A Novel Organic “Polyurea” Thin Film for Ultralong-Life Lithium-Metal Anodes via Molecular-Layer Deposition

2018 ◽  
Vol 31 (4) ◽  
pp. 1806541 ◽  
Author(s):  
Yipeng Sun ◽  
Yang Zhao ◽  
Jiwei Wang ◽  
Jianneng Liang ◽  
Changhong Wang ◽  
...  
Keyword(s):  
Thin Film ◽  
Molecular Layer ◽  
Lithium Metal ◽  
Molecular Layer Deposition ◽  
Layer Deposition ◽  
Lithium Metal Anodes ◽  
Metal Anodes

scholarly journals Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes

2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Xiangbo Meng ◽  
Kah Chun Lau ◽  
Hua Zhou ◽  
Sujan Kumar Ghosh ◽  
Mourad Benamara ◽  
...  
Keyword(s):  
Molecular Layer ◽  
Solid Electrolyte Interphase ◽  
Lithium Metal ◽  
Molecular Layer Deposition ◽  
Lithium Metal Batteries ◽  
Layer Deposition ◽  
Lithium Metal Anodes ◽  
First Time ◽  
Metal Anodes

In this work, we for the first time developed a novel lithium-containing crosslinked polymeric material, a lithicone that enables excellent protection effects over lithium (Li) metal anodes. This new lithicone was synthesized via an accurately controllable molecular layer deposition (MLD) process, in which lithium tert-butoxide (LTB) and glycerol (GL) were used as precursors. The resultant LiGL lithicone was analyzed using a suite of characterizations. Furthermore, we found that the LiGL thichicone could serve as an exceptional polymeric protection film over Li metal anodes. Our experimental data revealed that the Li electrodes coated by this LiGL lithicone can achieve a superior cycling stability, accounting for an extremely long cyclability of >13,600 Li-stripping/plating cycles and having no failures so far in Li/Li symmetric cells at a current density of 5 mA/cm2 and an areal capacity of 1 mAh/cm2. We found that, with a sufficient protection by this LiGL coating, Li electrodes could realize long-term stable cyclability with little formation of Li dendrites and solid electrolyte interphase. This novel LiGL represents a facile and effective solution to the existing issues of Li anodes and potentially paves a technically feasible route for lithium metal batteries.

Radical-triggered cross-linking for molecular layer deposition of SiAlCOH hybrid thin films

2021 ◽  
Author(s):  
Kristina Ashurbekova ◽  
Karina Ashurbekova ◽  
Iva Saric ◽  
Evgeny Modin ◽  
Mladen Petravic ◽  
...  
Keyword(s):  
Thin Film ◽  
Film Growth ◽  
Molecular Layer ◽  
Thin Film Growth ◽  
Cross Linking ◽  
Layer By Layer ◽  
Molecular Layer Deposition ◽  
Layer Deposition ◽  
Hybrid Thin Films ◽  
Enhanced Stability

We developed a thin film growth with a radical-initiated cross-linking of vinyl groups in a layer-by-layer manner via molecular layer deposition (MLD). The cross-linked film exhibited improved properties like 12% higher density and enhanced stability compared to the non-cross-linked film.

An organic-inorganic hybrid semiconductor for flexible thin film transistor using molecular layer deposition

2021 ◽  
Author(s):  
Seung-Hwan Lee ◽  
Hyun-Jun Jeong ◽  
Ki-Lim Han ◽  
GeonHo Beak ◽  
Jin-Seong Park
Keyword(s):  
Thin Film ◽  
Indium Oxide ◽  
Molecular Layer ◽  
Thin Film Transistor ◽  
Hybrid Films ◽  
Molecular Layer Deposition ◽  
Inorganic Hybrid ◽  
Layer Deposition

Indium oxide and indicone hybrid films consisting of indium oxide and organic aromatic linker are grown by molecular layer deposition (MLD) using bis(trimethylsilyl)amido-diethyl Indium (INCA-1) as the indium precursor, hydrogen...

Molecular Layer Deposition for Stable Lithium Metal Anode: From Composition Design to Mechanism Study

2021 ◽  
Vol MA2021-02 (29) ◽  
pp. 857-857
Author(s):  
Yipeng Sun ◽  
Yang Zhao ◽  
Keegan Adair ◽  
Tsun-Kong Sham ◽  
Xueliang Sun
Keyword(s):  
Molecular Layer ◽  
Lithium Metal ◽  
Mechanism Study ◽  
Molecular Layer Deposition ◽  
Composition Design ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Layer Deposition

scholarly journals Atomic/molecular layer deposition and electrochemical performance of dilithium 2-aminoterephthalate

2020 ◽  
Vol 49 (5) ◽  
pp. 1591-1599 ◽  
Author(s):  
Juho Heiska ◽  
Mikko Nisula ◽  
Eeva-Leena Rautama ◽  
Antti J. Karttunen ◽  
Maarit Karppinen
Keyword(s):  
Thin Film ◽  
Electrochemical Performance ◽  
Redox Potential ◽  
Molecular Layer ◽  
Amino Group ◽  
Molecular Layer Deposition ◽  
Layer Deposition ◽  
Thin Film Electrodes

Crystalline Li-terephthalate and amino-functionalized Li-terephthalate thin film electrodes are fabricated from gaseous precursors with ALD/MLD to show that the electron-donating amino group lowers the redox potential.

Molecular layer deposition of hybrid siloxane thin films by ring opening of cyclic trisiloxane (V3D3) and azasilane

2020 ◽  
Vol 56 (62) ◽  
pp. 8778-8781
Author(s):  
Kristina Ashurbekova ◽  
Karina Ashurbekova ◽  
Iva Saric ◽  
Evgenii Modin ◽  
Mladen Petravić ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Ring Opening ◽  
Molecular Layer ◽  
Molecular Layer Deposition ◽  
Layer Deposition ◽  
Ring Opening Reactions

Two consecutive vapor-to-solid ring opening reactions were applied for thin film siloxane polymerization by molecular layer deposition (MLD).

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