Carbonylative Tertiary Amide Synthesis from Aryl Iodides and Tertiary Amines via Oxidant-Free C−N Bond Cleavage Catalyzed by Palladium(II) Chloride in Polyethylene Glycol/Water

2017 ◽  
Vol 359 (15) ◽  
pp. 2621-2629 ◽  
Author(s):  
Rajendra S. Mane ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Polyethylene Glycol ◽  
Bond Cleavage ◽  
Tertiary Amines ◽  
Amide Synthesis ◽  
Tertiary Amide ◽  
Aryl Iodides

ChemInform Abstract: Iodine-Catalyzed C3-Formylation of Indoles via C-N Bond Cleavage of Tertiary Amines under Aerobic Conditions.

ChemInform ◽  
2015 ◽  
Vol 46 (37) ◽  
pp. no-no
Author(s):  
Lin Lu ◽  
Qiheng Xiong ◽  
Shengmei Guo ◽  
Tianqiang He ◽  
Feng Xu ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Tertiary Amines ◽  
Aerobic Conditions

Pd/C-catalyzed synthesis of oxamates by oxidative cross double carbonylation of alcohols and tertiary amines through C–N bond cleavage

2019 ◽  
Vol 43 (46) ◽  
pp. 18072-18078 ◽  
Author(s):  
Yuvraj A. Kolekar ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Active Compound ◽  
Bond Cleavage ◽  
Tertiary Amines ◽  
Carbonylation Reaction ◽  
Palladium Catalyzed ◽  
Biological Active Compound

Palladium-catalyzed oxidative cross double carbonylation reaction between tertiary amines and alcohols using oxidant O2 and KI as the additive affords oxamates. Oxamate are as a intermediate in biological active compound and glycol synthesis.

Palladium-catalyzed carbonylative synthesis of arylacetamides from benzyl formates and tertiary amines

2020 ◽  
Vol 7 (21) ◽  
pp. 3406-3410
Author(s):  
Ming Lai ◽  
Zhi-Peng Bao ◽  
Xinxin Qi ◽  
Xiao-Feng Wu
Keyword(s):  
Bond Cleavage ◽  
Tertiary Amines ◽  
Palladium Catalyzed

A palladium-catalyzed carbonylative synthesis of arylacetamides via a C–N bond cleavage of tertiary amines with benzyl formates as the CO source has been disclosed. A variety of arylacetamides were obtained in very good yields under oxidant-free conditions.

ChemInform Abstract: Direct Amidation of Carboxylic Acids with Tertiary Amines: Amide Formation over Copper Catalysts Through C-N Bond Cleavage.

ChemInform ◽  
2015 ◽  
Vol 46 (8) ◽  
pp. no-no
Author(s):  
Biquan Xiong ◽  
Longzhi Zhu ◽  
Xiaofeng Feng ◽  
Jian Lei ◽  
Tieqiao Chen ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Bond Cleavage ◽  
Copper Catalysts ◽  
Tertiary Amines ◽  
Amide Formation ◽  
Direct Amidation

Transamidation via C–N bond cleavage of amides and tertiary amines

2020 ◽  
Vol 7 (18) ◽  
pp. 2737-2743
Author(s):  
Muhammad Aliyu Idris ◽  
Sunwoo Lee
Keyword(s):  
Bond Cleavage ◽  
Tertiary Amines

Double C–N bond cleavage of amides and tertiary amines afforded the transamidated products in good yields.

ChemInform Abstract: A Versatile Cobalt Catalyst for Secondary and Tertiary Amide Synthesis from Various Carboxylic Acid Derivatives.

ChemInform ◽  
2016 ◽  
Vol 47 (26) ◽  
Author(s):  
Se Eun Kim ◽  
Hyungwoo Hahm ◽  
Suyeon Kim ◽  
Wonseok Jang ◽  
Byunghoon Jeon ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Cobalt Catalyst ◽  
Amide Synthesis ◽  
Tertiary Amide
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