scholarly journals Integrated Carbon/Red Phosphorus/Graphene Aerogel 3D Architecture via Advanced Vapor-Redistribution for High-Energy Sodium-Ion Batteries

2016 ◽  
Vol 6 (21) ◽  
pp. 1601037 ◽  
Author(s):  
Hong Gao ◽  
Tengfei Zhou ◽  
Yang Zheng ◽  
Yuqing Liu ◽  
Jun Chen ◽  
...  
2021 ◽  
Vol 6 (2) ◽  
pp. 547-556
Author(s):  
Xiang Liu ◽  
Biwei Xiao ◽  
Amine Daali ◽  
Xinwei Zhou ◽  
Zhou Yu ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3053
Author(s):  
Jong Hyuk Yun ◽  
San Moon ◽  
Do Kyung Kim ◽  
Joo-Hyung Kim

Due to the demand to upgrade from lithium-ion batteries (LIB), sodium-ion batteries (SIB) have been paid considerable attention for their high-energy, cost-effective, and sustainable battery system. Red phosphorus is one of the most promising anode candidates for SIBs, with a high theoretical specific capacity of 2596 mAh g−1 and in the discharge potential range of 0.01–0.8 V; however, it suffers from a low electrical conductivity, a substantial expansion of volume (~300%), and sluggish electron/ion kinetics. Herein, we have designed a well-defined electrode, which consists of red phosphorus, nanowire arrays encapsulated in the vertically aligned carbon nanotubes (P@C NWs), which were fabricated via a two-step, anodized-aluminum oxide template. The designed anode achieved a high specific capacity of 2250 mAh g−1 (87% of the theoretical capacity), and a stepwise analysis of the reaction behavior between sodium and red phosphorus was demonstrated, both of which have not been navigated in previous studies. We believe that our rational design of the red phosphorus electrode elicited the specific reaction mechanism revealed by the charge–discharge profiles, rendered excellent electrical conductivity, and accommodated volume expansion through the effective nano-architecture, thereby suggesting an efficient structure for the phosphorus anode to advance in the future.


Author(s):  
Jiefei Liu ◽  
Kangshou Lin ◽  
Yu Zhou ◽  
Yu Zhou ◽  
Xianhua Hou ◽  
...  

The sodium super ionic conductor (NASICON) materials are considered as the attractive cathode in sodium-ion batteries. Although the three-electron reactions in Na3MnTi(PO4)3 have greatly enhanced the capacity of NASICON-structure materials,...


Author(s):  
Indeok Lee ◽  
Gwangeon Oh ◽  
Seulgi Lee ◽  
Tae-Yeon Yu ◽  
Muhammad Hilmy Alfaruqi ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Lihong Xu ◽  
Xiaochuan Chen ◽  
Wenti Guo ◽  
Lingxing Zeng ◽  
Tao Yang ◽  
...  

To construct anode materials for sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) with high energy, and long lifespan is significant and still challenging. Here, sulfur-defective vanadium sulfide/carbon fibers composite (D-V5S8/CNFs)...


2013 ◽  
Vol 06 (01) ◽  
pp. 1330001 ◽  
Author(s):  
JING XU ◽  
DAE HOE LEE ◽  
YING SHIRLEY MENG

Significant progress has been achieved in the research on sodium intercalation compounds as positive electrode materials for Na-ion batteries. This paper presents an overview of the breakthroughs in the past decade for developing high energy and high power cathode materials. Two major classes, layered oxides and polyanion compounds, are covered. Their electrochemical performance and the related crystal structure, solid state physics and chemistry are summarized and compared.


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