Rational Design of Dopant‐Free Coplanar D‐π‐D Hole‐Transporting Materials for High‐Performance Perovskite Solar Cells with Fill Factor Exceeding 80%

2019 ◽  
Vol 9 (39) ◽  
pp. 1901268 ◽  
Author(s):  
Yatong Chen ◽  
Xiuwen Xu ◽  
Ning Cai ◽  
Sainan Qian ◽  
Ruixi Luo ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Rational Design ◽  
Fill Factor ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Hole Transporting Materials

Efficient, dopant free phenazine based hole transporting materials for high performance perovskite solar cells

Solar Energy ◽  
2021 ◽  
Vol 226 ◽  
pp. 501-512
Author(s):  
Gurulakshmi Maddala ◽  
Ramesh Gade ◽  
Jakeer Ahemed ◽  
Susmitha Kalvapalli ◽  
Narendra Babu Simhachalam ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Hole Transporting Materials

Fluorene-based enamines as low-cost and dopant-free hole transporting materials for high performance and stable perovskite solar cells

2021 ◽  
Vol 9 (1) ◽  
pp. 301-309
Author(s):  
Sarune Daskeviciute ◽  
Cristina Momblona ◽  
Kasparas Rakstys ◽  
Albertus Adrian Sutanto ◽  
Maryte Daskeviciene ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
One Pot ◽  
Free Hole ◽  
Hole Transporting ◽  
Exceptional Stability ◽  
Hole Transporting Materials

One-pot synthesized low-cost HTM V1275 exhibits a remarkable performance of 19.3% in PSCs with exceptional stability retaining 125% of the original PCE after 500 h.

Lewis-base containing spiro type hole transporting materials for high-performance perovskite solar cells with efficiency approaching 20%

Nanoscale ◽  
2020 ◽  
Vol 12 (24) ◽  
pp. 13157-13164 ◽  
Author(s):  
Jianbin Xu ◽  
Lusheng Liang ◽  
Chi-Lun Mai ◽  
Zilong Zhang ◽  
Qin Zhou ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Molecular Design ◽  
Perovskite Solar Cells ◽  
Lewis Base ◽  
Alternative Strategy ◽  
Hole Transporting ◽  
Hole Transporting Materials ◽  
Base Group

Lewis base group containing spiro-type hole conductors (spiro-CN-OMeTAD and spiro-PS-OMeTAD) have been synthesized to be HTMs. This study provides an alternative strategy for the molecular design of better HTMs in high-performance Perovskite solar cells.

scholarly journals Novel Anthracene HTM Containing TIPs for Perovskite Solar Cells

Processes ◽  
2021 ◽  
Vol 9 (12) ◽  
pp. 2249
Author(s):  
Sanghyun Paek
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Long Term Stability ◽  
Photovoltaic Conversion Efficiency ◽  
Hole Transporting ◽  
Hole Transporting Material ◽  
Hole Transporting Materials

Recently, perovskite solar cells have been in the spotlight due to several of their advantages. Among the components of PSCs, hole transporting materials (HTMs) re the most important factors for achieving high performance and a stable device. Here, we introduce a new D–π–D type hole transporting material incorporating Tips-anthracene as a π–conjugation part and dimethoxy-triphenylamine as a donor part (which can be easily synthesized using commercially available materials). Through the measurement of various optical properties, the new HTM not only has an appropriate energy level but also has excellent hole transport capability. The device with PEH-16 has a photovoltaic conversion efficiency of 17.1% under standard one sun illumination with negligible hysteresis, which can be compared to a device using Spiro_OMeTAD under the same conditions. Ambient stability for 1200 h shown that 98% of PEH-16 device from the initial PCE was retained, indicating that the devices had good long-term stability.

scholarly journals Effect of multi-armed triphenylamine-based hole transporting materials for high performance perovskite solar cells

2016 ◽  
Vol 7 (8) ◽  
pp. 5517-5522 ◽  
Author(s):  
Sungmin Park ◽  
Jin Hyuck Heo ◽  
Jae Hoon Yun ◽  
Tae Sub Jung ◽  
Kyungwon Kwak ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Hole Transporting Materials

The performance of planar perovskite solar cells was enhanced by using hole transporting materials containing triphenylamine groups with a multi-armed structure.

Two Anthracene-Based Copolymers as the Hole-Transporting Materials for High-Performance Inverted (p-i-n) Perovskite Solar Cells

2018 ◽  
Vol 51 (18) ◽  
pp. 7407-7416 ◽  
Author(s):  
Tong Tong ◽  
Chao Tan ◽  
Tina Keller ◽  
Bobo Li ◽  
Chaoyue Zheng ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Hole Transporting Materials

scholarly journals Development of simple hole-transporting materials for perovskite solar cells

2016 ◽  
Vol 94 (4) ◽  
pp. 352-359 ◽  
Author(s):  
Andrew M. Namespetra ◽  
Arthur D. Hendsbee ◽  
Gregory C. Welch ◽  
Ian G. Hill
Keyword(s):  
Solar Cells ◽  
High Performance ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Insulating Polymers ◽  
Hole Transporting Material ◽  
Surface Morphologies ◽  
Highest Occupied Molecular Orbitals ◽  
Hole Transporting Materials

Three low-cost propeller-shaped small molecules based on a triphenylamine core and the high-performance donor molecule 7,7′-[4,4-bis(2-ethylhexyl)-4H-silolo[3,2-b:4,5-b′]dithiophene-2,6-diyl]bis[6-fluoro-4-(5′-hexyl-[2,2′-bithiophen]-5-yl)benzo[c][1,2,5]thiadiazole] (DTS(FBTTh2)2) were investigated as hole-transporting materials in perovskite solar cells. Each hole-transporting material was designed with highly modular side arms, allowing for different bandgaps and thin-film properties while maintaining a consistent binding energy of the highest occupied molecular orbitals to facilitate hole extraction from the perovskite active layer. Perovskite solar cell devices were fabricated with each of the three triphenylamine-based hole-transporting materials and DTS(FBTTh2)2 and were compared to devices with 2,2′,7,7′-tetrakis(N,N-di-p-methoxyphenylamine)-9,9′-spirobifluorene (spiro-OMeTAD) hole-transporting layers. Each of our triphenylamine hole-transporting materials and DTS(FBTTh2)2 displayed surface morphologies that were considerably rougher than that of spiro-OMeTAD; a factor that may contribute to lower device performance. It was found that using inert, insulating polymers as additives with DTS(FBTTh2)2 reduced the surface roughness, resulting in devices with higher photocurrents.

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