Strong Surface Bonding of Polysulfides by Teflonized Carbon Matrix for Enhanced Performance in Room Temperature Sodium‐Sulfur Battery

2019 ◽  
Vol 6 (7) ◽  
pp. 1801873 ◽  
Author(s):  
Ajay Piriya Vijaya Kumar Saroja ◽  
Kamaraj Muthusamy ◽  
Ramaprabhu Sundara
Keyword(s):  
Room Temperature ◽  
Carbon Matrix ◽  
Strong Surface ◽  
Surface Bonding ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur

scholarly journals Research Progress toward Room Temperature Sodium Sulfur Batteries: A Review

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1535
Author(s):  
Yanjie Wang ◽  
Yingjie Zhang ◽  
Hongyu Cheng ◽  
Zhicong Ni ◽  
Ying Wang ◽  
...  
Keyword(s):  
Energy Storage ◽  
Room Temperature ◽  
High Energy ◽  
Safety Performance ◽  
High Energy Density ◽  
Research Progress ◽  
Storage Performance ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur

Lithium metal batteries have achieved large-scale application, but still have limitations such as poor safety performance and high cost, and limited lithium resources limit the production of lithium batteries. The construction of these devices is also hampered by limited lithium supplies. Therefore, it is particularly important to find alternative metals for lithium replacement. Sodium has the properties of rich in content, low cost and ability to provide high voltage, which makes it an ideal substitute for lithium. Sulfur-based materials have attributes of high energy density, high theoretical specific capacity and are easily oxidized. They may be used as cathodes matched with sodium anodes to form a sodium-sulfur battery. Traditional sodium-sulfur batteries are used at a temperature of about 300 °C. In order to solve problems associated with flammability, explosiveness and energy loss caused by high-temperature use conditions, most research is now focused on the development of room temperature sodium-sulfur batteries. Regardless of safety performance or energy storage performance, room temperature sodium-sulfur batteries have great potential as next-generation secondary batteries. This article summarizes the working principle and existing problems for room temperature sodium-sulfur battery, and summarizes the methods necessary to solve key scientific problems to improve the comprehensive energy storage performance of sodium-sulfur battery from four aspects: cathode, anode, electrolyte and separator.

scholarly journals High-performance room-temperature sodium–sulfur battery enabled by electrocatalytic sodium polysulfides full conversion

2020 ◽  
Vol 13 (2) ◽  
pp. 562-570 ◽  
Author(s):  
Nana Wang ◽  
Yunxiao Wang ◽  
Zhongchao Bai ◽  
Zhiwei Fang ◽  
Xiao Zhang ◽  
...  
Keyword(s):  
Energy Density ◽  
High Performance ◽  
Room Temperature ◽  
Gold Nanoclusters ◽  
High Energy ◽  
High Energy Density ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur ◽  
Full Conversion

Developing novel gold nanoclusters as an electrocatalyst can facilitate a completely reversible reaction between S and Na, achieving advanced high-energy-density room-temperature sodium–sulfur batteries.

Room-Temperature Solid-State Sodium∕Sulfur Battery

2006 ◽  
Vol 9 (3) ◽  
pp. A123 ◽  
Author(s):  
Cheol-Wan Park ◽  
Jou-Hyeon Ahn ◽  
Ho-Suk Ryu ◽  
Ki-Won Kim ◽  
Hyo-Jun Ahn
Keyword(s):  
Solid State ◽  
Room Temperature ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur

High Performance Room Temperature Sodium–Sulfur Battery by Eutectic Acceleration in Tellurium-Doped Sulfurized Polyacrylonitrile

2019 ◽  
Vol 2 (4) ◽  
pp. 2956-2964 ◽  
Author(s):  
Shuping Li ◽  
Ziqi Zeng ◽  
Jiaqiang Yang ◽  
Zhilong Han ◽  
Wei Hu ◽  
...  
Keyword(s):  
High Performance ◽  
Room Temperature ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur

scholarly journals Batteries: A High-Energy Room-Temperature Sodium-Sulfur Battery (Adv. Mater. 8/2014)

2014 ◽  
Vol 26 (8) ◽  
pp. 1308-1308 ◽  
Author(s):  
Sen Xin ◽  
Ya-Xia Yin ◽  
Yu-Guo Guo ◽  
Li-Jun Wan
Keyword(s):  
Room Temperature ◽  
High Energy ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur

scholarly journals A singular flexible cathode for room temperature sodium/sulfur battery

2016 ◽  
Vol 307 ◽  
pp. 31-37 ◽  
Author(s):  
Icpyo Kim ◽  
Chang Hyeon Kim ◽  
Sun hwa Choi ◽  
Jae-Pyoung Ahn ◽  
Jou-Hyeon Ahn ◽  
...  
Keyword(s):  
Room Temperature ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur

Stable sodium-sulfur electrochemistry enabled by phosphorus-based complexation

2021 ◽  
Vol 118 (49) ◽  
pp. e2116184118
Author(s):  
Chuanlong Wang ◽  
Yue Zhang ◽  
Yiwen Zhang ◽  
Jianmin Luo ◽  
Xiaofei Hu ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Density Functional ◽  
Room Temperature ◽  
Solid Phase ◽  
Density Functional Theory Calculations ◽  
Functional Theory ◽  
Wide Range ◽  
Sulfur Battery ◽  
Sodium Sulfur Battery ◽  
Sodium Sulfur

A series of sodium phosphorothioate complexes are shown to have electrochemical properties attractive for sodium-sulfur battery applications across a wide operating temperature range. As cathode materials, they resolve a long-standing issue of cyclic liquid–solid phase transition that causes sluggish reaction kinetics and poor cycling stability in conventional, room-temperature sodium-sulfur batteries. The cathode chemistry yields 80% cyclic retention after 400 cycles at room temperature and a superior low-temperature performance down to −60 °C. Coupled experimental characterization and density functional theory calculations revealed the complex structures and electrochemical reaction mechanisms. The desirable electrochemical properties are attributed to the ability of the complexes to prevent the formation of solid precipitates over a fairly wide range of voltage.

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