ◽  
Vol 6 (18) ◽  
pp. 8331-8339 ◽  
Author(s):  
Saim Saher ◽  
Jia Song ◽  
Vaibhav Vibhu ◽  
Clément Nicollet ◽  
Aurélien Flura ◽  
...  
Keyword(s):  
Oxygen Transport ◽  
Higher Order ◽  
Transport Kinetics ◽  
Intermediate Temperature ◽  
Kinetics Of

Decomposition of the layered Ruddlesden–Popper (RP) phase Pr2NiO4+δ into higher order phases during long-term annealing dramatically enhances oxygen transport.

Kinetics of the multidrug transporter (P-glycoprotein) and its reversal

1997 ◽  
Vol 77 (2) ◽  
pp. 545-590 ◽  
Author(s):  
W. D. Stein
Keyword(s):  
Final Section ◽  
Transport Kinetics ◽  
Multidrug Transporter ◽  
Chemotherapeutic Drugs ◽  
Multidrug Resistance Proteins ◽  
Binding Properties ◽  
Membrane Pump ◽  
Resistance Proteins ◽  
P Glycoprotein ◽  
Kinetics Of

Most cancer deaths result from the cancer's either being intrinsically resistant to chemotherapeutic drugs or becoming resistant after being initially sensitive. Often, in cells grown in cell culture, drug resistance correlates with the presence of one or more of the so-called P-glycoproteins or multidrug resistance proteins, products of the mdr family of genes. This review is largely concerned with the transport kinetics of the P-glycoproteins. We first present a brief overview of the P-glycoproteins, their properties, and their clinical significance. Later sections of the review expand on this material with special emphasis on the substrates of P-glycoprotein and how they cross the cell membrane, on the transport kinetics of the P-glycoprotein, on reversers of its action, and on its activity as an ATPase. In a final section, we consider the mechanism of action of P-glycoprotein as an actively transporting membrane pump. The characteristic of P-glycoprotein considered the most difficult to explain is its very broad specificity (or lack of specificity), but there are precedents for this property in well-known proteins such as serum albumin, which binds a range of molecular types, including substrates and reversers of P-glycoprotein, seemingly as broad as does P-glycoprotein. Pointing out this analogy does not provide a molecular explanation for the substrate-binding properties of P-glycoprotein but does make those properties more assimilable.

scholarly journals Unexpected Role of Electronic Coupling between Host Redox Centers in Transport Kinetics of Lithium Ions in Olivine Phosphate Materials

2021 ◽  
Author(s):  
Yu Gao ◽  
Jun Huang ◽  
Yuwen Liu ◽  
Shengli Chen
Keyword(s):  
Activation Energy ◽  
Diffusion Coefficient ◽  
Lithium Ion ◽  
Transport Kinetics ◽  
Electronic Coupling ◽  
Lithium Ions ◽  
Kinetics Of ◽  
Olivine Phosphate ◽  
Redox Centers

The discrepancy between the trend in the diffusion coefficient of lithium ion (DLi+) and that in the activation energy of ion hopping signals hidden factors determining ion transport kinetics in...

scholarly journals Carbon Nanotube Electrodes for Electrochemical Detection of Dopamine

2021 ◽  
Author(s):  
Gaurang Khot ◽  
Frank Platte ◽  
Neil Shirtcliffe ◽  
Tansu Celikel
Keyword(s):  
Electron Transport ◽  
Pyrolytic Carbon ◽  
Transport Kinetics ◽  
Electrochemical Kinetics ◽  
Current Voltage ◽  
Surface Diameter ◽  
Kinetics Of ◽  
The Brain ◽  
Anodic Region ◽  
Basal Concentration

AbstractCarbon nanotubes (CNTs) are suited for neurochemistry because of their biological inertness, ability to withstand biofouling, and superior electron transport kinetics. Dopamine, the canonical monoaminergic neuromodulator, contributes to reward, cognition and attention, however, its detection in real-time is challenging due to its low basal concentration in the brain (100nM L-1). In our present work, we fabricate pyrolytic carbon electrodes and perform a CNT coating to improve the electrochemical kinetics of dopamine. Upon CNTs coating, dopamine shows a sensitivity of 9±18nA/μM for a cylindrical electrode having a mean surface diameter of 8±4μm. Increasing the scan frequency from 10-100 Hz shows that dopamine electron transfer kinetics improves; wherein dopamine is oxidized at 0.35±0.09V and reduced to -0.10±0.05V for 10 Hz. Increasing the frequency results in a shift of oxidation peak towards the anodic region, wherein dopamine oxidizes at 0.08±3V and reduces at -0.1±0.05V for 100 Hz, thus showing that dopamine redox is reversible which can be attributed to the superior electron transport kinetics of CNTs. The sensor was able to distinguish dopamine signals against other neurochemicals like serotonin and foulant 3,4-Dihydroxyphenylacetic acid (DOPAC). The minimum chemical detection that can be performed using these nanopipettes is 50±18nM L-1, which is well below the physiological concentrations of dopamine in the brain.Graphical AbstractA: Pictorial view of background-subtracted voltammetry. The waveform used was -0.4V to 1.3 V and cycled back to -0.4V at 10 Hz. B: The voltammogram was converted as a 2-D representation, into current, voltage, and repetition to understand the dopamine oxidation. C: Background subtracted voltammetry for dopamine using 100 Hz waveform. D: The 2-D representation of current, voltage, and repetition.

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