scholarly journals Engineering Catalytic Active Sites on Cobalt Oxide Surface for Enhanced Oxygen Electrocatalysis

2017 ◽  
Vol 8 (10) ◽  
pp. 1702222 ◽  
Author(s):  
Xiaopeng Han ◽  
Guowei He ◽  
Yu He ◽  
Jinfeng Zhang ◽  
Xuerong Zheng ◽  
...  
Keyword(s):  
Cobalt Oxide ◽  
Active Sites ◽  
Oxide Surface ◽  
Catalytic Active Sites

scholarly journals Metal Air Batteries: Engineering Catalytic Active Sites on Cobalt Oxide Surface for Enhanced Oxygen Electrocatalysis (Adv. Energy Mater. 10/2018)

2018 ◽  
Vol 8 (10) ◽  
pp. 1870043 ◽  
Author(s):  
Xiaopeng Han ◽  
Guowei He ◽  
Yu He ◽  
Jinfeng Zhang ◽  
Xuerong Zheng ◽  
...  
Keyword(s):  
Cobalt Oxide ◽  
Active Sites ◽  
Oxide Surface ◽  
Catalytic Active Sites ◽  
Energy Mater

scholarly journals Spinel of Nickel-Cobalt Oxide with Rod-Like Architecture as Electrocatalyst for Oxygen Evolution Reaction

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 3918
Author(s):  
Anna Dymerska ◽  
Wojciech Kukułka ◽  
Marcin Biegun ◽  
Ewa Mijowska
Keyword(s):  
Cobalt Oxide ◽  
Oxygen Evolution ◽  
Active Sites ◽  
Solvothermal Reaction ◽  
Step Method ◽  
One Pot ◽  
Widespread Application ◽  
Nickel Cobalt ◽  
Slow Kinetics ◽  
Nickel Cobalt Oxide

The renewable energy technologies require electrocatalysts for reactions, such as the oxygen and/or hydrogen evolution reaction (OER/HER). They are complex electrochemical reactions that take place through the direct transfer of electrons. However, mostly they have high over-potentials and slow kinetics, that is why they require electrocatalysts to lower the over-potential of the reactions and enhance the reaction rate. The commercially used catalysts (e.g., ruthenium nanoparticles—Ru, iridium nanoparticles—Ir, and their oxides: RuO2, IrO2, platinum—Pt) contain metals that have poor stability, and are not economically worthwhile for widespread application. Here, we propose the spinel structure of nickel-cobalt oxide (NiCo2O4) fabricated to serve as electrocatalyst for OER. These structures were obtained by a facile two-step method: (1) One-pot solvothermal reaction and subsequently (2) pyrolysis or carbonization, respectively. This material exhibits novel rod-like morphology formed by tiny spheres. The presence of transition metal particles such as Co and Ni due to their conductivity and electron configurations provides a great number of active sites, which brings superior electrochemical performance in oxygen evolution and good stability in long-term tests. Therefore, it is believed that we propose interesting low-cost material that can act as a super stable catalyst in OER.

scholarly journals Facile Synthesis of Uniform Mesoporous Nb2O5 Micro-Flowers for Enhancing Photodegradation of Methyl Orange

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3783
Author(s):  
Jian-Qing Qiu ◽  
Huan-Qing Xie ◽  
Ya-Hao Wang ◽  
Lan Yu ◽  
Fang-Yuan Wang ◽  
...  
Keyword(s):  
Methyl Orange ◽  
Active Sites ◽  
High Performance ◽  
Diffuse Reflectance Spectroscopy ◽  
X Ray Diffraction ◽  
Flower Structure ◽  
Electron Microscopies ◽  
Bet Method ◽  
One Step ◽  
Catalytic Active Sites

The removal of organic pollutants using green environmental photocatalytic degradation techniques urgently need high-performance catalysts. In this work, a facile one-step hydrothermal technique has been successfully applied to synthesize a Nb2O5 photocatalyst with uniform micro-flower structure for the degradation of methyl orange (MO) under UV irradiation. These nanocatalysts are characterized by transmission and scanning electron microscopies (TEM and SEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) method, and UV-Vis diffuse reflectance spectroscopy (DRS). It is found that the prepared Nb2O5 micro-flowers presents a good crystal phases and consist of 3D hierarchical nanosheets with 400–500 nm in diameter. The surface area is as large as 48.6 m2 g−1. Importantly, the Nb2O5 micro-flowers exhibit superior catalytic activity up to 99.9% for the photodegradation of MO within 20 mins, which is about 60-fold and 4-fold larger than that of without catalysts (W/O) and commercial TiO2 (P25) sample, respectively. This excellent performance may be attributed to 3D porous structure with abundant catalytic active sites.

scholarly journals NaBr Poisoning of Au/TiO2 Catalysts: Effects on Kinetics, Poisoning Mechanism, and Estimation of the Number of Catalytic Active Sites

ACS Catalysis ◽  
2012 ◽  
Vol 2 (4) ◽  
pp. 684-694 ◽  
Author(s):  
Bert D. Chandler ◽  
Shane Kendell ◽  
Hieu Doan ◽  
Rachel Korkosz ◽  
Lars C. Grabow ◽  
...  
Keyword(s):  
Active Sites ◽  
Catalytic Active Sites

scholarly journals A Combined Computational and Experimental Study of Methane Activation during Oxidative Coupling of Methane (OCM) by Surface Metal Oxide Catalysts

2021 ◽  
Author(s):  
Daniyal Kiani ◽  
Sagar Sourav ◽  
Jonas Baltrusaitis ◽  
Israel E Wachs
Keyword(s):  
Experimental Study ◽  
Metal Oxide ◽  
Oxidative Coupling ◽  
Active Sites ◽  
Computational Models ◽  
Oxidative Coupling Of Methane ◽  
Catalytic Active Sites ◽  
Surface Metal ◽  
Heterolytic Dissociation ◽  
First Time

The experimentally validated computational models developed herein, for the first time, show that Mn-promotion does not enhance the activity of the surface Na2WO4 catalytic active sites for CH4 heterolytic dissociation...

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