Self-Assembled Binary Organic Granules with Multiple Lithium Uptake Mechanisms toward High-Energy Flexible Lithium-Ion Hybrid Supercapacitors

2018 ◽  
Vol 8 (30) ◽  
pp. 1802273 ◽  
Author(s):  
Zhongli Hu ◽  
Shah Sayed ◽  
Tao Jiang ◽  
Xingyu Zhu ◽  
Chen Lu ◽  
...  
2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Shengyang Dong ◽  
Yi Wang ◽  
Chenglong Chen ◽  
Laifa Shen ◽  
Xiaogang Zhang

AbstractAqueous hybrid supercapacitors are attracting increasing attention due to their potential low cost, high safety and eco-friendliness. However, the narrow operating potential window of aqueous electrolyte and the lack of suitable negative electrode materials seriously hinder its future applications. Here, we explore high concentrated lithium acetate with high ionic conductivity of 65.5 mS cm−1 as a green “water-in-salt” electrolyte, providing wide voltage window up to 2.8 V. It facilitates the reversible function of niobium tungsten oxide, Nb18W16O93, that otherwise only operations in organic electrolytes previously. The Nb18W16O93 with lithium-ion intercalation pseudocapacitive behavior exhibits excellent rate performance, high areal capacity, and ultra-long cycling stability. An aqueous lithium-ion hybrid capacitor is developed by using Nb18W16O93 as negative electrode combined with graphene as positive electrode in lithium acetate-based “water-in-salt” electrolyte, delivering a high energy density of 41.9 W kg−1, high power density of 20,000 W kg−1 and unexceptionable stability of 50,000 cycles.


Nanoscale ◽  
2016 ◽  
Vol 8 (37) ◽  
pp. 16761-16768 ◽  
Author(s):  
Juan Xu ◽  
Yuanyuan Li ◽  
Lei Wang ◽  
Qifa Cai ◽  
Qingwei Li ◽  
...  

RSC Advances ◽  
2020 ◽  
Vol 10 (17) ◽  
pp. 9833-9839
Author(s):  
Changzhen Zhan ◽  
Jianan Song ◽  
Xiaolong Ren ◽  
Yang Shen ◽  
Hui Wu ◽  
...  

Constructing flexible hybrid supercapacitors is a feasible way to achieve devices with high energy density, high power density and flexibility at the same time.


2017 ◽  
Vol 23 (17) ◽  
pp. 4203-4209 ◽  
Author(s):  
Huiling Yang ◽  
Henghui Xu ◽  
Libin Wang ◽  
Lei Zhang ◽  
Yunhui Huang ◽  
...  

2019 ◽  
Vol 7 (2) ◽  
pp. 693-703 ◽  
Author(s):  
Shengyuan Li ◽  
Ting Wang ◽  
Wangqin Zhu ◽  
Jiabiao Lian ◽  
Yunpeng Huang ◽  
...  

Uniform mesoporous H-Nb2O5/rGO nanocomposites are developed for advanced lithium ion hybrid supercapacitors with remarkably high energy/power densities and excellent cycling stability.


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