Fast Diffusion of Multivalent Ions Facilitated by Concerted Interactions in Dual-Ion Battery Systems

2018 ◽  
Vol 8 (27) ◽  
pp. 1801475 ◽  
Author(s):  
Hongyi Li ◽  
Norihiko L. Okamoto ◽  
Takuya Hatakeyama ◽  
Yu Kumagai ◽  
Fumiyasu Oba ◽  
...  
2021 ◽  
Vol 118 (38) ◽  
pp. e2111549118
Author(s):  
Jinlin Yang ◽  
Jibiao Li ◽  
Wenbin Gong ◽  
Fengxia Geng

Rechargeable magnesium batteries represent a viable alternative to lithium-ion technology that can potentially overcome its safety, cost, and energy density limitations. Nevertheless, the development of a competitive room temperature magnesium battery has been hindered by the sluggish dissociation of electrolyte complexes and the low mobility of Mg2+ ions in solids, especially in metal oxides that are generally used in lithium-ion batteries. Herein, we introduce a generic proton-assisted method for the dissociation of the strong Mg–Cl bond to enable genuine Mg2+ intercalation into an oxide host lattice; meanwhile, the anisotropic Smoluchowski effect produced by titanium oxide lattices results in unusually fast Mg2+ diffusion kinetics along the atomic trough direction with a record high ion conductivity of 1.8 × 10−4 S ⋅ cm−1 on the same order as polymer electrolyte. The realization of genuine Mg2+ storage and fast diffusion kinetics enabled a rare high-power Mg-intercalation battery with inorganic oxides. The success of this work provides important information on engineering surface and interlayer chemistries of layered materials to tackle the sluggish intercalation kinetics of multivalent ions.


2020 ◽  
Vol 70 ◽  
pp. 101656
Author(s):  
Hedda Ransan-Cooper ◽  
Heather Lovell ◽  
Phillipa Watson ◽  
Andrew Harwood ◽  
Veryan Hann

Author(s):  
Long Yao ◽  
Shunlong Ju ◽  
Xuebin Yu

Rechargeable aluminum batteries (RABs) based on multivalent ions transfer have attracted great attention due to their large specific capacities, natural abundance, and high safety of metallic Al anode. However, the...


Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1397
Author(s):  
Yang-Duan Su ◽  
Yuliya Preger ◽  
Hannah Burroughs ◽  
Chenhu Sun ◽  
Paul Ohodnicki

Applications of fiber optic sensors to battery monitoring have been increasing due to the growing need of enhanced battery management systems with accurate state estimations. The goal of this review is to discuss the advancements enabling the practical implementation of battery internal parameter measurements including local temperature, strain, pressure, and refractive index for general operation, as well as the external measurements such as temperature gradients and vent gas sensing for thermal runaway imminent detection. A reasonable matching is discussed between fiber optic sensors of different range capabilities with battery systems of three levels of scales, namely electric vehicle and heavy-duty electric truck battery packs, and grid-scale battery systems. The advantages of fiber optic sensors over electrical sensors are discussed, while electrochemical stability issues of fiber-implanted batteries are critically assessed. This review also includes the estimated sensing system costs for typical fiber optic sensors and identifies the high interrogation cost as one of the limitations in their practical deployment into batteries. Finally, future perspectives are considered in the implementation of fiber optics into high-value battery applications such as grid-scale energy storage fault detection and prediction systems.


2021 ◽  
Vol 16 (3) ◽  
pp. 1285-1296
Author(s):  
Youssef Alidrissi ◽  
Radouane Ouladsine ◽  
Abdellatif Elmouatamid ◽  
Mohamed Bakhouya

2021 ◽  
Vol 170 ◽  
pp. 884-896
Author(s):  
Marcos Tostado-Véliz ◽  
Daniel Icaza-Alvarez ◽  
Francisco Jurado

Author(s):  
Chandra Chowdhury ◽  
Pranab Gain ◽  
Ayan Datta

Utilization of multivalent ions such as Ca(II), Mg(II), Al(III) in the energy storage devices opens up new opportunities to store energy density in a more efficient manner rather than monovalent...


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