Cationic Polyelectrolyte Bridged Boron Nitride Microplatelet Based Poly(vinyl alcohol) Composite: A Novel Method toward High Thermal Conductivity

2019 ◽  
Vol 6 (17) ◽  
pp. 1900787 ◽  
Author(s):  
Huayuan Li ◽  
Yuan Gao ◽  
Pengli Zhu ◽  
Xiaomeng Du ◽  
Xuecheng Yu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Boron Nitride ◽  
Vinyl Alcohol ◽  
Cationic Polyelectrolyte ◽  
High Thermal Conductivity ◽  
Poly Vinyl Alcohol ◽  
Novel Method

Anisotropy-Driven High Thermal Conductivity in Stretchable Poly(vinyl alcohol)/Hexagonal Boron Nitride Nanohybrid Films

2018 ◽  
Vol 10 (40) ◽  
pp. 34625-34633 ◽  
Author(s):  
O. Hwan Kwon ◽  
Taeyong Ha ◽  
Dong-Gyun Kim ◽  
Byoung Gak Kim ◽  
Yong Seok Kim ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Boron Nitride ◽  
Vinyl Alcohol ◽  
Hexagonal Boron Nitride ◽  
High Thermal Conductivity ◽  
Poly Vinyl Alcohol

scholarly journals Hexagonal Boron Nitride/Microfibril Cellulose/Poly(vinyl alcohol) Ternary Composite Film with Thermal Conductivity and Flexibility

Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 104 ◽  
Author(s):  
Xin Ge ◽  
Wei-Jie Liang ◽  
Jian-Fang Ge ◽  
Xun-Jun Chen ◽  
Jian-Ye Ji ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Boron Nitride ◽  
Composite Film ◽  
Photoelectron Spectroscopy ◽  
Vinyl Alcohol ◽  
Hexagonal Boron Nitride ◽  
Poly Vinyl Alcohol ◽  
Thermal Interface Materials ◽  
Binding Effect ◽  
Ft Ir

Microfibril cellulose (MFC), which is detrimental to soil cultivation and environmental protection, is derived from waste pineapple leaves. Hexagonal boron nitride (h-BN) was modified with polydopamine (PDA)—PDA@h-BN named pBN, and then combined with MFC to prepare a novel hybrid powder. The effect of PDA on h-BN and the binding effect between pBN and MFC were characterized by X-ray photoelectron spectroscopy (XPS), Thermogravimetric (TG), scanning electron microscopy (SEM), and Fourier Transform-Infrared (FT-IR). Poly (vinyl alcohol) (PVA) was used as an eco-friendly polymeric matrix to prepare a pBN-MFC-PVA composite film. The mechanical strength, hydrophobicity, and thermal conductivity of the film were studied and the results confirmed that h-BN was chemically modified with PDA and was uniformly distributed along the MFC. The thermal conductivity of the pBN-MFC-PVA composite film increased with the addition of a pBN-MFC novel powder. MFC acted as “guides” to mitigate the h-BN agglomerate. In addition to the possible usage in the pBN-MFC-PVA composite film itself, the pBN-MFC hybrid powder may be a potential filler candidate for manufacturing thermal interface materials and wearable devices or protective materials.

scholarly journals Incorporating MXene into Boron Nitride/Poly(Vinyl Alcohol) Composite Films to Enhance Thermal and Mechanical Properties

Polymers ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 379
Author(s):  
Seonmin Lee ◽  
Jooheon Kim
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Boron Nitride ◽  
Composite Film ◽  
Vinyl Alcohol ◽  
Composite Films ◽  
Poly Vinyl Alcohol ◽  
Thermal And Mechanical Properties ◽  
Conduction Path ◽  
Thermally Conductive

Aggregated boron nitride (ABN) is advantageous for increasing the packing and thermal conductivity of the matrix in composite materials, but can deteriorate the mechanical properties by breaking during processing. In addition, there are few studies on the use of Ti3C2 MXene as thermally conductive fillers. Herein, the development of a novel composite film is described. It incorporates MXene and ABN into poly(vinyl alcohol) (PVA) to achieve a high thermal conductivity. Polysilazane (PSZ)-coated ABN formed a heat conduction path in the composite film, and MXene supported it to further improve the thermal conductivity. The prepared polymer composite film is shown to provide through-plane and in-plane thermal conductivities of 1.51 and 4.28 W/mK at total filler contents of 44 wt.%. The composite film is also shown to exhibit a tensile strength of 11.96 MPa, which is much greater than that without MXene. Thus, it demonstrates that incorporating MXene as a thermally conductive filler can enhance the thermal and mechanical properties of composite films.

scholarly journals A Novel Method to Prepare Transparent, Flexible and Thermally Conductive Polyethylene/Boron Nitride Films

Nanomaterials ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 111
Author(s):  
Mingming Yi ◽  
Meng Han ◽  
Junlin Chen ◽  
Zhifeng Hao ◽  
Yuanzhou Chen ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Boron Nitride ◽  
Thermal Management ◽  
Self Assembly ◽  
High Performance ◽  
High Thermal Conductivity ◽  
Polyethylene Film ◽  
High Concentration ◽  
Thermally Conductive ◽  
Novel Method

The high thermal conductivity and good insulating properties of boron nitride (BN) make it a promising filler for high-performance polymer-based thermal management materials. An easy way to prepare BN-polymer composites is to directly mix BN particles with polymer matrix. However, a high concentration of fillers usually leads to a huge reduction of mechanical strength and optical transmission. Here, we propose a novel method to prepare polyethylene/boron nitride nanoplates (PE/BNNPs) composites through the combination of electrostatic self-assembly and hot pressing. Through this method, the thermal conductivity of the PE/BNNPs composites reach 0.47 W/mK, which gets a 14.6% improvement compared to pure polyethylene film. Thanks to the tight bonding of polyethylene with BNNPs, the tensile strength of the composite film reaches 1.82 MPa, an increase of 173.58% compared to that of pure polyethylene film (0.66 MPa). The fracture stress was also highly enhanced, with an increase of 148.44% compared to pure polyethylene film. Moreover, the addition of BNNPs in PE does not highly reduce its good transmittance, which is preferred for thermal management in devices like light-emitting diodes. This work gives an insight into the preparation strategy of transparent and flexible thermal management materials with high thermal conductivity.

Porous boron nitride nanofibers as effective nanofillers for poly(vinyl alcohol) composite hydrogels with excellent self-healing performances

Soft Matter ◽  
2022 ◽  
Author(s):  
Xiangqian Gao ◽  
Tiantian Deng ◽  
Xindi Huang ◽  
Mengmeng Yu ◽  
Danyang Li ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Vinyl Alcohol ◽  
Poly Vinyl Alcohol ◽  
Self Healing ◽  
One Pot ◽  
One Dimensional ◽  
Composite Hydrogels ◽  
Assembly Method

A new composite hydrogels with excellent self-healing properties was prepared by combining poly(vinyl alcohol) (PVA) and boron nitride nanofibers (BNNFs) via a facile one-pot assembly method. One-dimensional porous BNNFs with...

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