Organocatalyzed Thia-Michael Addition and Sequential Inverse Electron Demanding Diels-Alder Reaction to 3-Vinyl-1,2,4- triazine Platforms

2017 ◽  
Vol 359 (23) ◽  
pp. 4106-4110 ◽  
Author(s):  
Clément Berthonneau ◽  
Floris Buttard ◽  
Marie-Aude Hiebel ◽  
Franck Suzenet ◽  
Jean-François Brière
Keyword(s):  
Michael Addition ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Self-crosslinkable polymers from furan-functionalized Meldrum's acid and maleimides as effective precursors of free-standing and flexible crosslinked polymer films showing low dielectric constants

2020 ◽  
Vol 11 (9) ◽  
pp. 1606-1613 ◽  
Author(s):  
Chien-Ho Huang ◽  
Ying-Ling Liu
Keyword(s):  
Polymer Films ◽  
Michael Addition ◽  
Alder Reaction ◽  
Diels Alder ◽  
Dielectric Constants ◽  
Free Standing ◽  
Crosslinked Polymer ◽  
Low Dielectric ◽  
Diels Alder Reaction ◽  
Reactive Polymers

The integration of Michael addition and Diels–Alder reaction in the synthesis of reactive polymers for self-standing and flexible crosslinked polymer films.

A Diels-Alder reaction / oxa-Michael addition / acyloin rearrangement cascade on tropolonic substrates

2018 ◽  
Vol 59 (16) ◽  
pp. 1560-1563 ◽  
Author(s):  
Macarena Eugui ◽  
Katerine Rasquin ◽  
Andrés López Radcenco ◽  
Leopoldo Suescun ◽  
Guillermo Moyna
Keyword(s):  
Michael Addition ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Struktur und Reaktivität von isoanellierten heterocyclischen Systemen mit 4nπ- und (4n+2)π-Elektronen, XVII [1] Diels-Aider- und Michael-Additionsreaktionen von 3-Alkoxy-2,4-dihydropyrrolo[3,4-b]indolen mit Ethindicarbonsäuredialkylestern / Structure and Reactivity of Isoannelated Heterocyclic Systems with 4nπ- and (4n+2)π-Electrons, XVII [1] Diels-Alder and Michael Addition Reactions of 3-Alkoxy-2,4-dihydropyrrolo[3,4-b]indoles with Dialkyl Acetylenedicarboxylates

1988 ◽  
Vol 43 (12) ◽  
pp. 1656-1661 ◽  
Author(s):  
Gerald Dyker ◽  
Richard P. Kreher
Keyword(s):  
Michael Addition ◽  
Isotopic Labeling ◽  
Alder Reaction ◽  
Diels Alder ◽  
Addition Reactions ◽  
Current Interest ◽  
Polar Solvents ◽  
Dialkyl Acetylenedicarboxylates ◽  
Diels Alder Reaction

Abstract The reactions of 2-rm-butyl-3-methoxy-4-methyl-2,4-dihydropyrrolo[3,4-b]indole (3) with dialkyl acetylenedicarboxylates are decisively influenced by the solvent. In the presence of alcohols as protic and polar solvents Michael addition is prefered, while in aprotic and less polar solvents like ether the Diels-Alder reaction is favoured. Based on stereospecific hydrolysis and isotopic labeling dipolar intermediates are discussed. The results are of current interest for mechanistic and theoretical reasons

Diverse Routes for the synthesis of Indole-fused Complex Architecture from Simple Molecules

2020 ◽  
Vol 17 ◽  
Author(s):  
Singh Shivendra ◽  
Suresh Singh Chauhan ◽  
Neeraj Kumar Sharma ◽  
Dutt Sunil ◽  
Keshav Lalit Ameta
Keyword(s):  
Michael Addition ◽  
High Selectivity ◽  
Alder Reaction ◽  
Diels Alder ◽  
Catalytic Reactions ◽  
Diels Alder Reaction ◽  
Simple Molecules ◽  
Complex Architecture ◽  
The Given

: Several easy, efficient and convenient procedures to access indoles fused heterocyclic systems are described in this review. These heterocyclic systems were synthesized from several cyclic or acyclic molecules via a variety of reactions such as Diels-Alder reaction, Michael addition, Morita-Baylis-Hillmann reaction and many other domino/Cascade approaches with high selectivity. Most of the given protocols in this review proceed though organocatalytic pathways, however some underwent via different catalytic and non-catalytic reactions.

ChemInform Abstract: Sequential Michael Addition and Enamine-Promoted Inverse Electron Demanding Diels-Alder Reaction upon 3-Vinyl-1,2,4-triazine Platforms.

ChemInform ◽  
2015 ◽  
Vol 46 (44) ◽  
pp. no-no
Author(s):  
Magali Lorion ◽  
Gerald Guillaumet ◽  
Jean-Francois Briere ◽  
Franck Suzenet
Keyword(s):  
Michael Addition ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction

Sequential Michael Addition and Enamine-Promoted Inverse Electron Demanding Diels–Alder Reaction upon 3-Vinyl-1,2,4-triazine Platforms

2015 ◽  
Vol 17 (12) ◽  
pp. 3154-3157 ◽  
Author(s):  
Magali Lorion ◽  
Gérald Guillaumet ◽  
Jean-François Brière ◽  
Franck Suzenet
Keyword(s):  
Michael Addition ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction
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