Donor and Acceptor Fused 16,16‐Dimethyl‐11,16‐dihydrodibenzo[2,3:5,6]pyrrolizino[1,7‐ ab ]acridine as a Blue‐Emitting Chromophore for High External Quantum Efficiency and Long Lifetime

2020 ◽  
Vol 8 (17) ◽  
pp. 2000480
Author(s):  
Vilas Venunath Patil ◽  
Kyung Hyung Lee ◽  
Jun Yeob Lee
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Donor And Acceptor ◽  
Long Lifetime

A novel molecular design employing a backbone freezing linker for improved efficiency, sharpened emission and long lifetime in thermally activated delayed fluorescence emitters

2019 ◽  
Vol 7 (10) ◽  
pp. 2919-2926 ◽  
Author(s):  
Ji Gwang Yu ◽  
Si Hyun Han ◽  
Ha Lim Lee ◽  
Wan Pyo Hong ◽  
Jun Yeob Lee
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Molecular Design ◽  
Delayed Fluorescence ◽  
Thermally Activated Delayed Fluorescence ◽  
Emission Profile ◽  
Thermally Activated ◽  
Long Lifetime ◽  
Backbone Structure

A novel molecular design employing a backbone structure freezing linker was developed to improve the external quantum efficiency, lifetime and emission profile of thermally activated delayed fluorescence (TADF) emitters.

Demonstration of ultra-small (0.2%) for mini-displays

2020 ◽  
Vol 14 (1) ◽  
pp. 011004
Author(s):  
Shubhra S. Pasayat ◽  
Chirag Gupta ◽  
Matthew S. Wong ◽  
Ryan Ley ◽  
Michael J. Gordon ◽  
...  
Keyword(s):  
Quantum Efficiency ◽  
External Quantum Efficiency

scholarly journals Phenylalkylammonium passivation enables perovskite light emitting diodes with record high-radiance operational lifetime: the chain length matters

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yuwei Guo ◽  
Sofia Apergi ◽  
Nan Li ◽  
Mengyu Chen ◽  
Chunyang Yin ◽  
...  
Keyword(s):  
Chain Length ◽  
Quantum Efficiency ◽  
External Quantum Efficiency ◽  
Light Emitting Diodes ◽  
Surface Defects ◽  
Theoretical Modelling ◽  
Ion Migration ◽  
Light Emitting ◽  
Operational Lifetime ◽  
Chain Lengths

AbstractPerovskite light emitting diodes suffer from poor operational stability, exhibiting a rapid decay of external quantum efficiency within minutes to hours after turn-on. To address this issue, we explore surface treatment of perovskite films with phenylalkylammonium iodide molecules of varying alkyl chain lengths. Combining experimental characterization and theoretical modelling, we show that these molecules stabilize the perovskite through suppression of iodide ion migration. The stabilization effect is enhanced with increasing chain length due to the stronger binding of the molecules with the perovskite surface, as well as the increased steric hindrance to reconfiguration for accommodating ion migration. The passivation also reduces the surface defects, resulting in a high radiance and delayed roll-off of external quantum efficiency. Using the optimized passivation molecule, phenylpropylammonium iodide, we achieve devices with an efficiency of 17.5%, a radiance of 1282.8 W sr−1 m−2 and a record T50 half-lifetime of 130 h under 100 mA cm−2.

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