Porous Electrode Materials for Lithium-Ion Batteries - How to Prepare Them and What Makes Them Special

2012 ◽  
Vol 2 (9) ◽  
pp. 1056-1085 ◽  
Author(s):  
Anh Vu ◽  
Yuqiang Qian ◽  
Andreas Stein
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Porous Electrode ◽  
Lithium Ion

scholarly journals Advances in the Applications of Graphene-Based Nanocomposites in Clean Energy Materials

Crystals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 47
Author(s):  
Yiqiu Xiang ◽  
Ling Xin ◽  
Jiwei Hu ◽  
Caifang Li ◽  
Jimei Qi ◽  
...  
Keyword(s):  
Solar Cells ◽  
Fuel Cells ◽  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Clean Energy ◽  
Proton Exchange ◽  
Energy Storage And Conversion ◽  
Thermoelectric Conversion

Extensive use of fossil fuels can lead to energy depletion and serious environmental pollution. Therefore, it is necessary to solve these problems by developing clean energy. Graphene materials own the advantages of high electrocatalytic activity, high conductivity, excellent mechanical strength, strong flexibility, large specific surface area and light weight, thus giving the potential to store electric charge, ions or hydrogen. Graphene-based nanocomposites have become new research hotspots in the field of energy storage and conversion, such as in fuel cells, lithium-ion batteries, solar cells and thermoelectric conversion. Graphene as a catalyst carrier of hydrogen fuel cells has been further modified to obtain higher and more uniform metal dispersion, hence improving the electrocatalyst activity. Moreover, it can complement the network of electroactive materials to buffer the change of electrode volume and prevent the breakage and aggregation of electrode materials, and graphene oxide is also used as a cheap and sustainable proton exchange membrane. In lithium-ion batteries, substituting heteroatoms for carbon atoms in graphene composite electrodes can produce defects on the graphitized surface which have a good reversible specific capacity and increased energy and power densities. In solar cells, the performance of the interface and junction is enhanced by using a few layers of graphene-based composites and more electron-hole pairs are collected; therefore, the conversion efficiency is increased. Graphene has a high Seebeck coefficient, and therefore, it is a potential thermoelectric material. In this paper, we review the latest progress in the synthesis, characterization, evaluation and properties of graphene-based composites and their practical applications in fuel cells, lithium-ion batteries, solar cells and thermoelectric conversion.

scholarly journals Electrochemical Model-Based Investigation of Thick LiFePO4 Electrode Design Parameters

Modelling ◽  
2021 ◽  
Vol 2 (2) ◽  
pp. 259-287
Author(s):  
Robert Franke-Lang ◽  
Julia Kowal
Keyword(s):  
Lithium Ion Batteries ◽  
Porous Electrode ◽  
Lithium Ion ◽  
Size Composition ◽  
Design Parameters ◽  
Model Parameters ◽  
Electrode Structure ◽  
Transport Channel ◽  
Scale Particle ◽  
Electrochemical Model

The electrification of the powertrain requires enhanced performance of lithium-ion batteries, mainly in terms of energy and power density. They can be improved by optimising the positive electrode, i.e., by changing their size, composition or morphology. Thick electrodes increase the gravimetric energy density but generally have an inefficient performance. This work presents a 2D modelling approach for better understanding the design parameters of a thick LiFePO4 electrode based on the P2D model and discusses it with common literature values. With a superior macrostructure providing a vertical transport channel for lithium ions, a simple approach could be developed to find the best electrode structure in terms of macro- and microstructure for currents up to 4C. The thicker the electrode, the more important are the direct and valid transport paths within the entire porous electrode structure. On a smaller scale, particle size, binder content, porosity and tortuosity were identified as very impactful parameters, and they can all be attributed to the microstructure. Both in modelling and electrode optimisation of lithium-ion batteries, knowledge of the real microstructure is essential as the cross-validation of a cellular and lamellar freeze-casted electrode has shown. A procedure was presented that uses the parametric study when few model parameters are known.

Recent Developments on and Prospects for Electrode Materials with Hierarchical Structures for Lithium-Ion Batteries

2017 ◽  
Vol 8 (6) ◽  
pp. 1701415 ◽  
Author(s):  
Limin Zhou ◽  
Kai Zhang ◽  
Zhe Hu ◽  
Zhanliang Tao ◽  
Liqiang Mai ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Hierarchical Structures ◽  
Lithium Ion ◽  
Recent Developments

scholarly journals Aging Mechanisms of Electrode Materials in Lithium-Ion Batteries for Electric Vehicles

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Cheng Lin ◽  
Aihua Tang ◽  
Hao Mu ◽  
Wenwei Wang ◽  
Chun Wang
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Electrochemical Behaviour ◽  
Lithium Ion ◽  
Storage Conditions ◽  
Carbon Anode ◽  
Side Reactions ◽  
Metallic Oxide ◽  
Lithium Ions ◽  
Aging Mechanisms

Electrode material aging leads to a decrease in capacity and/or a rise in resistance of the whole cell and thus can dramatically affect the performance of lithium-ion batteries. Furthermore, the aging phenomena are extremely complicated to describe due to the coupling of various factors. In this review, we give an interpretation of capacity/power fading of electrode-oriented aging mechanisms under cycling and various storage conditions for metallic oxide-based cathodes and carbon-based anodes. For the cathode of lithium-ion batteries, the mechanical stress and strain resulting from the lithium ions insertion and extraction predominantly lead to structural disordering. Another important aging mechanism is the metal dissolution from the cathode and the subsequent deposition on the anode. For the anode, the main aging mechanisms are the loss of recyclable lithium ions caused by the formation and increasing growth of a solid electrolyte interphase (SEI) and the mechanical fatigue caused by the diffusion-induced stress on the carbon anode particles. Additionally, electrode aging largely depends on the electrochemical behaviour under cycling and storage conditions and results from both structural/morphological changes and side reactions aggravated by decomposition products and protic impurities in the electrolyte.

Self-assembly synthesis of nitrogen-doped mesoporous carbons used as high-performance electrode materials in lithium-ion batteries and supercapacitors

2017 ◽  
Vol 41 (21) ◽  
pp. 12901-12909 ◽  
Author(s):  
Chunfeng Shao ◽  
Ziqiang Wang ◽  
Errui Wang ◽  
Shujun Qiu ◽  
Hailiang Chu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Self Assembly ◽  
High Performance ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Mesoporous Carbons ◽  
Nitrogen Doped ◽  
First Time ◽  
Enhanced Electrochemical Performance

Guanine was, for the first time, used as a nitrogen source during the synthesis of nitrogen-doped porous carbons (NMCs) with enhanced electrochemical performance.

LixCn as Anode Material for Lithium Ion Batteries

2006 ◽  
Vol 972 ◽  
Author(s):  
Haiming Xie ◽  
Haiying Yu ◽  
Abraham F. Jalbout ◽  
Guiling Yang ◽  
Xiumei Pan ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Cathode Materials ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Limiting Factors ◽  
Discharge Process ◽  
Metal Foil ◽  
Lithium Metal ◽  
Lithium Secondary Batteries

AbstractWe design a way that the anode hosts provide lithium ion in lithium ion battery operation. If the limiting factors of the cathode materials are less, there will be more alternatives for it. It was proven to be successful by two kinds of test cells based on LixCn as anode material, and β-FeOOH or Cr8O21 as cathode materials. Their theoretical capacities are much higher than those present electrode materials. Unlike the lithium secondary batteries with lithium metal foil or lithium alloy as anode, this type of lithium ion batteries with LixCn as anode prohibit dendrite formation during charging-discharge process. The idea of lithium ion sources coming from the anode can come true successfully as a result that steady protecting solution be sought for LixCn.

scholarly journals Ternary NiCoP nanoparticles assembled on graphene for high-performance lithium-ion batteries and supercapacitors

RSC Advances ◽  
2017 ◽  
Vol 7 (42) ◽  
pp. 26120-26124 ◽  
Author(s):  
Chunde Wang ◽  
Yinyin Qian ◽  
Jing Yang ◽  
Shiqi Xing ◽  
Xu Ding ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Room Temperature ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Solution Phase ◽  
Phase Method ◽  
Self Assembled ◽  
Solution Phase Method

We demonstrate that ternary NiCoP nanoparticles can be self-assembled on graphene at room temperature by a solution-phase method and our electrode materials exhibit a high performance for LIBs and supercapacitors.

SnO2–carbon–RGO heterogeneous electrode materials with enhanced anode performances in lithium ion batteries

2012 ◽  
Vol 22 (7) ◽  
pp. 2851 ◽  
Author(s):  
Baojun Li ◽  
Huaqiang Cao ◽  
Jingxian Zhang ◽  
Meizhen Qu ◽  
Fang Lian ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Lithium Ion

Leaching lithium from the anode electrode materials of spent lithium-ion batteries by hydrochloric acid (HCl)

2016 ◽  
Vol 51 ◽  
pp. 227-233 ◽  
Author(s):  
Yang Guo ◽  
Feng Li ◽  
Haochen Zhu ◽  
Guangming Li ◽  
Juwen Huang ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Lithium Ion ◽  
Anode Electrode
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