Bifunctional Amine-Squaramide Catalyzed Friedel-Crafts Alkylation Based onortho-Quinone Methides in Oil-Water Phases: Enantioselective Synthesis of Triarylmethanes

2017 ◽  
Vol 359 (5) ◽  
pp. 791-797 ◽  
Author(s):  
Yifeng Wang ◽  
Cheng Zhang ◽  
Haojiang Wang ◽  
Yidong Jiang ◽  
Xiaohua Du ◽  
...  
2021 ◽  
Author(s):  
Wanlong Xiao ◽  
Yuhao Mo ◽  
Jing Guo ◽  
Zhishan Su ◽  
Shunxi Dong ◽  
...  

A new type of C2-symmetric chiral macrodiolides are readily obtained via chiral N,Nʹ-dioxide-scandium(III) complex-promoted asymmetric tandem Friedel-Crafts alkylation/intermolecular macrolactonization of ortho-quinone methides with C3-substituted indoles. This protocol provides an array...


2020 ◽  
Vol 56 (3) ◽  
pp. 439-442 ◽  
Author(s):  
Yong You ◽  
Ting-Ting Li ◽  
Shu-Pei Yuan ◽  
Ke-Xin Xie ◽  
Zhen-Hua Wang ◽  
...  

An asymmetric [4+2] cycloaddition of 1-((2-aryl)vinyl)naphthalen-2-ols with in situ generated ortho-quinone methides enables the highly enantioselective synthesis of polysubstituted chromanes.


2019 ◽  
Vol 361 (6) ◽  
pp. 1241-1246 ◽  
Author(s):  
Gong‐Bin Huang ◽  
Wei‐Hua Huang ◽  
Jing Guo ◽  
Dong‐Liang Xu ◽  
Xiao‐Chen Qu ◽  
...  

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