scholarly journals High-Mobility p-Type Organic Semiconducting Interlayer Enhancing Efficiency and Stability of Perovskite Solar Cells

2017 ◽  
Vol 4 (9) ◽  
pp. 1700025 ◽  
Author(s):  
Mingyu Zhang ◽  
Jiayu Wang ◽  
Liang Li ◽  
Guanhaojie Zheng ◽  
Kuan Liu ◽  
...  
Nano Energy ◽  
2017 ◽  
Vol 38 ◽  
pp. 1-11 ◽  
Author(s):  
Xiaolu Zheng ◽  
Hongwei Lei ◽  
Guang Yang ◽  
Weijun Ke ◽  
Zhiliang Chen ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 389
Author(s):  
Mohammad Aminul Islam ◽  
Yasmin Abdu Wahab ◽  
Mayeen Uddin Khandaker ◽  
Abdullah Alsubaie ◽  
Abdulraheem SA Almalki ◽  
...  

Copper oxide (CuxO) films are considered to be an attractive hole-transporting material (HTM) in the inverted planar heterojunction perovskite solar cells due to their unique optoelectronic properties, including intrinsic p-type conductivity, high mobility, low-thermal emittance, and energy band level matching with the perovskite (PS) material. In this study, the potential of reactive sputtered CuxO thin films with a thickness of around 100 nm has been extensively investigated as a promising HTM for effective and stable perovskite solar cells. The as-deposited and annealed films have been characterized by using X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Photoluminescence (PL), UV-Vis spectroscopy, and Hall-effect measurement techniques. The significant change in structural and optoelectronic properties has been observed as an impact of the thermal annealing process. The phase conversion from Cu2O to CuO, including grain size increment, was observed upon thermal annealing. The transmittance and optical bandgap were found to vary with the films’ crystallographic transformation. The predominant p-type conductivity and optimum annealing time for higher mobility have been confirmed from the Hall measurement. Films’ optoelectrical properties were implemented in the complete perovskite solar cell for numerical analysis. The simulation results show that a 40 min annealed CuxO film yields the highest efficiency of 22.56% with a maximum open-circuit voltage of 1.06 V.


2021 ◽  
Vol 13 (5) ◽  
pp. 6688-6698
Author(s):  
Zilong Zhang ◽  
Lusheng Liang ◽  
Longhui Deng ◽  
Lu Ren ◽  
Nan Zhao ◽  
...  

2021 ◽  
Vol 60 (19) ◽  
pp. 10608-10613
Author(s):  
Jian Du ◽  
Jialong Duan ◽  
Xiya Yang ◽  
Yanyan Duan ◽  
Quanzhu Zhou ◽  
...  

2015 ◽  
Vol 6 (9) ◽  
pp. 1666-1673 ◽  
Author(s):  
Jiewei Liu ◽  
Sandeep Pathak ◽  
Thomas Stergiopoulos ◽  
Tomas Leijtens ◽  
Konrad Wojciechowski ◽  
...  

Solar RRL ◽  
2018 ◽  
Vol 3 (1) ◽  
pp. 1800232 ◽  
Author(s):  
Xiao-Xin Gao ◽  
Ding-Jiang Xue ◽  
Dong Gao ◽  
Qiwei Han ◽  
Qian-Qing Ge ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 2592 ◽  
Author(s):  
Funeka Matebese ◽  
Raymond Taziwa ◽  
Dorcas Mutukwa

P-type wide bandgap semiconductor materials such as CuI, NiO, Cu2O and CuSCN are currently undergoing intense research as viable alternative hole transport materials (HTMs) to the spiro-OMeTAD in perovskite solar cells (PSCs). Despite 23.3% efficiency of PSCs, there are still a number of issues in addition to the toxicology of Pb such as instability and high-cost of the current HTM that needs to be urgently addressed. To that end, copper thiocyanate (CuSCN) HTMs in addition to robustness have high stability, high hole mobility, and suitable energy levels as compared to spiro-OMeTAD HTM. CuSCN HTM layer use affordable materials, require short synthesis routes, require simple synthetic techniques such as spin-coating and doctor-blading, thus offer a viable way of developing cost-effective PSCs. HTMs play a vital role in PSCs as they can enhance the performance of a device by reducing charge recombination processes. In this review paper, we report on the current progress of CuSCN HTMs that have been reported to date in PSCs. CuSCN HTMs have shown enhanced stability when exposed to weather elements as the solar devices retained their initial efficiency by a greater percentage. The efficiency reported to date is greater than 20% and has a potential of increasing, as well as maintaining thermal stability.


2019 ◽  
Vol 12 (1) ◽  
pp. 230-237 ◽  
Author(s):  
E. Yalcin ◽  
M. Can ◽  
C. Rodriguez-Seco ◽  
E. Aktas ◽  
R. Pudi ◽  
...  

Herein, we studied the use of two different Self Assembled Monolayers (SAMs) made of semiconductor hole transport organic molecules to replace the most common p-type contact, PEDOT:PSS, in PiN methyl ammonium lead iodide perovskite solar cells (PSCs).


Sign in / Sign up

Export Citation Format

Share Document