scholarly journals FeNi2 Se4 -Reduced Graphene Oxide Nanocomposite: Enhancing Bifunctional Electrocatalytic Activity for Oxygen Evolution and Reduction through Synergistic Effects

2017 ◽  
Vol 1 (10) ◽  
pp. 1700086 ◽  
Author(s):  
Siddesh Umapathi ◽  
Jahangir Masud ◽  
Abdurazag T. Swesi ◽  
Manashi Nath
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Oxygen Evolution ◽  
Electrocatalytic Activity ◽  
Synergistic Effects ◽  
Reduced Graphene

Enhanced electrolytic oxygen evolution by the synergistic effects of trimetallic FeCoNi boride oxides immobilized on polypyrrole/reduced graphene oxide

2020 ◽  
Vol 8 (4) ◽  
pp. 1821-1828 ◽  
Author(s):  
Hui Mao ◽  
Xi Guo ◽  
Yuanlin Fu ◽  
Haoran Yang ◽  
Yu Zhang ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Oxygen Evolution ◽  
Synergistic Effects ◽  
Reduced Graphene

Trimetallic FeCoNiBOx/PPy/rGO nanocomposites exhibit optimal OER activity due to the synergistic effects of each component.

Co–Fe Bimetal Phosphate Composite Loaded on Reduced Graphene Oxide for Oxygen Evolution

NANO ◽  
2019 ◽  
Vol 14 (01) ◽  
pp. 1950003 ◽  
Author(s):  
Guoxing Zhu ◽  
Xulan Xie ◽  
Lisong Xiao ◽  
Xiaoyun Li ◽  
Xiaoping Shen ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Synergistic Effects ◽  
Water Electrolysis ◽  
Onset Potential ◽  
Reduced Graphene

Development of high-performance nonprecious metal-based catalysts for oxygen evolution reaction (OER) is crucial to improve the efficiency of water electrolysis and photoelectrochemical water splitting for harvesting and storage of solar energy. Herein, Co–Fe phosphates and their composites with reduced graphene oxide (rGO) were prepared by a simple hydrothermal method, which then acted as oxygen evolution reaction catalysts. In 1.0 M KOH aqueous solution, the as-obtained optimal composite, Co–Fe phosphate/rGO, can catalyze oxygen evolution reaction with a very sharp onset potential and a small over-potential of 338[Formula: see text]mV to achieve a current density of 10[Formula: see text]mA[Formula: see text]cm[Formula: see text]. It was found that in these Co–Fe phosphates, the optimal Co:Fe ratio is 0.75:0.25. The excellent electrocatalytic performance of the Co–Fe phosphate/rGO composite would benefit from the synergistic effects between Fe and Co species, as well as rGO substrate providing conductive channels. The formed Co–Fe phosphate/rGO electrocatalysts can be the promising replacement of precious metal-based catalysts for more practical and cost-efficient water splitting.

scholarly journals Electrocatalytic Activity of Reduced Graphene Oxide Supported Cobalt Cinnamate for Oxygen Evolution Reaction

Energies ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 5020
Author(s):  
Myung Jun Lee ◽  
Junyeop Kim ◽  
Jaeun Kang ◽  
Hyewon Shin ◽  
Junghwan Do ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Electrochemical Reaction ◽  
Porous Coordination Polymers ◽  
Inorganic Hybrid ◽  
Reduced Graphene ◽  
The Stability

The stability of porous coordination polymers during an electrochemical reaction could be improved by introducing supporter materials. An I3O0-type inorganic hybrid electrocatalyst, cobalt cinnamate, supported on reduced graphene oxide (rGO) was successfully prepared for an oxygen evolution reaction. The electrocatalytic activity and stability of cobalt cinnamate(catalyst)/rGO composite were significantly improved due to the strong interaction between catalyst and supporter, which led to enhanced anchoring stability and electrical conductivity. The catalyst/rGO composite shows ~30 mV reduction in overpotential and improvement in durability from ≥35% to ≥70% after a reaction time of 12 h, compared to the catalyst alone.

Preparation and enhanced electrocatalytic activity of graphene supported palladium nanoparticles with multi-edges and corners

RSC Advances ◽  
2016 ◽  
Vol 6 (101) ◽  
pp. 98708-98716 ◽  
Author(s):  
Zhelin Liu ◽  
Yinghui Feng ◽  
Xiaofeng Wu ◽  
Keke Huang ◽  
Shouhua Feng ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Electrocatalytic Activity ◽  
Palladium Nanoparticles ◽  
Pd Nanoparticles ◽  
Reduced Graphene ◽  
Point Discharge ◽  
Supported Palladium ◽  
Activity Point

Pd nanoparticles with multi-edges and corners are prepared and assembled on reduced graphene oxide to examine the electrocatalytic activity. Point discharge is regarded to be capable of facilitating the electron transfer.

scholarly journals Electrodeposition–Assisted Assembled Multilayer Films of Gold Nanoparticles and Glucose Oxidase onto Polypyrrole-Reduced Graphene Oxide Matrix and Their Electrocatalytic Activity toward Glucose

Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 993 ◽  
Author(s):  
Baoyan Wu ◽  
Shihua Hou ◽  
Yongyong Xue ◽  
Zhan Chen
Keyword(s):  
Gold Nanoparticles ◽  
Graphene Oxide ◽  
Glucose Oxidase ◽  
Reduced Graphene Oxide ◽  
Self Assembly ◽  
Electrocatalytic Activity ◽  
Multilayer Films ◽  
Glucose Biosensor ◽  
Future Design ◽  
Reduced Graphene

The study reports a facile and eco-friendly approach for nanomaterial synthesis and enzyme immobilization. A corresponding glucose biosensor was fabricated by immobilizing the gold nanoparticles (AuNPs) and glucose oxidase (GOD) multilayer films onto the polypyrrole (PPy)/reduced graphene oxide (RGO) modified glassy carbon electrode (GCE) via the electrodeposition and self-assembly. PPy and graphene oxide were first coated on the surface of a bare GCE by the electrodeposition. Then, AuNPs and GOD were alternately immobilized onto PPy-RGO/GCE electrode using the electrodeposition of AuNPs and self-assembly of GOD to obtain AuNPs-GOD multilayer films. The resulting PPy-RGO-(AuNPs-GOD)n/GCE biosensors were used to characterize and assess their electrocatalytic activity toward glucose using cyclic voltammetry and amperometry. The response current increased with the increased number of AuNPs-GOD layers, and the biosensor based on four layers of AuNPs-GOD showed the best performance. The PPy-RGO-(AuNPs-GOD)4/GCE electrode can detect glucose in a linear range from 0.2 mM to 8 mM with a good sensitivity of 0.89 μA/mM, and a detection limit of 5.6 μM (S/N = 3). This study presents a promising eco-friendly biosensor platform with advantages of electrodeposition and self-assembly, and would be helpful for the future design of more complex electrochemical detection systems.

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