scholarly journals High‐Performance Ammonium Cobalt Phosphate Nanosheet Electrocatalyst for Alkaline Saline Water Oxidation

2021 ◽  
pp. 2100498
Author(s):  
Zhongxin Song ◽  
Kaixi (Cathy) Wang ◽  
Qian Sun ◽  
Lei Zhang ◽  
Junjie Li ◽  
...  
Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.


2021 ◽  
pp. 120510
Author(s):  
Shaista Ibrahim ◽  
Uzaira Rafique ◽  
Mohsin Saleem ◽  
Waheed Iqbal ◽  
Saghir Abbas ◽  
...  

2021 ◽  
Author(s):  
Luke Sibimol ◽  
Manjunath Chatti ◽  
Asha Yadav ◽  
Brittany Kerr ◽  
Jiban Kangsabanik ◽  
...  

Proton-exchange membrane water electrolysers provide many advantages for the energy-efficient production of H<sub>2</sub>, but the current technology relies on high loadings of expensive iridium at the anodes, which are often unstable in operation. To address this, the present work scrutinises the properties of antimony-metal (Co, Mn, Ni, Fe, Ru) oxides synthesised as flat thin films by a solution-based method for the oxygen evolution reaction in 0.5 M H<sub>2</sub>SO<sub>4</sub>. Among the non-noble-metal catalysts, only cobalt-antimony and manganese-antimony oxides demonstrate high stability and reasonable activity under ambient conditions, but slowly lose activity at elevated temperatures. The ruthenium-antimony system is highly active, requiring an overpotential of 0.39 ± 0.03 and 0.34 ± 0.01 V to achieve 10 mA cm<sup>-2</sup> at 24 ± 2 and 80 °C, respectively, and remaining remarkably stable during one-week tests at 80 °C. The <i>S</i>-number for this catalyst is higher than that for the high-performance benchmark Ir-based systems. Density functional theory analysis and physical characterisation reveal that this high stability is supported by the enhanced hybridisation of the oxygen p- and metal d-orbitals induced by antimony, and can arise from two distinct structural scenarios: either formation of an antimonate phase, or nanoscale intermixing of metal and antimony oxide crystallites.


Author(s):  
Shijun Lei ◽  
Dali Huang ◽  
Shuhao Liu ◽  
Mingfeng Chen ◽  
Rong Ma ◽  
...  

Solar-thermal desalination by interfacial evaporation that leverages abundant solar energy to convert saline water into clean freshwater has promised an exciting alternative to meet the grand challenges of water scarcity....


Sign in / Sign up

Export Citation Format

Share Document