ZnO Nanosheets Abundant in Oxygen Vacancies Derived from Metal‐Organic Frameworks for ppb‐Level Gas Sensing

2019 ◽  
Vol 31 (11) ◽  
pp. 1807161 ◽  
Author(s):  
Hongye Yuan ◽  
Saif Abdulla Ali Alateeqi Aljneibi ◽  
Jiaren Yuan ◽  
Yuxiang Wang ◽  
Hui Liu ◽  
...  
Keyword(s):  
Oxygen Vacancies ◽  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Zno Nanosheets ◽  
Metal Organic

scholarly journals Biosensors: ZnO Nanosheets Abundant in Oxygen Vacancies Derived from Metal‐Organic Frameworks for ppb‐Level Gas Sensing (Adv. Mater. 11/2019)

2019 ◽  
Vol 31 (11) ◽  
pp. 1970076 ◽  
Author(s):  
Hongye Yuan ◽  
Saif Abdulla Ali Alateeqi Aljneibi ◽  
Jiaren Yuan ◽  
Yuxiang Wang ◽  
Hui Liu ◽  
...  
Keyword(s):  
Oxygen Vacancies ◽  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Zno Nanosheets ◽  
Metal Organic

scholarly journals On the Use of MOFs and ALD Layers as Nanomembranes for the Enhancement of Gas Sensors Selectivity

Nanomaterials ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1552 ◽  
Author(s):  
Weber ◽  
Graniel ◽  
Balme ◽  
Miele ◽  
Bechelany
Keyword(s):  
Thin Films ◽  
Gas Sensors ◽  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Atomic Layer ◽  
Operational Performance ◽  
Layer Deposition ◽  
Metal Organic ◽  
Further Development ◽  
Different Gases

Improving the selectivity of gas sensors is crucial for their further development. One effective route to enhance this key property of sensors is the use of selective nanomembrane materials. This work aims to present how metal-organic frameworks (MOFs) and thin films prepared by atomic layer deposition (ALD) can be applied as nanomembranes to separate different gases, and hence improve the selectivity of gas sensing devices. First, the fundamentals of the mechanisms and configuration of gas sensors will be given. A selected list of studies will then be presented to illustrate how MOFs and ALD materials can be implemented as nanomembranes and how they can be implemented to improve the operational performance of gas sensing devices. This review comprehensively shows the benefits of these novel selective nanomaterials and opens prospects for the sensing community.

scholarly journals Curating Metal-Organic Frameworks to Compose Robust Gas Sensor Arrays in Dilute Conditions

2019 ◽  
Author(s):  
Arni Sturluson ◽  
Rachel Sousa ◽  
Yujing Zhang ◽  
Melanie T. Huynh ◽  
Caleb Laird ◽  
...  
Keyword(s):  
Sensor Array ◽  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Sensor Arrays ◽  
Gas Composition ◽  
Composition Space ◽  
The Matrix ◽  
Metal Organic ◽  
Analyte Detection ◽  
Value Decomposition

Metal-organic frameworks (MOFs)-- tunable, nano-porous materials-- are alluring recognition elements for gas sensing. Mimicking human olfaction, an array of cross-sensitive, MOF-based sensors could enable analyte detection in complex, variable gas mixtures containing confounding gas species. Herein, we address the question: given a set of MOF candidates and their adsorption properties, how do we select the optimal subset to compose a sensor array that accurately and robustly predicts the gas composition via monitoring the adsorbed mass in each MOF? We first mathematically formulate the MOF-based sensor array problem under dilute conditions. Instructively, the sensor array can be viewed as a linear map from <i>gas composition space</i> to <i>sensor array response space</i> defined by the matrix <b>H</b> of Henry coefficients of the gases in the MOFs. Characterizing this mapping, the singular value decomposition of <b>H </b>is a useful tool for evaluating MOF subsets for sensor arrays, as it determines the sensitivity of the predicted gas composition to measurement error, quantifies the magnitude of the response to changes in composition, and recovers which direction in gas composition space elicits the largest/smallest response. To illustrate, on the basis of experimental adsorption data, we curate MOFs for a sensor array with the objective of determining the concentration of CO<sub>2</sub> and SO<sub>2</sub> in the gas phase.

Hierarchical hollow ZnO cubes constructed using self-sacrificial ZIF-8 frameworks and their enhanced benzene gas-sensing properties

2015 ◽  
Vol 39 (9) ◽  
pp. 7060-7065 ◽  
Author(s):  
Wenhui Li ◽  
Xiaofeng Wu ◽  
Haidi Liu ◽  
Jiayuan Chen ◽  
Wenxiang Tang ◽  
...  
Keyword(s):  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Chemical Sensitivity ◽  
Sensing Properties ◽  
Low Concentration ◽  
Gas Sensing Properties ◽  
Metal Organic ◽  
Gaseous Benzene

Hierarchical ZnO hollow cubes constructed using Zn-based metal–organic frameworks enhance significantly chemical sensitivity towards low-concentration gaseous benzene.

Functionalization of zirconium-based metal–organic frameworks for gas sensing applications

2021 ◽  
Vol 403 ◽  
pp. 124104 ◽  
Author(s):  
Jae-Hyoung Lee ◽  
Trang Thi Thu Nguyen ◽  
Linh Ho Thuy Nguyen ◽  
Thang Bach Phan ◽  
Sang Sub Kim ◽  
...  
Keyword(s):  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Sensing Applications ◽  
Metal Organic

Metal-organic frameworks derived porous Co3O4 dodecahedeons with abundant active Co3+ for ppb-level CO gas sensing

2020 ◽  
Vol 506 ◽  
pp. 144900 ◽  
Author(s):  
Cong Qin ◽  
Bing Wang ◽  
Nan Wu ◽  
Cheng Han ◽  
Chunzhi Wu ◽  
...  
Keyword(s):  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Co Gas

scholarly journals Gas Sensing Properties of Mg-Incorporated Metal–Organic Frameworks

Sensors ◽  
2019 ◽  
Vol 19 (15) ◽  
pp. 3323 ◽  
Author(s):  
Jae-Hyoung Lee ◽  
Thanh-Binh Nguyen ◽  
Duy-Khoi Nguyen ◽  
Jae-Hun Kim ◽  
Jin-Young Kim ◽  
...  
Keyword(s):  
Pore Size ◽  
Gas Sensors ◽  
Gas Sensing ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
Kinetic Properties ◽  
Sensing Properties ◽  
Sensing Applications ◽  
Gas Sensing Properties ◽  
Metal Organic

The gas sensing properties of two novel series of Mg-incorporated metal–organic frameworks (MOFs), termed Mg-MOFs-I and -II, were assessed. The synthesized iso-reticular type Mg-MOFs exhibited good crystallinity, high thermal stability, needle-shape morphology and high surface area (up to 2900 m2·g−1), which are promising for gas sensing applications. Gas-sensing studies of gas sensors fabricated from Mg-MOFs-II revealed better sensing performance, in terms of the sensor dynamics and sensor response, at an optimal operating temperature of 200 °C. The MOF gas sensor with a larger pore size and volume showed shorter response and recovery times, demonstrating the importance of the pore size and volume on the kinetic properties of MOF-based gas sensors. The gas-sensing results obtained in this study highlight the potential of Mg-MOFs gas sensors for the practical monitoring of toxic gases in a range of environments.

Cerium-based UiO-66 metal–organic frameworks explored as efficient redox catalysts: titanium incorporation and generation of abundant oxygen vacancies

2019 ◽  
Vol 55 (93) ◽  
pp. 13959-13962 ◽  
Author(s):  
Yajun Zhang ◽  
Hanjiao Chen ◽  
Yi Pan ◽  
Xiaoliang Zeng ◽  
Xiaofang Jiang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Oxygen Vacancies ◽  
Metal Organic Frameworks ◽  
Redox Catalysts ◽  
Metal Organic ◽  
Titanium Incorporation ◽  
First Time

For the first time, UiO-66(Ce) was endowed with greatly improved redox photocatalytic activity via Ti incorporation, based on the formation of oxygen vacancies.

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