scholarly journals Ferromagnetic Insulators: Room-Temperature Ferromagnetic Insulating State in Cation-Ordered Double-Perovskite Sr2 Fe1+ x Re1− x O6 Films (Adv. Mater. 4/2019)

2019 ◽  
Vol 31 (4) ◽  
pp. 1970021
Author(s):  
Changhee Sohn ◽  
Elizabeth Skoropata ◽  
Yongseong Choi ◽  
Xiang Gao ◽  
Ankur Rastogi ◽  
...  
2019 ◽  
Vol 123 (12) ◽  
Author(s):  
S. Yamada ◽  
N. Abe ◽  
H. Sagayama ◽  
K. Ogawa ◽  
T. Yamagami ◽  
...  

2019 ◽  
Vol 09 (01) ◽  
pp. 1950004 ◽  
Author(s):  
R. K. Parida ◽  
D. K. Pattanayak ◽  
Bhagyashree Mohanty ◽  
Nimai C. Nayak ◽  
B. N. Parida

The polycrystalline ceramic Pb[Formula: see text]Ba[Formula: see text]BiVO6 manifesting the complex double perovskite structure was tailored by the conventional solid state route at a moderate temperature. Qualitative phase analysis and formation of the ceramic were affirmed by XRD analysis. The X-ray powder diffraction pattern of the compound explored at room temperature affirms the single phase formation with double perovskite structure exhibiting rhombohedral phase. Microstructural analysis of the studied compound procured from the Scanning Electron Microscope (SEM) validates the formation of dense microstructures and nonuniformly distributed grains with minimal voids. Compositional analysis was shaped through the Electron Diffraction Spectroscopy (EDS) confirming the absence of contamination of any other metals apart from the mentioned ones. Dielectric (Cr and [Formula: see text]) parameters of the compound were studied using the LCR analyzer at different temperatures and wide range of frequencies. The polarization and dielectric study affirms the presence of ferroelectricity in the material with transition temperature much above the room temperature. The tangent dielectric loss of this sample being almost minimal at room temperature attributes it to find applications in different grounds of electronics. Optical equities of the ceramic were further analyzed by the RAMAN, FTIR, UV–Vis and Photoluminescence spectroscopy.


1999 ◽  
Vol 74 (12) ◽  
pp. 1737-1739 ◽  
Author(s):  
T. H. Kim ◽  
M. Uehara ◽  
S-W. Cheong ◽  
S. Lee

2012 ◽  
Vol 522 ◽  
pp. 90-95 ◽  
Author(s):  
P. Neenu Lekshmi ◽  
S. Savitha Pillai ◽  
K.G. Suresh ◽  
P.N. Santhosh ◽  
Manoj Raama Varma

ChemInform ◽  
2011 ◽  
Vol 42 (35) ◽  
pp. no-no
Author(s):  
Jaewan Chang ◽  
Kyujoon Lee ◽  
Myung Hwa Jung ◽  
Ji-Hwan Kwon ◽  
Miyoung Kim ◽  
...  

2017 ◽  
Vol 4 (11) ◽  
pp. 170920 ◽  
Author(s):  
Sameh Megdiche Borchani ◽  
Wissem Cheikh-Rouhou Koubaa ◽  
Makrem Megdiche

Structural, magnetic, magnetocaloric, electrical and magnetoresistance properties of an LaNaMnMoO 6 powder sample have been investigated by X-ray diffraction (XRD), magnetic and electrical measurements. Our sample has been synthesized using the ceramic method. Rietveld refinements of the XRD patterns show that our sample is single phase and it crystallizes in the orthorhombic structure with Pnma space group. Magnetization versus temperature in a magnetic applied field of 0.05 T shows that our sample exhibits a paramagnetic–ferromagnetic transition with decreasing temperature. The Curie temperature T C is found to be 320 K. Arrott plots show that all our double-perovskite oxides exhibit a second-order magnetic phase transition. From the measured magnetization data of an LaNaMnMoO 6 sample as a function of the magnetic applied field, the associated magnetic entropy change |−ΔSM| and the relative cooling power (RCP) have been determined. In the vicinity of T C , |−ΔSM| reached, in a magnetic applied field of 8 T, a maximum value of ∼4 J kg −1  K −1 . Our sample undergoes a large magnetocaloric effect at near-room temperature. Resistivity measurements reveal the presence of an insulating-metal transition at Tρ = 180 K. A magnetoresistance of 30% has been observed at room temperature for 6 T, significantly larger than that reported for the A 2 FeMoO 6 (A = Sr, Ba) double-perovskite system.


Author(s):  
Nhat Hoang Nam

The CaCu3Ti4O12 ceramic has been prepared by Solid State Reaction method in excess oxygen. It possesses a well-defined double-perovskite type crystalline structure and exhibits a colossal dielectric constant at around 50000 at room temperature. This paper revised the imprints of Raman spectroscopy of this compound to validate its structural characteristics and optical behaviors. A special attention is paid on the account of optical phonons which show a recognizable agreement with the other results recently reported


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