scholarly journals Highly Active Trimetallic NiFeCr Layered Double Hydroxide Electrocatalysts for Oxygen Evolution Reaction

2018 ◽  
Vol 8 (15) ◽  
pp. 1703189 ◽  
Author(s):  
Yang Yang ◽  
Lianna Dang ◽  
Melinda J. Shearer ◽  
Hongyuan Sheng ◽  
Wenjie Li ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Oxygen Evolution Reaction ◽  
Highly Active ◽  
Double Hydroxide

scholarly journals 3D-printed NiFe-layered double hydroxide pyramid electrodes for enhanced electrocatalytic oxygen evolution reaction

2022 ◽  
Vol 12 (1) ◽  
Author(s):  
Jinhyuck Ahn ◽  
Yoo Sei Park ◽  
Sanghyeon Lee ◽  
Juchan Yang ◽  
Jaeyeon Pyo ◽  
...  
Keyword(s):  
Surface Area ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Oxygen Evolution Reaction ◽  
Active Sites ◽  
Step Method ◽  
Highly Active ◽  
3D Printed ◽  
Double Hydroxide

AbstractElectrochemical water splitting has been considered one of the most promising methods of hydrogen production, which does not cause environmental pollution or greenhouse gas emissions. Oxygen evolution reaction (OER) is a significant step for highly efficient water splitting because OER involves the four electron transfer, overcoming the associated energy barrier that demands a potential greater than that required by hydrogen evolution reaction. Therefore, an OER electrocatalyst with large surface area and high conductivity is needed to increase the OER activity. In this work, we demonstrated an effective strategy to produce a highly active three-dimensional (3D)-printed NiFe-layered double hydroxide (LDH) pyramid electrode for OER using a three-step method, which involves direct-ink-writing of a graphene pyramid array and electrodeposition of a copper conducive layer and NiFe-LDH electrocatalyst layer on printed pyramids. The 3D pyramid structures with NiFe-LDH electrocatalyst layers increased the surface area and the active sites of the electrode and improved the OER activity. The overpotential (η) and exchange current density (i0) of the NiFe-LDH pyramid electrode were further improved compared to that of the NiFe-LDH deposited Cu (NiFe-LDH/Cu) foil electrode with the same base area. The 3D-printed NiFe-LDH electrode also exhibited excellent durability without potential decay for 60 h. Our 3D printing strategy provides an effective approach for the fabrication of highly active, stable, and low-cost OER electrocatalyst electrodes.

scholarly journals Improvement of Trisodium Citrate-Modified NiFe-Layered Double Hydroxide Nanosheets with Carbon Black for Oxygen Evolution Reaction

Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 431
Author(s):  
Haitong He ◽  
Jun Gu ◽  
Xiaomeng Liu ◽  
Delong Yang ◽  
Yong Zhu ◽  
...  
Keyword(s):  
Carbon Black ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Oxygen Evolution Reaction ◽  
Low Cost ◽  
Cost Effective ◽  
Trisodium Citrate ◽  
Energy Storage And Conversion ◽  
Highly Active ◽  
Double Hydroxide

The pursuit of highly active and cost-effective catalysts toward oxygen evolution reaction (OER) is a crucial strategy to resolve the imminent energy crisis. NiFe layered double hydroxide (NiFe LDH) is acknowledged as one of the most promising OER electrocatalysts in alkaline electrolytes. Herein, we report a novel stepwise approach to synthesize NiFe LDHs materials merging with carbon black (CB) via trisodium citrate (TC), modifying toward OER. Benefiting from the inimitable wrapped structure, the decreased size of porous nanosheets and the superconductivity of CB substrate, NiFe LDHs/CB-TC presents excellent catalytic features with a comparative overpotential (236 mV at 10 mA cm−2) and an ultralow Tafel slope (31 mV dec−1), which are almost lower than those of advanced catalysts associated with expensive carbonaceous materials. Therefore, it is expected that such a high-activity and low-cost material can be a promising catalyst employed for the electrochemical energy storage and conversion systems.

Hierarchically porous FeNi3@FeNi layered double hydroxide nanostructures: One-step fast electrodeposition and highly efficient electrocatalytic performances for overall water splitting

2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Hierarchically Porous ◽  
One Step ◽  
Double Hydroxide

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...

LDH-derived phosphide/N-doped graphene oxide hierarchical electrocatalyst for enhanced oxygen evolution reaction

CrystEngComm ◽  
2022 ◽  
Author(s):  
Meng Ya Yang ◽  
Rong Zhao ◽  
Yi Liu ◽  
Hua Lin
Keyword(s):  
Graphene Oxide ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Hierarchical Structure ◽  
Oxygen Evolution Reaction ◽  
High Efficient ◽  
Doped Graphene ◽  
Double Hydroxide

In this work, high efficient electrocatalyst Fe-Ni2P/N-GO with hierarchical structure was developed through phosphating NiFe-based layered double hydroxide (LDH) supported by N-doped graphene oxide (GO), which was assembled by the...

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