Hydrosilylation of Aldehydes and Ketones Catalyzed by an N-Heterocyclic Carbene-Nickel Hydride Complex under Mild Conditions

2012 ◽  
Vol 354 (14-15) ◽  
pp. 2619-2624 ◽  
Author(s):  
Linus P. Bheeter ◽  
Mickaël Henrion ◽  
Lydia Brelot ◽  
Christophe Darcel ◽  
Michael J. Chetcuti ◽  
...  
Keyword(s):  
Hydride Complex ◽  
Mild Conditions ◽  
Nickel Hydride ◽  
Aldehydes And Ketones

ChemInform Abstract: Hydrosilylation of Aldehydes and Ketones Catalyzed by an N-Heterocyclic Carbene-Nickel Hydride Complex under Mild Conditions.

ChemInform ◽  
2013 ◽  
Vol 44 (14) ◽  
pp. no-no
Author(s):  
Linus P. Bheeter ◽  
Mickael Henrion ◽  
Lydia Brelot ◽  
Christophe Darcel ◽  
Michael J. Chetcuti ◽  
...  
Keyword(s):  
Hydride Complex ◽  
Mild Conditions ◽  
Nickel Hydride ◽  
Aldehydes And Ketones

Ketone hydrogenation catalyzed by a new iron(ii)–PNN complex

2016 ◽  
Vol 6 (12) ◽  
pp. 4428-4437 ◽  
Author(s):  
B. Butschke ◽  
M. Feller ◽  
Y. Diskin-Posner ◽  
D. Milstein
Keyword(s):  
Hydride Complex ◽  
Mild Conditions ◽  
Ketone Hydrogenation ◽  
Proton Migration

A dearomatized Fe(ii)–hydride complex mediates the hydrogenation of enolizable ketones under very mild conditions. Deactivation occursviaintramolecular proton migration.

scholarly journals Improved hydrogen storage properties of Mg/MgH2 thanks to the addition of nickel hydride complex precursors

2019 ◽  
Vol 44 (54) ◽  
pp. 28848-28862 ◽  
Author(s):  
Basile Galey ◽  
Aline Auroux ◽  
Sylviane Sabo-Etienne ◽  
Sameh Dhaher ◽  
Mary Grellier ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Hydrogen Storage Properties ◽  
Hydride Complex ◽  
Nickel Hydride ◽  
Storage Properties

Dehydrogenative Coupling of Aldehydes with Alcohols Catalyzed by a Nickel Hydride Complex

2019 ◽  
Vol 38 (7) ◽  
pp. 1468-1478 ◽  
Author(s):  
Nathan A. Eberhardt ◽  
Nadeesha P. N. Wellala ◽  
Yingze Li ◽  
Jeanette A. Krause ◽  
Hairong Guan
Keyword(s):  
Hydride Complex ◽  
Nickel Hydride ◽  
Dehydrogenative Coupling

α-Chymotrypsin-Induced Acetalization of Aldehydes and Ketones with Alcohols

Synthesis ◽  
2020 ◽  
Vol 52 (14) ◽  
pp. 2121-2126
Author(s):  
Zhanggao Le ◽  
Zongbo Xie ◽  
Jin Lan ◽  
Guofang Jiang ◽  
Jiangnan Yang ◽  
...  
Keyword(s):  
Catalytic Amount ◽  
First Report ◽  
Mild Conditions ◽  
Aldehydes And Ketones ◽  
Neutral Conditions ◽  
Induced Reaction ◽  
General Method

This is the first report of a simple and general method for acetalization­ of aldehydes via an α-chymotrypsin-induced reaction under mild conditions. A broad range of aromatic and heteroaromatic aldehydes have been acetalized under neutral conditions in good yields using a catalytic amount of chymotrypsin.

A Nickel Hydride Complex in the Active Site of Methyl-Coenzyme M Reductase: Implications for the Catalytic Cycle

2008 ◽  
Vol 130 (33) ◽  
pp. 10907-10920 ◽  
Author(s):  
Jeffrey Harmer ◽  
Cinzia Finazzo ◽  
Rafal Piskorski ◽  
Sieglinde Ebner ◽  
Evert C. Duin ◽  
...  
Keyword(s):  
Active Site ◽  
Catalytic Cycle ◽  
Coenzyme M ◽  
Hydride Complex ◽  
Nickel Hydride ◽  
Methyl Coenzyme M Reductase

The Reductive Amination of Aldehydes and Ketones by Catalytic Use of Dibutylchlorotin Hydride Complex.

ChemInform ◽  
2007 ◽  
Vol 38 (8) ◽  
Author(s):  
Hirofumi Kato ◽  
Ikuya Shibata ◽  
Yuta Yasaka ◽  
Shinji Tsunoi ◽  
Makoto Yasuda ◽  
...  
Keyword(s):  
Reductive Amination ◽  
Hydride Complex ◽  
Aldehydes And Ketones
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