scholarly journals Energy Level Alignment in Ternary Organic Solar Cells

2020 ◽  
Vol 6 (8) ◽  
pp. 2000213
Author(s):  
Vincent Lami ◽  
Yvonne J. Hofstetter ◽  
Julian F. Butscher ◽  
Yana Vaynzof
Keyword(s):  
Solar Cells ◽  
Energy Level ◽  
Organic Solar Cells ◽  
Energy Level Alignment

Energy level alignment in polymer organic solar cells at donor-acceptor planar junction formed by electrospray vacuum deposition

2014 ◽  
Vol 104 (16) ◽  
pp. 163303 ◽  
Author(s):  
Ji-Hoon Kim ◽  
Jong-Am Hong ◽  
Dae-Gyeon Kwon ◽  
Jaewon Seo ◽  
Yongsup Park
Keyword(s):  
Solar Cells ◽  
Energy Level ◽  
Organic Solar Cells ◽  
Vacuum Deposition ◽  
Energy Level Alignment ◽  
Donor Acceptor ◽  
Planar Junction

Energy level alignment of dipolar interface layer in organic and hybrid perovskite solar cells

2018 ◽  
Vol 6 (12) ◽  
pp. 2915-2924 ◽  
Author(s):  
Kyung-Geun Lim ◽  
Soyeong Ahn ◽  
Tae-Woo Lee
Keyword(s):  
Solar Cells ◽  
Energy Level ◽  
Organic Solar Cells ◽  
Dipole Moments ◽  
Perovskite Solar Cells ◽  
Interface Layer ◽  
Interface Dipole ◽  
Hybrid Perovskite ◽  
Energy Level Alignment

The energy-level adjustment of the dipolar interface layer in organic solar cells and hybrid perovskite solar cells is elucidated by interface dipole moments.

Determination of energy level alignment at interfaces of hybrid and organic solar cells under ambient environment

2011 ◽  
Vol 21 (6) ◽  
pp. 1721-1729 ◽  
Author(s):  
Robert J. Davis ◽  
Matthew T. Lloyd ◽  
Summer R. Ferreira ◽  
Matthew J. Bruzek ◽  
Scott E. Watkins ◽  
...  
Keyword(s):  
Solar Cells ◽  
Energy Level ◽  
Organic Solar Cells ◽  
Ambient Environment ◽  
Energy Level Alignment

scholarly journals The Effects of Molecular Packing Behavior of Small-Molecule Acceptors in Ternary Organic Solar Cells

2021 ◽  
Vol 11 (2) ◽  
pp. 755
Author(s):  
Eunhee Lim
Keyword(s):  
Solar Cells ◽  
Energy Level ◽  
Ternary System ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Orbital Energy ◽  
Working Mechanism ◽  
Energy Level Structure ◽  
The Third ◽  
Molecular Backbone

Herein, two diketopyrrolopyrrole (DPP)-based, small-molecule isomers, o- and p-DPP-PhCN, were introduced as acceptors in ternary organic solar cells (OSCs). The isomers have the same molecular backbone but differ in the positions of the cyanide (CN) substituents (ortho and para), which greatly affects their packing behavior. Ternary solar cells composed of poly(3-hexylthiophene) (P3HT):DPP-PhCN:phenyl-C61-butyric acid methyl ester (PCBM) were fabricated, and the effects of the different packing behaviors of the third component on the device performance and the working mechanism of the ternary cells were investigated. The addition of o-DPP-PhCN with a relatively high-lying lowest unoccupied molecular orbital energy level resulted in an increase in the open-circuit voltage (VOC) in the ternary devices, demonstrating the alloy-like structure of the two acceptors (o-DPP-PhCN and PCBM) in the ternary system. However, the p-DPP-PhCN-based ternary cells exhibited VOC values similar to that of a P3HT:PCBM binary cell, irrespective of the addition of p-DPP-PhCN, indicating a cascade energy-level structure in the ternary system and an effective charge transfer from the P3HT to the PCBM. Importantly, by increasing the addition of p-DPP-PhCN, the short-circuit current density increased substantially, resulting in pronounced shoulder peaks in the external quantum efficiency responses in the long-wavelength region, corresponding to the contribution of the photocurrent generated by the light absorption of p-DPP-PhCN. Despite sharing the same molecular backbone, the two DPP-PhCNs exhibited substantially different packing behaviors according to the position of their CN substituents, which also greatly affected the working mechanism of the ternary devices fabricated using the DPP-PhCNs as the third component.

Uphill and downhill charge generation from charge transfer to charge separated states in organic solar cells

2021 ◽  
Author(s):  
Shahidul Alam ◽  
Vojtech Nádaždy ◽  
Tomáš Váry ◽  
Christian Friebe ◽  
Rico Meitzner ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Solar Cells ◽  
Charge Transfer ◽  
Energy Level ◽  
Density Of States ◽  
Organic Solar Cells ◽  
Joint Density ◽  
Charge Generation ◽  
Donor Acceptor

Energy level alignments at the organic donor–acceptor interface cannot be predicted from cyclic voltammetry. Onsets for joint density of states and charge generation, reveal cases of energy uphill and – newly observed – downhill charge generation.

scholarly journals 9.0% power conversion efficiency from ternary all-polymer solar cells

2017 ◽  
Vol 10 (10) ◽  
pp. 2212-2221 ◽  
Author(s):  
Zhaojun Li ◽  
Xiaofeng Xu ◽  
Wei Zhang ◽  
Xiangyi Meng ◽  
Zewdneh Genene ◽  
...  
Keyword(s):  
Solar Cells ◽  
Energy Level ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
High Performance ◽  
Polymer Solar Cells ◽  
Power Conversion ◽  
Energy Level Alignment ◽  
Proper Energy

High-performance ternary all-polymer solar cells with outstanding efficiency of 9.0% are realized by incorporating two donor and one acceptor polymers with complementary absorption and proper energy level alignment.

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