Iron(II) Chloride-Catalyzed Nitrene Transfer Reaction for Dearomative Amination of β-Naphthols with Aryl Azides

2018 ◽  
Vol 360 (24) ◽  
pp. 4720-4725 ◽  
Author(s):  
Dun-Qi Wu ◽  
Zhen-Yu Guan ◽  
Yi Peng ◽  
Jian Sun ◽  
Cheng Zhong ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Aryl Azides ◽  
Nitrene Transfer

Iron-Catalyzed Nitrene Transfer Reaction of 4-Hydroxystilbenes with Aryl Azides: Synthesis of Imines via C═C Bond Cleavage

2019 ◽  
Vol 21 (20) ◽  
pp. 8389-8394 ◽  
Author(s):  
Yi Peng ◽  
Yan-Hui Fan ◽  
Si-Yuan Li ◽  
Bin Li ◽  
Jing Xue ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Bond Cleavage ◽  
Aryl Azides ◽  
Nitrene Transfer

Mn-salen catalyzed nitrene transfer reaction: Enantioselective imidation of alkyl aryl sulfides

Tetrahedron ◽  
1999 ◽  
Vol 55 (49) ◽  
pp. 13937-13946 ◽  
Author(s):  
Hisashi Nishikori ◽  
Chisa Ohta ◽  
Eva Oberlin ◽  
Ryo Irie ◽  
Tsutomu Katsuki
Keyword(s):  
Transfer Reaction ◽  
Alkyl Aryl ◽  
Nitrene Transfer ◽  
Aryl Sulfides

scholarly journals Nitrene-Transfer Reaction between Azide and Unsaturated Ether in the Presence of Pd(II) Catalyst

1988 ◽  
Vol 61 (3) ◽  
pp. 931-938 ◽  
Author(s):  
Toshihiko Migita ◽  
Kazuya Hongoh ◽  
Hiroyuki Naka ◽  
Setsuko Nakaido ◽  
Masanori Kosugi
Keyword(s):  
Transfer Reaction ◽  
Nitrene Transfer ◽  
Unsaturated Ether

ChemInform Abstract: Mn-Salen Catalyzed Nitrene Transfer Reaction: Enantioselective Imidation of Alkyl Aryl Sulfides.

ChemInform ◽  
2010 ◽  
Vol 31 (10) ◽  
pp. no-no
Author(s):  
Hisashi Nishikori ◽  
Chisa Ohta ◽  
Eva Oberlin ◽  
Ryo Irie ◽  
Tsutomu Katsuki
Keyword(s):  
Transfer Reaction ◽  
Alkyl Aryl ◽  
Nitrene Transfer ◽  
Aryl Sulfides

Site-Selective and Chemoselective C–H Functionalization for the Synthesis of Spiroaminals via a Silver-Catalyzed Nitrene Transfer Reaction

ACS Catalysis ◽  
2020 ◽  
Vol 10 (22) ◽  
pp. 13296-13304
Author(s):  
Shingo Harada ◽  
Mayu Kobayashi ◽  
Masato Kono ◽  
Tetsuhiro Nemoto
Keyword(s):  
Transfer Reaction ◽  
Nitrene Transfer ◽  
Site Selective

scholarly journals Synthesis of a copper-supported triplet nitrene complex pertinent to copper-catalyzed amination

Science ◽  
2019 ◽  
Vol 365 (6458) ◽  
pp. 1138-1143 ◽  
Author(s):  
Kurtis M. Carsch ◽  
Ida M. DiMucci ◽  
Diana A. Iovan ◽  
Alex Li ◽  
Shao-Liang Zheng ◽  
...  
Keyword(s):  
Multiple Bond ◽  
Transfer Reactions ◽  
Aryl Azides ◽  
Nitrene Transfer ◽  
Quantum Chemistry Calculations ◽  
Triplet Nitrene ◽  
X Ray Absorption ◽  
Dinitrogen Complex ◽  
Transfer Mechanisms ◽  
Bond Character

Terminal copper-nitrenoid complexes have inspired interest in their fundamental bonding structures as well as their putative intermediacy in catalytic nitrene-transfer reactions. Here, we report that aryl azides react with a copper(I) dinitrogen complex bearing a sterically encumbered dipyrrin ligand to produce terminal copper nitrene complexes with near-linear, short copper–nitrenoid bonds [1.745(2) to 1.759(2) angstroms]. X-ray absorption spectroscopy and quantum chemistry calculations reveal a predominantly triplet nitrene adduct bound to copper(I), as opposed to copper(II) or copper(III) assignments, indicating the absence of a copper−nitrogen multiple-bond character. Employing electron-deficient aryl azides renders the copper nitrene species competent for alkane amination and alkene aziridination, lending further credence to the intermediacy of this species in proposed nitrene-transfer mechanisms.

scholarly journals Synthesis and catalytic activity of μ-oxo ruthenium(IV) porphyrin species to promote amination reactions

2016 ◽  
Vol 20 (08n11) ◽  
pp. 1156-1165 ◽  
Author(s):  
Paolo Zardi ◽  
Daniela Intrieri ◽  
Daniela Maria Carminati ◽  
Francesco Ferretti ◽  
Piero Macchi ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Catalytic Activity ◽  
Single Crystal ◽  
General Formula ◽  
Catalytic Efficiency ◽  
Transfer Reactions ◽  
Aryl Azides ◽  
X Ray ◽  
Nitrene Transfer ◽  
Catalytically Active

This work describes the synthesis of ruthenium(IV) [Formula: see text]-oxo porphyrin complexes of general formula [RuIV(TPP)(X)]2O which have been applied as catalysts in nitrene transfer reactions using aryl azides (ArN[Formula: see text] as nitrene sources. Collected data indicated that the catalytic efficiency of [RuIV(TPP)(OCH[Formula: see text]]2O was comparable to that of RuII(TPP)CO because of their analogous reactivity towards aryl azides to give the same catalytically active bis-imido species RuVI(TPP)(ArN)2. The reaction of [RuIV(TPP)(OCH[Formula: see text]]2O with Ph3CN3 or (CH[Formula: see text]SiN3 afforded [RuIV(TPP)(N[Formula: see text]]2O which was fully characterised, its molecular structure was also determined by single crystal X-ray analysis.

Nitrene transfer reaction catalyzed by substituted metallophthalocyanines

2006 ◽  
Vol 248 (1-2) ◽  
pp. 148-151 ◽  
Author(s):  
Sheng-Yong Yan ◽  
Yi Wang ◽  
Yuan-Jie Shu ◽  
Hui-Hua Liu ◽  
Xiang-Ge Zhou
Keyword(s):  
Transfer Reaction ◽  
Nitrene Transfer
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