The Prediction of Carbothermal Reduction Reaction Induced Ti 4 O 7 /Ti 5 O 9 Interface Structures in Titanium Oxide Nanosystems

2018 ◽  
Vol 5 (23) ◽  
pp. 1801256 ◽  
Author(s):  
Yimin Lei ◽  
Xin Lin ◽  
Qihang Hu ◽  
Nuanyang Cui ◽  
Peng Zhong ◽  
...  
2011 ◽  
Vol 119 (1394) ◽  
pp. 740-744 ◽  
Author(s):  
Shinobu HASHIMOTO ◽  
Syuho OHASHI ◽  
Kiyoshi HIRAO ◽  
You ZHOU ◽  
Hideki HYUGA ◽  
...  

1993 ◽  
Vol 8 (6) ◽  
pp. 1428-1441 ◽  
Author(s):  
S. Jayashankar ◽  
M.J. Kaufman

MoSi2-based composites have been synthesized through the mechanical alloying (MA) of elemental molybdenum and silicon powders with and without carbon additions. The interplay between the phase formation sequence in the powders and the microstructural evolution in the consolidated samples is described. It is shown that the glassy SiO2 phase characteristic of conventional powder processed MoSi2 can be effectively eliminated by combining mechanical alloying, carbon additions, and an in situ carbothermal reduction reaction. Using this approach, composites consisting of uniformly distributed micron-size SiC in an MoSi2 matrix can be formed. The effect of important processing variables such as the extent of carbon additions, extraneous iron pickup during MA, partial pressures of oxygen, consolidation temperatures, and consolidation atmospheres is discussed based on the evidence obtained from DTA, TGA, TEM, and XRD.


2010 ◽  
Vol 146-147 ◽  
pp. 526-529
Author(s):  
Bei Yue Ma ◽  
Qiang Zhu ◽  
Yong Sun ◽  
Jing Kun Yu ◽  
Ying Li

The corundum based material was prepared, with fused white corundum, commercial SiC powder and superfine Al2O3-SiC powder synthesized from clay by carbothermal reduction reaction as raw materials. The influences of SiC and Al2O3-SiC powders on the slag penetration and corrosion resistance of the material were investigated, and the slag resistance mechanisms of the additives were also discussed. It was found that the slag resistance of the corundum material by adding Al2O3-SiC and SiC powders could be improved obviously. For improving the slag resistance of the corundum material, adding Al2O3-SiC was much better than adding commercial SiC. When the Al2O3-SiC powder contacted with the molten slag, Al2O3 in the additive could be dissolved into the molten slag immediately, while SiC remained, which caused the viscosity of molten slag to be increased. So, the slag penetration and slag corrosion into the corundum material could be effectively inhibited.


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