scholarly journals Hollow Functional Materials Derived from Metal–Organic Frameworks: Synthetic Strategies, Conversion Mechanisms, and Electrochemical Applications

2019 ◽  
Vol 31 (11) ◽  
pp. 1804903 ◽  
Author(s):  
Ze‐Xing Cai ◽  
Zhong‐Li Wang ◽  
Jeonghun Kim ◽  
Yusuke Yamauchi
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Electrochemical Applications ◽  
Metal Organic

Metal-Organic Frameworks: New Functional Materials and Applications

2019 ◽  
pp. 35-54
Author(s):  
Peiyu Cai ◽  
Wenmiao Chen ◽  
Gregory S. Day ◽  
Hannah F. Drake ◽  
Elizabeth A. Joseph ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Metal Organic

Biomimetic mineralization of metal–organic frameworks around polysaccharides

2017 ◽  
Vol 53 (7) ◽  
pp. 1249-1252 ◽  
Author(s):  
Kang Liang ◽  
Ru Wang ◽  
Manon Boutter ◽  
Cara M. Doherty ◽  
Xavier Mulet ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Biomimetic Mineralization ◽  
Metal Organic

Biomimetic mineralization exploits natural biomineralization processes for the design and fabrication of synthetic functional materials.

scholarly journals Gas Adsorption Selectivity in Topologically Disordered Metal–Organic Frameworks

2021 ◽  
Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren K. Macreadie ◽  
Seok J. Lee ◽  
Tim Johnson ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Interaction Strength ◽  
Functional Materials ◽  
Adsorption Selectivity ◽  
Guest Molecules ◽  
Sorption Behaviour ◽  
Ideal Adsorbed Solution Theory ◽  
Industrial Gases ◽  
Metal Organic

<div><p>Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas adsorption in the topologically disordered Fe-BTC framework and its crystalline counterpart, MIL‑100. Despite their similar chemistry and local structure, they exhibit very different sorption behaviour towards a range of industrial gases, noble gases and hydrocarbons. Virial analysis reveals that Fe-BTC has enhanced interaction strength with guest molecules compared to MIL‑100. Most notably, we observe striking discrimination between the adsorption of C<sub>3</sub>H<sub>6</sub> and C<sub>3</sub>H<sub>8</sub> in Fe‑BTC, with over a twofold increase in the amount of C<sub>3</sub>H<sub>6</sub> being adsorbed than C<sub>3</sub>H<sub>8</sub>. Thermodynamic selectivity towards a range of industrially relevant binary mixtures is probed using ideal adsorbed solution theory (IAST). Together, this suggests the disordered material may possess powerful separation capabilities that are rare even amongst crystalline frameworks.</p></div>

Metal-organic frameworks for direct electrochemical applications

2018 ◽  
Vol 376 ◽  
pp. 292-318 ◽  
Author(s):  
Yuxia Xu ◽  
Qing Li ◽  
Huaiguo Xue ◽  
Huan Pang
Keyword(s):  
Metal Organic Frameworks ◽  
Electrochemical Applications ◽  
Metal Organic

Synthesis of micro/nanoscaled metal–organic frameworks and their direct electrochemical applications

2020 ◽  
Vol 49 (1) ◽  
pp. 301-331 ◽  
Author(s):  
Xiao Xiao ◽  
Lianli Zou ◽  
Huan Pang ◽  
Qiang Xu
Keyword(s):  
Metal Organic Frameworks ◽  
Electrochemical Applications ◽  
Metal Organic ◽  
Developing Strategies

Developing strategies to control the morphology and size of MOFs is important for their applications in batteries, supercapacitors and electrocatalysis. This review focuses on the design and fabrication of MOFs at the micro/nanoscale.

ChemInform Abstract: Giant Metal-Organic Frameworks with Bulky Scaffolds: From Microporous to Mesoporous Functional Materials

ChemInform ◽  
2012 ◽  
Vol 43 (26) ◽  
pp. no-no
Author(s):  
Pounraj Thanasekaran ◽  
Tzuoo-Tsair Luo ◽  
Jing-Yun Wu ◽  
Kuang-Lieh Lu
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Metal Organic

scholarly journals Gas adsorption in the topologically disordered Fe-BTC framework

2021 ◽  
Author(s):  
Adam Sapnik ◽  
Christopher W. Ashling ◽  
Lauren Macreadie ◽  
Seok J. Lee ◽  
Timothy Johnson ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Gas Storage ◽  
Metal Organic

Disordered metal–organic frameworks are emerging as an attractive class of functional materials, however their applications in gas storage and separation have yet to be fully explored. Here, we investigate gas...

Giant metal–organic frameworks with bulky scaffolds: from microporous to mesoporous functional materials

2012 ◽  
Vol 41 (18) ◽  
pp. 5437 ◽  
Author(s):  
Pounraj Thanasekaran ◽  
Tzuoo-Tsair Luo ◽  
Jing-Yun Wu ◽  
Kuang-Lieh Lu
Keyword(s):  
Metal Organic Frameworks ◽  
Functional Materials ◽  
Metal Organic
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