Asymmetric Dearomative Halogenation of β-Naphthols: The Axial Chirality Transfer Reaction

2017 ◽  
Vol 360 (3) ◽  
pp. 401-405 ◽  
Author(s):  
Pengxin Wang ◽  
Jie Wang ◽  
Linqing Wang ◽  
Dan Li ◽  
Kezhou Wang ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Chirality Transfer ◽  
Axial Chirality

An Axial-to-Axial Chirality Transfer Strategy for Atroposelective Construction of C–N Axial Chirality

2021 ◽  
Author(s):  
Ze-Shui Liu ◽  
Pei-Pei Xie ◽  
Yu Hua ◽  
Chenggui Wu ◽  
Yuanyuan Ma ◽  
...  
Keyword(s):  
Chirality Transfer ◽  
Axial Chirality

Organocatalytic Asymmetric Methodologies towards the Synthesis of Atropisomeric N-Heterocycles

Synthesis ◽  
2020 ◽  
Vol 52 (17) ◽  
pp. 2450-2468
Author(s):  
Vasco Corti ◽  
Giulio Bertuzzi
Keyword(s):  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Chirality Transfer ◽  
Axial Chirality ◽  
Axially Chiral ◽  
Molecular Architectures

A perspective on the literature dealing with the organocatalytic asymmetric preparation of axially chiral N-heterocycles is provided. A particular focus is devoted to rationalize the synthetic strategies employed in each case. Moreover, specific classes of organocatalysts are shown to stand out as privileged motives for the stereoselective preparation of such synthetically challenging molecular architectures. Finally, an overview of the main trends in the field is given.1 Introduction2 Five-Membered Rings2.1 Arylation2.2 Dynamic Kinetic Resolution2.3 Ring Construction2.4 Central-to-Axial Chirality Conversion and Chirality Transfer2.5 Desymmetrization3 Six-Membered Rings3.1 Desymmetrization3.2 (Dynamic) Kinetic Resolution3.3 Ring Construction3.4 Central-to-Axial Chirality Conversion4 Conclusion

Synthesis of Chiral 1-Substituted Tetrahydroisoquinolines by the Intramolecular 1,3-Chirality Transfer Reaction Catalyzed by Bi(OTf)3

2011 ◽  
Vol 76 (7) ◽  
pp. 2102-2114 ◽  
Author(s):  
Nobuyuki Kawai ◽  
Ryuzou Abe ◽  
Mika Matsuda ◽  
Jun’ichi Uenishi
Keyword(s):  
Transfer Reaction ◽  
Chirality Transfer

scholarly journals Pericyclic Cascade with Chirality Transfer: Reaction Pathway and Origin of Enantioselectivity of the Hetero-Claisen Approach to Oxindoles

2011 ◽  
Vol 50 (48) ◽  
pp. 11478-11482 ◽  
Author(s):  
Nihan Çelebi-Ölçüm ◽  
Yu-hong Lam ◽  
Edward Richmond ◽  
Kenneth B. Ling ◽  
Andrew D. Smith ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Reaction Pathway ◽  
Chirality Transfer

ChemInform Abstract: Pericyclic Cascade with Chirality Transfer: Reaction Pathway and Origin of Enantioselectivity of the Hetero-Claisen Approach to Oxindoles.

ChemInform ◽  
2012 ◽  
Vol 43 (18) ◽  
pp. no-no
Author(s):  
Nihan Celebi-Oelcuem ◽  
Yu-hong Lam ◽  
Edward Richmond ◽  
Kenneth B. Ling ◽  
Andrew D. Smith ◽  
...  
Keyword(s):  
Transfer Reaction ◽  
Reaction Pathway ◽  
Chirality Transfer
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