Dynamic CO2 adsorption performance of internally cooled silica-supported poly(ethylenimine) hollow fiber sorbents

AIChE Journal ◽  
2014 ◽  
Vol 60 (11) ◽  
pp. 3878-3887 ◽  
Author(s):  
Yanfang Fan ◽  
Ying Labreche ◽  
Ryan P. Lively ◽  
Christopher W. Jones ◽  
William J. Koros
Polymer ◽  
2014 ◽  
Vol 55 (6) ◽  
pp. 1341-1346 ◽  
Author(s):  
Fuyue Stephanie Li ◽  
Ying Labreche ◽  
Ryan P. Lively ◽  
Jong Suk Lee ◽  
Christopher W. Jones ◽  
...  

Author(s):  
Diogo P. S. Silva ◽  
Alef T. Santos ◽  
Thaís R. S. Ribeiro ◽  
Julyane R. S. Solano ◽  
Roberta K. B. C. Cavalcanti ◽  
...  

Processes ◽  
2019 ◽  
Vol 7 (11) ◽  
pp. 801
Author(s):  
Liu ◽  
Li ◽  
Dong ◽  
Li ◽  
Feng ◽  
...  

Focusing on the bottlenecks of traditional physical activation method for the preparation of activated carbons (ACs), we established a simple and scalable method to control the physicochemical structure of ACs and study their CO2 adsorption performance. The preparation is achieved by ammonia activation at different volume fractions of ammonia in the mixture (10%, 25%, 50%, 75%, and 100%) to introduce the nitrogen-containing functional groups and form the original pores and subsequent chemical vapor deposition (CVD) at different deposition times (30, 60, 90, and 120 min) to further adjust the pore structure. The nitrogen content of ACs-0.1/0.25/0.5/0.75/1 increases gradually from 2.11% to 8.84% with the increase of ammonia ratio in the mixture from 10% to 75% and then decreases to 3.02% in the process of pure ammonia activation (100%), during which the relative content of pyridinium nitrogen (N-6), pyrrolidine (N-5), and graphite nitrogen (N-Q) increase sequentially but nitrogen oxygen structure (N-O) increase continuously. In addition, ACs-0.5 and ACs-0.75, with a relatively high nitrogen content (6.37% and 8.84%) and SBET value (1048.65 m2/g and 814.36 m2/g), are selected as typical samples for subsequent CVD. In the stage of CVD, ACs-0.5-60 and ACs-0.75-90, with high SBET (1897.25 and 1971.57 m2/g) value and an appropriate pore-size distribution between 0.5 and 0.8 nm, can be obtained with the extension of deposition time from 60 to 90 min. The results of CO2 adsorption test indicate that an adsorption capacity of ACs-0.75-90, at 800 mmHg, is the largest (6.87 mmol/g) out of all the tested samples. In addition, the comparison of CO2 adsorption performance of tested samples with different nitrogen content and pore structure indicates that the effect of nitrogen content seems to be more pronounced in this work.


Membranes ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 63
Author(s):  
Mohd Ridhwan Adam ◽  
Mohd Hafiz Dzarfan Othman ◽  
Siti Hamimah Sheikh Abdul Kadir ◽  
Mohd Nazri Mohd Sokri ◽  
Zhong Sheng Tai ◽  
...  

Natural zeolite is widely used in removing ammonia via adsorption process because of its superior ion-exchange properties. Ceramic particle size affects the adsorptivity of particles toward ammonia. In this study, hollow fiber ceramic membrane (HFCM) was fabricated from natural zeolite via phase inversion. The effect of natural zeolite particle size toward the properties and performance of HFCM was evaluated. The results show that the HFCM with smaller particle sizes exhibited a more compact morphological structure with better mechanical strength. The adsorption performance of HFCM was significantly improved with smaller particle sizes because of longer residence time, as proven by the lower water permeability. A high adsorption performance of 96.67% was achieved for HFCM with the smallest particle size (36 μm). These findings provide a new perspective on the promising properties of the natural zeolite-derived HFCM for ammonia removal.


2016 ◽  
Vol 4 (14) ◽  
pp. 5223-5234 ◽  
Author(s):  
Kaimin Li ◽  
Sicong Tian ◽  
Jianguo Jiang ◽  
Jiaming Wang ◽  
Xuejing Chen ◽  
...  

After carbonization and activation, pine cone shell-based activated carbons were used to adsorb CO2, and presenting a good adsorption performance.


2017 ◽  
Vol 57 ◽  
pp. 418-428 ◽  
Author(s):  
Gutiérrez-Bonilla Elvira ◽  
Granados-Correa Francisco ◽  
Sánchez-Mendieta Víctor ◽  
Morales-Luckie Raúl Alberto

2015 ◽  
Vol 24 (3) ◽  
pp. 322-330 ◽  
Author(s):  
Zhilin Liu ◽  
Yang Teng ◽  
Kai Zhang ◽  
Honggang Chen ◽  
Yongping Yang

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