Atomically Dispersed Zinc(I) Active Sites to Accelerate Nitrogen Reduction Kinetics for Ammonia Electrosynthesis

2021 ◽  
pp. 2103548
Author(s):  
Yan Kong ◽  
Yan Li ◽  
Xiahan Sang ◽  
Bin Yang ◽  
Zhongjian Li ◽  
...  
Keyword(s):  
Active Sites ◽  
Reduction Kinetics ◽  
Nitrogen Reduction

Efficient N2 Reduction with VS2 Electrocatalyst: Identifying the Active Sites and Unraveling the Reaction Pathway

2021 ◽  
Author(s):  
Liang Zhao ◽  
Rui Zhao ◽  
Yixiang Zhou ◽  
Xiaoxuan Wang ◽  
Xinyue Chi ◽  
...  
Keyword(s):  
Active Sites ◽  
Reaction Pathway ◽  
Reduction Reaction ◽  
Sustainable Production ◽  
Nitrogen Reduction

Electrochemical nitrogen reduction reaction (NRR) is an effective method for sustainable production of NH3. However, a robust NRR electrocatalyst is predominantly required in order to active the inert N2 molecule....

On the mechanism of electrochemical ammonia synthesis on the Ru catalyst

2016 ◽  
Vol 18 (13) ◽  
pp. 9161-9166 ◽  
Author(s):  
Seoin Back ◽  
Yousung Jung
Keyword(s):  
Active Sites ◽  
Hydrogen Adsorption ◽  
Ammonia Synthesis ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Associative Mechanism ◽  
Ru Catalyst

The nitrogen reduction reaction (NRR) pathways involving various N–N dissociation steps are found to be comparable to the conventional associative mechanism. The competitive hydrogen adsorption and evolution is revealed to negatively affect the NRR for two reasons, an increase in NRR overpotentials as a function of partial H-coverages as well as a decreased number of active sites.

scholarly journals Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride

2019 ◽  
Vol 131 (39) ◽  
pp. 13906-13910 ◽  
Author(s):  
Xuan Yang ◽  
Shyam Kattel ◽  
Jared Nash ◽  
Xiaoxia Chang ◽  
Ji Hoon Lee ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Active Sites ◽  
Reduction Reaction ◽  
Vanadium Nitride ◽  
Nitrogen Reduction

scholarly journals Nitrogen Reduction to Ammonia on Atomic‐Scale Active Sites under Mild Conditions

Small Methods ◽  
2019 ◽  
Vol 3 (9) ◽  
pp. 1800501 ◽  
Author(s):  
Xiao Yan ◽  
Daolan Liu ◽  
Huanhuan Cao ◽  
Feng Hou ◽  
Ji Liang ◽  
...  
Keyword(s):  
Active Sites ◽  
Atomic Scale ◽  
Nitrogen Reduction ◽  
Mild Conditions

scholarly journals Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride

2019 ◽  
Vol 58 (39) ◽  
pp. 13768-13772 ◽  
Author(s):  
Xuan Yang ◽  
Shyam Kattel ◽  
Jared Nash ◽  
Xiaoxia Chang ◽  
Ji Hoon Lee ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Active Sites ◽  
Reduction Reaction ◽  
Vanadium Nitride ◽  
Nitrogen Reduction
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