Plantwide control of an isopropyl alcohol dehydration process

AIChE Journal ◽  
2006 ◽  
Vol 52 (6) ◽  
pp. 2290-2296 ◽  
Author(s):  
William L. Luyben
Keyword(s):  
Isopropyl Alcohol ◽  
Dehydration Process ◽  
Alcohol Dehydration ◽  
Plantwide Control

WC-based catalyst for isopropyl alcohol dehydration as prepared by combustion synthesis

2011 ◽  
Vol 20 (1) ◽  
pp. 1-5 ◽  
Author(s):  
Kh. V. Manukyan ◽  
A. R. Zurnachyan ◽  
S. L. Kharatyan ◽  
R. A. Mnatsakanyan
Keyword(s):  
Combustion Synthesis ◽  
Isopropyl Alcohol ◽  
Alcohol Dehydration

scholarly journals ASPECTOS ENERGÉTICOS E ELETRÔNICOS DA ZEÓLITA H-ZSM-5 NA AÇÃO CATALÍTICA DA REAÇÃO DE DESIDRATAÇÃO DE ÁLCOOIS

2020 ◽  
Author(s):  
Gustavo Gomes de Sousa ◽  
José Roberto dos Santos Politi
Keyword(s):  
Reaction Mechanism ◽  
Fossil Fuels ◽  
Acid Catalysis ◽  
High Efficiency ◽  
Dehydration Process ◽  
Dehydration Reaction ◽  
Alcohol Dehydration ◽  
Catalytic Behavior ◽  
Zeolite Cavity ◽  
Computational Methodology

Due to the growth of ecological concerns and the need to reduce dependence on fossil fuels, the dehydration of alcohols by acid catalysis has been used for the production of various hydrocarbons. Inside this theme, the H-ZSM-5 zeolite has been widely used as a catalyst for this reaction because its high efficiency. Thus, in order to understand the catalyzed reaction mechanism of the alcohol dehydration reaction, this work used the computational methodology ONIOM to study the catalytic behavior of the H-ZSM-5. It was modeled the dehydration reaction process for several alcohols (ethanol, propanol, isopropanol, butanol and 2-butanol) by modeling these alcohols within the zeolite cavity. The study was divided into 3 stages: the adsorption and protonation of alcohols by zeolite, the description of the hydroxyl outlet, and the formation of the double bond. The analysis of the results indicates that the first stage of the reaction occurs with the contact of alcohol with the zeolite cavity, where acid hydrogen promotes the protonation of alcohols, occurring differently for each alcohol. The dehydration process occurs, preferably, via E2 type elimination mechanisms. However, the profile of the energy curves indicates that for larger alcohols, the mechanism is intermediate between the elimination mechanisms E2 with some features of E1 (E2[E1]). Therefore, the zeolite converts alcohols to hydrocarbons in a specific way. Primary, lower-chain alcohols follow E2 mechanism, while secondary and longer-chain alcohols react by a slightly different mechanism, namely E2[E1].

Isopropyl Alcohol Dehydration by Hot Gas Pressure Swing Adsorption: Experiments, Simulations, and Implementation

2014 ◽  
Vol 53 (20) ◽  
pp. 8599-8607 ◽  
Author(s):  
Yujun Liu ◽  
Shawn D. Feist ◽  
Christopher M. Jones ◽  
Daniel R. Armstrong
Keyword(s):  
Pressure Swing Adsorption ◽  
Isopropyl Alcohol ◽  
Gas Pressure ◽  
Alcohol Dehydration ◽  
Hot Gas ◽  
Pressure Swing
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