scholarly journals Perovskite/Metal‐Based Hyperbolic Metamaterials: Tailoring the Permittivity Properties of Coexisting Anisotropies in the Visible Region (Advanced Optical Materials 1/2021)

2021 ◽  
Vol 9 (1) ◽  
pp. 2170004
Author(s):  
Supratim Basak ◽  
Ofer Bar‐On ◽  
Jacob Scheuer
2020 ◽  
Vol 28 (2) ◽  
pp. 1507 ◽  
Author(s):  
Rahul Kumar ◽  
Kotaro Kajikawa

2016 ◽  
Vol 4 (11) ◽  
pp. 1659-1659 ◽  
Author(s):  
Kandammathe Valiyaveedu Sreekanth ◽  
Yunus Alapan ◽  
Mohamed ElKabbash ◽  
Amy M. Wen ◽  
Efe Ilker ◽  
...  

2021 ◽  
Vol 9 (7) ◽  
pp. 2170024
Author(s):  
Irdi Murataj ◽  
Marwan Channab ◽  
Eleonora Cara ◽  
Candido F. Pirri ◽  
Luca Boarino ◽  
...  

2021 ◽  
Vol 9 (9) ◽  
pp. 2170031
Author(s):  
Arrigo Calzolari ◽  
Alessandra Catellani ◽  
Marco Buongiorno Nardelli ◽  
Marco Fornari

2019 ◽  
Vol 7 (14) ◽  
pp. 1970054 ◽  
Author(s):  
Pengcheng Huo ◽  
Si Zhang ◽  
Yuzhang Liang ◽  
Yanqing Lu ◽  
Ting Xu

2021 ◽  
Vol 8 (8) ◽  
pp. 210570
Author(s):  
Muhammad Khalid ◽  
Muhammad Usman Khan ◽  
Iqra Shafiq ◽  
Riaz Hussain ◽  
Akbar Ali ◽  
...  

A donor–π–acceptor type series of Triphenylamine–dicyanovinylene-based chromophores ( DPMN1–DPMN11 ) was designed theoretically by the structural tailoring of π-linkers of experimentally synthesized molecules DTTh and DTTz to exploit changes in the optical properties and their nonlinear optical materials (NLO) behaviour. Density functional theory (DFT) computations were employed to understand the electronic structures, absorption spectra, charge transfer phenomena and the influence of these structural modifications on NLO properties. Interestingly, all investigated chromophores exhibited lower band gap (2.22–2.60 eV) with broad absorption spectra in the visible region, reflecting the remarkable NLO response. Furthermore, natural bond orbital (NBO) findings revealed a strong push–pull mechanism in DPMN1–DPMN11 as donor and π-conjugates exhibited positive, while all acceptors showed negative values. Examination of electronic transitions from donor to acceptor moieties via π-conjugated linkers revealed greater linear (〈 α 〉 = 526.536–641.756 a.u.) and nonlinear ( β tot = 51 313.8–314 412.661 a.u.) response. It was noted that the chromophores containing imidazole in the second p-linker expressed greater hyperpolarizability when compared with the ones containing pyrrole. This study reveals that by controlling the type of π-spacers, interesting metal-free NLO materials can be designed, which can be valuable for the hi-tech NLO applications.


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