Backbone‐Acceptor/Pendant‐Donor Strategy for Efficient Thermally Activated Delayed Fluorescence Conjugated Polymers with External Quantum Efficiency Close to 25% and Emission Peak at 608 nm

2021 ◽  
pp. 2001981
Author(s):  
Tao Wang ◽  
Bing Yao ◽  
Kuofei Li ◽  
Yuannan Chen ◽  
Hongmei Zhan ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Delayed Fluorescence ◽  
Emission Peak ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

scholarly journals Red to orange thermally activated delayed fluorescence polymers based on 2-(4-(diphenylamino)-phenyl)-9H-thioxanthen-9-one-10,10-dioxide for efficient solution-processed OLEDs

RSC Advances ◽  
2021 ◽  
Vol 11 (40) ◽  
pp. 24794-24806
Author(s):  
Praetip Khammultri ◽  
Pongsakorn Chasing ◽  
Chirawat Chitpakdee ◽  
Supawadee Namuangruk ◽  
Taweesak Sudyoadsuk ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Current Efficiency ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Efficient Solution ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Maximum Current ◽  
Orange Color

TADF conjugated polymers having 2-(4-(diphenylamino)-phenyl)-9H-thioxanthen-9-one-10,10-dioxide as a TADF unit showed red/orange color emissions and enabled OLED devices with a maximum external quantum efficiency of 10.44% and a maximum current efficiency of 14.97 cd A−1

Bright white electroluminescence from a single polymer containing a thermally activated delayed fluorescence unit and a solution-processed orange OLED approaching 20% external quantum efficiency

2017 ◽  
Vol 5 (41) ◽  
pp. 10715-10720 ◽  
Author(s):  
Yanjie Wang ◽  
Yunhui Zhu ◽  
Guohua Xie ◽  
Hongmei Zhan ◽  
Chuluo Yang ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Delayed Fluorescence ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
White Electroluminescence

Efficient white and orange emissions have been achieved in doped OLEDs using TADF conjugated polymers with a backbone-donor/pendant-acceptor architecture.

Over 20% external quantum efficiency in red thermally activated delayed fluorescence organic light-emitting diodes using a reverse intersystem crossing activating host

2018 ◽  
Vol 6 (20) ◽  
pp. 5363-5368 ◽  
Author(s):  
Ji Han Kim ◽  
Dong Ryun Lee ◽  
Si Hyun Han ◽  
Jun Yeob Lee
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Light Emitting Diodes ◽  
Delayed Fluorescence ◽  
Organic Light Emitting Diodes ◽  
Intersystem Crossing ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Organic Light

Highly efficient red thermally activated delayed fluorescence organic light-emitting diodes were developed using a reverse intersystem crossing activating host derived from phenylcarbazole and pyridofuropyridine.

High efficiency pure blue thermally activated delayed fluorescence molecules having 10H-phenoxaborin and acridan units

2015 ◽  
Vol 51 (46) ◽  
pp. 9443-9446 ◽  
Author(s):  
Masaki Numata ◽  
Takuma Yasuda ◽  
Chihaya Adachi
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
New Materials ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

New materials emitting pure blue thermally activated delayed fluorescence achieve 20% external quantum efficiency and exhibit nearly concentration-independent photoluminescence.

Benzothienopyrimidine as a co-planar type rigid acceptor for high external quantum efficiency in thermally activated delayed fluorescence emitters

2019 ◽  
Vol 7 (25) ◽  
pp. 7643-7653 ◽  
Author(s):  
Chan Seok Oh ◽  
Ha Lim Lee ◽  
Wan Pyo Hong ◽  
Jun Yeob Lee
Keyword(s):  
Hydrogen Bonding ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
Planar Structure ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

Thermally activated delayed fluorescence (TADF) emitters based on a new benzothienopyrimidine acceptor, which is rigid and can form a co-planar structure via hydrogen bonding, were developed as high-efficiency TADF emitters.

scholarly journals Thermally activated delayed fluorescence with 7% external quantum efficiency from a light-emitting electrochemical cell

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Petter Lundberg ◽  
Youichi Tsuchiya ◽  
E. Mattias Lindh ◽  
Shi Tang ◽  
Chihaya Adachi ◽  
...  
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Active Material ◽  
Fluorescence Emission ◽  
Single Layer ◽  
Delayed Fluorescence ◽  
Electrochemical Cells ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated

AbstractWe report on light-emitting electrochemical cells, comprising a solution-processed single-layer active material and air-stabile electrodes, that exhibit efficient and bright thermally activated delayed fluorescence. Our optimized devices delivers a luminance of 120 cd m−2 at an external quantum efficiency of 7.0%. As such, it outperforms the combined luminance/efficiency state-of-the art for thermally activated delayed fluorescence light-emitting electrochemical cells by one order of magnitude. For this end, we employed a polymeric blend host for balanced electrochemical doping and electronic transport as well as uniform film formation, an optimized concentration (<1 mass%) of guest for complete host-to-guest energy transfer at minimized aggregation and efficient emission, and an appropriate concentration of an electrochemically stabile electrolyte for desired doping effects. The generic nature of our approach is manifested in the attainment of bright and efficient thermally activated delayed fluorescence emission from three different light-emitting electrochemical cells with invariant host:guest:electrolyte number ratio.

scholarly journals Realizing 20% External Quantum Efficiency in Electroluminescence with Efficient Thermally Activated Delayed Fluorescence from an Exciplex

2019 ◽  
Vol 11 (14) ◽  
pp. 13460-13471 ◽  
Author(s):  
Marian Chapran ◽  
Piotr Pander ◽  
Marharyta Vasylieva ◽  
Gabriela Wiosna-Salyga ◽  
Jacek Ulanski ◽  
...  
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

A novel molecular design employing a backbone freezing linker for improved efficiency, sharpened emission and long lifetime in thermally activated delayed fluorescence emitters

2019 ◽  
Vol 7 (10) ◽  
pp. 2919-2926 ◽  
Author(s):  
Ji Gwang Yu ◽  
Si Hyun Han ◽  
Ha Lim Lee ◽  
Wan Pyo Hong ◽  
Jun Yeob Lee
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Molecular Design ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Emission Profile ◽  
Thermally Activated ◽  
Long Lifetime ◽  
Backbone Structure

A novel molecular design employing a backbone structure freezing linker was developed to improve the external quantum efficiency, lifetime and emission profile of thermally activated delayed fluorescence (TADF) emitters.

Asymmetric-triazine-cored triads as thermally activated delayed fluorescence emitters for high-efficiency yellow OLEDs with slow efficiency roll-off

2016 ◽  
Vol 4 (42) ◽  
pp. 9998-10004 ◽  
Author(s):  
Yepeng Xiang ◽  
Shaolong Gong ◽  
Yongbiao Zhao ◽  
Xiaojun Yin ◽  
Jiajia Luo ◽  
...  
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
High Luminance ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
First Time

Two asymmetric-triazine triads are demonstrated for the first time as yellow TADF emitters exhibiting a peak external quantum efficiency of 13.0% and an ultra-slow efficiency roll-off of 11.5% at high luminance.

Sign in / Sign up

Export Citation Format

Share Document