Highly Luminescent Cesium Lead Halide Perovskite Nanocrystals Stabilized in Glasses for Light‐Emitting Applications

2019 ◽  
Vol 7 (9) ◽  
pp. 1801663 ◽  
Author(s):  
Ying Ye ◽  
Wenchao Zhang ◽  
Zhiyong Zhao ◽  
Jing Wang ◽  
Chao Liu ◽  
...  
2019 ◽  
Vol 11 (24) ◽  
pp. 21655-21660 ◽  
Author(s):  
Stefan T. Ochsenbein ◽  
Franziska Krieg ◽  
Yevhen Shynkarenko ◽  
Gabriele Rainò ◽  
Maksym V. Kovalenko

Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1751 ◽  
Author(s):  
Chen Chen ◽  
Louwen Zhang ◽  
Tielin Shi ◽  
Guanglan Liao ◽  
Zirong Tang

All inorganic cesium lead halide (CsPbX3, X = Cl, Br, I) perovskite nanocrystals (PNCs) exhibit promising applications in light-emitting devices due to their excellent photophysical properties. Herein, we developed a low-cost and convenient method for the preparation of CsPbX3 PNCs in a multiligand-assisted reaction system where peanut oil is applied as a ligand source. The mixed-halide PNCs with tunable optical-band gap were prepared by mixing the single-halide perovskite solutions at room temperature. The resulting PNCs had good monodispersity, with dimensions of 8–10 nm, high photoluminescence quantum yield (96.9%), narrow emission widths (15–34 nm), and tunable emission wavelength (408–694 nm), covering the entire visible spectrum. Additionally, various morphologies of PNCs, such as nanospheres, nanocubes, and nanowires, were obtained by controlling reaction temperature and time, and the amount of oleamine with multiple ligands in peanut oil potentially playing a dominant role in the nucleation/growth processes of our PNCs. Finally, the resulting CsPbBr3 PNCs were employed to develop a white light-emitting diode (WLED), demonstrating the potential lighting applications for our method.


2020 ◽  
Vol MA2020-02 (42) ◽  
pp. 2721-2721
Author(s):  
Tongtong Xuan ◽  
Tianliang Zhou ◽  
Jing Wang ◽  
Rong-Jun Xie

Molecules ◽  
2020 ◽  
Vol 25 (5) ◽  
pp. 1151 ◽  
Author(s):  
Jinlei Zhang ◽  
Jiuyang He ◽  
Lun Yang ◽  
Zhixing Gan

Despite intensive efforts, the fluorescence of perovskite nanocrystals (NCs) still suffers from a poor color purity, which limits the applications in light emitting and multicolor display. A deep understanding on the fundamental of the photoluminescent (PL) spectral broadening is thus of great significance. Herein, the PL decay curves of the CsPbClxBr3-x NCs are monitored at different wavelengths covering the entire PL band. Moreover, energy relaxation time τ and radiative recombination time β are obtained by numerical fittings. The dependences of τ and 1/β on the detection wavelength agree well with the steady-state PL spectrum, indicating the observed PL broadening is an intrinsic effect due to the resonance and off-resonance exciton radiative recombination processes. This work not only provides a new analysis method for time-resolved PL spectra of perovskites, but also gains a deep insight into the spectral broadening of the lead halide perovskite NCs.


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