Reductive Reformatsky-Honda Reaction of α,β-Unsaturated Esters: Facile Formation of 1,3-Dicarbonyl Compounds and β-Hydroxy Esters

2012 ◽  
Vol 354 (2-3) ◽  
pp. 510-514 ◽  
Author(s):  
Kazuyuki Sato ◽  
Motoyuki Isoda ◽  
Shizuka Ohata ◽  
Shuhei Morita ◽  
Atsushi Tarui ◽  
...  
Keyword(s):  
Dicarbonyl Compounds ◽  
Unsaturated Esters ◽  
Hydroxy Esters

ChemInform Abstract: Reductive Reformatsky-Honda Reaction of α,β-Unsaturated Esters: Facile Formation of 1,3-Dicarbonyl Compounds and β-Hydroxy Esters.

ChemInform ◽  
2012 ◽  
Vol 43 (26) ◽  
pp. no-no
Author(s):  
Kazuyuki Sato ◽  
Motoyuki Isoda ◽  
Shizuka Ohata ◽  
Shuhei Morita ◽  
Atsushi Tarui ◽  
...  
Keyword(s):  
Dicarbonyl Compounds ◽  
Unsaturated Esters ◽  
Hydroxy Esters

Thiol esters in organic synthesis. X. A new approach to 1,5-ketols and 5-hydroxy esters using S,S'-diethyl dithiomalonate as an ethanol carbanion equivalent

1982 ◽  
Vol 60 (1) ◽  
pp. 94-96 ◽  
Author(s):  
Hsing-Jang Liu ◽  
Isaac V. Oppong
Keyword(s):  
Organic Synthesis ◽  
Raney Nickel ◽  
Michael Addition ◽  
New Approach ◽  
Unsaturated Esters ◽  
Thiol Esters ◽  
Hydroxy Esters

Michael addition of S,S′-diethyl dithiomalonate to conjugated enones and α,β-unsaturated esters followed by reduction with Raney nickel gave rise to 1,5-ketols and 5-hydroxy esters respectively in good yields.

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