Functionalized assembly of solid membranes for chiral separation using polyelectrolytes and chiral ionic liquid

AIChE Journal ◽  
2013 ◽  
Vol 59 (12) ◽  
pp. 4772-4779 ◽  
Author(s):  
Hong Meng ◽  
Sumin Li ◽  
Ling Xiao ◽  
Chunxi Li
Keyword(s):  
Ionic Liquid ◽  
Chiral Separation ◽  
Chiral Ionic Liquid

Chiral separation of phenylalanine and tryptophan by capillary electrophoresis using a mixture ofβ-CD and chiral ionic liquid ([TBA] [l-ASP]) as selectors

2013 ◽  
Vol 28 (5) ◽  
pp. 610-614 ◽  
Author(s):  
Wu Yujiao ◽  
Wang Guoyan ◽  
Zhao Wenyan ◽  
Zhang Hongfen ◽  
Jing Huanwang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Capillary Electrophoresis ◽  
Chiral Separation ◽  
Chiral Ionic Liquid

L-Histidinium Chiral Ionic Liquid Functionalized β-Cyclodextrin as Chiral Selector in Capillary Electrophoresis

2021 ◽  
Author(s):  
Xiaofei Ma ◽  
Jingtang Li ◽  
Xiaoqi Li ◽  
Zijie Feng ◽  
Xuan Yang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Capillary Electrophoresis ◽  
Ionic Liquids ◽  
Molecular Modeling ◽  
Chiral Separation ◽  
Chiral Selector ◽  
Chiral Discrimination ◽  
Chiral Ionic Liquid ◽  
First Time ◽  
Good Agreement

Abstract Nowadays, ionic liquids (ILs) functionalized cyclodextrins (CDs) have drawn increasing attention in chiral separation. Herein, a novel β-CD derivative functionalized by L-histidinium IL, mono-6-deoxy-6-L-histidinium-β-cyclodextrin chloride (L-HMCDCl), was synthesized for the first time and utilized for enantioseparation of nefopam and chlorphenamine in capillary electrophoresis. The L-HMCDCl exhibited superior enantioselectivity compared with native β-CD. The effect of some key parameters such as chiral selector concentration, buffer pH and applied voltage on the enantioseparation was investigated in detail. In the interest of the chiral discrimination mechanism and the enhanced enantioselectivity of L-HMCDCl, molecular modeling with AutoDock was employed to study the interaction, which was in good agreement with experimental results.

Synthesis, Characterization and Thermal Properties of a Novel Chiral Ionic Liquid with Chiral Center in Anion

2011 ◽  
Vol 233-235 ◽  
pp. 184-187
Author(s):  
Jin Yang Yu ◽  
Xiao Ling Hu ◽  
Yi Mei Tang ◽  
Liang Liang
Keyword(s):  
Ionic Liquid ◽  
Thermal Properties ◽  
Asymmetric Synthesis ◽  
Chiral Separation ◽  
Chiral Center ◽  
Chiral Catalyst ◽  
One Step ◽  
Ft Ir ◽  
Chiral Ionic Liquid ◽  
First Time

An imidazolium-based chiral ionic liquid with chiral center in anion was synthesized in one step from the materials of alkylation of N-methylimidzole and (S)-(-)-2-chloro-propionic acid for the first time. The structures and thermal properties of the objective product were confirmed by FT-IR,1HNMR and DSC, respectively. The results indicate that it may be used as a new chiral solvent for asymmetric synthesis, chiral catalyst and chiral separation.

ChemInform Abstract: Chiral Ionic Liquid Mediated Diels-Alder Reaction Between Anthrone Enolate and Maleimides.

ChemInform ◽  
2010 ◽  
Vol 41 (40) ◽  
pp. no-no
Author(s):  
Nitin A. Mirgane ◽  
Mohammed Hasan H. Akhtar ◽  
Anil V. Karnik
Keyword(s):  
Ionic Liquid ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Chiral Ionic Liquid

Synthesis and Characterization of N-butyl-N-methylimidazolium- D-(-)-tartrate Chiral Ionic Liquid

2012 ◽  
Vol 518-523 ◽  
pp. 3989-3992 ◽  
Author(s):  
Yang Zhang ◽  
Xiao Hua Tu ◽  
Cheng Ping Miao ◽  
Jian Yi Wu
Keyword(s):  
Ionic Liquid ◽  
1H Nmr ◽  
Ion Chromatography ◽  
13C Nmr ◽  
Nmr Spectra ◽  
Optical Rotation ◽  
Synthesis And Characterization ◽  
13C Nmr Spectra ◽  
Chiral Ionic Liquid

A novel CIL of N-butyl-N-methyl imidazolium-D-(-)-tartrate has been designed and synthesized by neutralization reaction. Its structure was characterized by 1H-NMR and 13C-NMR spectra, the optical rotation was characterized by polarimeter with the value of-15.0º, and the purity was characterized by ion chromatography with the value of 98.4%.

scholarly journals Chiral ionic liquid crystals based on thiourea

2019 ◽  
Vol 43 (5) ◽  
pp. 2053-2056 ◽  
Author(s):  
Sarah Kirchhecker ◽  
Duncan W. Bruce
Keyword(s):  
Ionic Liquid ◽  
Liquid Crystals ◽  
Ionic Liquid Crystals ◽  
Chiral Ionic Liquid

Chiral ionic liquid crystals based on the S-methyl-N,N′-α-methylarylthiouronium cation have been prepared and studied.

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