Design Principles and Synergistic Effects of Chlorination on a Conjugated Backbone for Efficient Organic Photovoltaics: A Critical Review

2020 ◽  
Vol 32 (11) ◽  
pp. 1906175 ◽  
Author(s):  
Gururaj P. Kini ◽  
Sung Jae Jeon ◽  
Doo Kyung Moon
2017 ◽  
Vol 5 (7) ◽  
pp. 1569-1585 ◽  
Author(s):  
Chuanxing Zhan ◽  
Guoqiang Yu ◽  
Yang Lu ◽  
Luyan Wang ◽  
Evan Wujcik ◽  
...  

Conductive polymer nanocomposites have found applications in advanced devices: organic light emission diodes, organic photovoltaics, electrochromic devices, and others.


2013 ◽  
Vol 14 (11) ◽  
pp. 3123-3130 ◽  
Author(s):  
Achilleas Savva ◽  
Marios Neophytou ◽  
Charalambos Koutsides ◽  
Kyriacos Kalli ◽  
Stelios A. Choulis

Author(s):  
Teresa de la Hera ◽  
Jeroen Jansz ◽  
Ruud Jacobs ◽  
Ben Schouten ◽  
Joost Raessens ◽  
...  

This chapter offers a multifaceted reflection on persuasive gaming divided into three pillars: persuasiveness, design, and validation. The first section on persuasiveness is a critical review of previous and current persuasive gaming theory and analysis. It argues that the contemporary gaming landscape needs to expand theoretically and presents a multidimensional persuasive approach as one way in which this can be done. The following section on the design of persuasive games looks at research on design principles, which are the defining characteristics of persuasive games. The final section on validation discusses existing studies on the effects of persuasive games and the case-based assessment of the impact of new games.


Joule ◽  
2017 ◽  
Vol 1 (4) ◽  
pp. 857-870 ◽  
Author(s):  
Steven A. Lopez ◽  
Benjamin Sanchez-Lengeling ◽  
Julio de Goes Soares ◽  
Alán Aspuru-Guzik

2019 ◽  
Vol 48 (6) ◽  
pp. 1596-1625 ◽  
Author(s):  
Andrew Wadsworth ◽  
Maximilian Moser ◽  
Adam Marks ◽  
Mark S. Little ◽  
Nicola Gasparini ◽  
...  

A critical analysis of the molecular design strategies employed in the recent progress of non-fullerene electron acceptors for organic photovoltaics.


Author(s):  
W.W. Adams ◽  
S. J. Krause

Rigid-rod polymers such as PBO, poly(paraphenylene benzobisoxazole), Figure 1a, are now in commercial development for use as high-performance fibers and for reinforcement at the molecular level in molecular composites. Spinning of liquid crystalline polyphosphoric acid solutions of PBO, followed by washing, drying, and tension heat treatment produces fibers which have the following properties: density of 1.59 g/cm3; tensile strength of 820 kpsi; tensile modulus of 52 Mpsi; compressive strength of 50 kpsi; they are electrically insulating; they do not absorb moisture; and they are insensitive to radiation, including ultraviolet. Since the chain modulus of PBO is estimated to be 730 GPa, the high stiffness also affords the opportunity to reinforce a flexible coil polymer at the molecular level, in analogy to a chopped fiber reinforced composite. The objectives of the molecular composite concept are to eliminate the thermal expansion coefficient mismatch between the fiber and the matrix, as occurs in conventional composites, to eliminate the interface between the fiber and the matrix, and, hopefully, to obtain synergistic effects from the exceptional stiffness of the rigid-rod molecule. These expectations have been confirmed in the case of blending rigid-rod PBZT, poly(paraphenylene benzobisthiazole), Figure 1b, with stiff-chain ABPBI, poly 2,5(6) benzimidazole, Fig. 1c A film with 30% PBZT/70% ABPBI had tensile strength 190 kpsi and tensile modulus of 13 Mpsi when solution spun from a 3% methane sulfonic acid solution into a film. The modulus, as predicted by rule of mixtures, for a film with this composition and with planar isotropic orientation, should be 16 Mpsi. The experimental value is 80% of the theoretical value indicating that the concept of a molecular composite is valid.


2021 ◽  
Author(s):  
Manuela Oliverio ◽  
Monica Nardi ◽  
Maria Luisa Di Gioia ◽  
Paola Costanzo ◽  
Sonia Bonacci ◽  
...  

Semi-synthesis is an effective strategy to obtain both natural and synthetic analogues of the olive secoiridoids, starting from easy accessible natural compounds.


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