Rhodium-Catalyzed, Three-Component Reaction of Diazo Compounds with Amines and Azodicarboxylates

2005 ◽  
Vol 347 (4) ◽  
pp. 531-534 ◽  
Author(s):  
Haoxi Huang ◽  
Yuanhua Wang ◽  
Zhiyong Chen ◽  
Wenhao Hu
Keyword(s):  
Diazo Compounds ◽  
Three Component Reaction

Palladium‐Catalyzed Three‐Component Reaction of Allenes, Aryl Iodides, and Diazo Compounds: Approach to 1,3‐Dienes

2013 ◽  
Vol 125 (35) ◽  
pp. 9475-9478 ◽  
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  
Keyword(s):  
Diazo Compounds ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed

Ag(I)-Catalyzed Three-Component Reaction of 2-Alkynylbenzaldehydes, Amines, and Diazo Compounds

2015 ◽  
Vol 17 (17) ◽  
pp. 4332-4335 ◽  
Author(s):  
Tiebo Xiao ◽  
Pai Peng ◽  
Yang Xie ◽  
Zhao-yang Wang ◽  
Lei Zhou
Keyword(s):  
Diazo Compounds ◽  
Three Component Reaction

Palladium-Catalyzed Three-Component Reaction of Allenes, Aryl Iodides, and Diazo Compounds: Approach to 1,3-Dienes

2013 ◽  
Vol 52 (35) ◽  
pp. 9305-9308 ◽  
Author(s):  
Qing Xiao ◽  
Binglong Wang ◽  
Leiming Tian ◽  
Yang Yang ◽  
Jian Ma ◽  
...  
Keyword(s):  
Diazo Compounds ◽  
Aryl Iodides ◽  
Three Component Reaction ◽  
Palladium Catalyzed

scholarly journals Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates

2019 ◽  
Author(s):  
Masaaki Komatsuda ◽  
Hiroki Kato ◽  
Kei Muto ◽  
Junichiro Yamaguchi
Keyword(s):  
Diazo Compound ◽  
Diazo Compounds ◽  
Reaction Conditions ◽  
Three Component Reaction

Acatalytic dearomative three-component reaction of bromoarenes with TMS-diazomethane and allyl borate was developed. The key of this assembling reaction is the use of a diazo compound to generate a Pd-π-benzyl intermediate through a Pd-carbenoid species. This method allowed for a dearomative functionalization using arenes as limiting reagents. Heteroaryl bromides were also applicable to give dearomatized structures under the reaction conditions.

Highly diastereoselective synthesis of vicinal diamines via Rh-catalyzed three-component reaction of diazo compounds with diarylmethanimines and ketimines

2021 ◽  
Author(s):  
Kai Zhou ◽  
Ming Bao ◽  
Hong-Kai Sha ◽  
Guizhi Dong ◽  
Kemiao Hong ◽  
...  
Keyword(s):  
Diazo Compounds ◽  
Diastereoselective Synthesis ◽  
Three Component Reaction ◽  
Vicinal Diamines ◽  
Convenient Access

A Rh-catalyzed diastereoselective three-component reaction of diazo compounds with diarylmethanimines and ketimines has been reported, which offers an efficient and convenient access to furnish vicinal diamine derivatives with two tertiary...

Pd-Catalyzed Dearomative Three-Component Reaction of Bromoarenes with Diazo Compounds and Allylborates

2019 ◽  
Author(s):  
Masaaki Komatsuda ◽  
Hiroki Kato ◽  
Kei Muto ◽  
Junichiro Yamaguchi
Keyword(s):  
Diazo Compound ◽  
Diazo Compounds ◽  
Reaction Conditions ◽  
Three Component Reaction

Acatalytic dearomative three-component reaction of bromoarenes with TMS-diazomethane and allyl borate was developed. The key of this assembling reaction is the use of a diazo compound to generate a Pd-π-benzyl intermediate through a Pd-carbenoid species. This method allowed for a dearomative functionalization using arenes as limiting reagents. Heteroaryl bromides were also applicable to give dearomatized structures under the reaction conditions.

Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

2017 ◽  
Vol 4 (4) ◽  
pp. 529-533 ◽  
Author(s):  
Jun Huang ◽  
Linyong Li ◽  
Haoguo Chen ◽  
Tiebo Xiao ◽  
Yuwei He ◽  
...  
Keyword(s):  
Nitrogen Source ◽  
New Method ◽  
Diazo Compounds ◽  
Three Component Reaction

A silver-catalyzed three-component reaction of diazoketones, anilines and NFSI is developed. The reaction provides a new method for gem-aminofluorination of acceptor diazo compounds with aniline as the nitrogen source and NFSI as the fluorine source.

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