MOF-Confined Sub-2 nm Atomically Ordered Intermetallic PdZn Nanoparticles as High-Performance Catalysts for Selective Hydrogenation of Acetylene

2018 ◽  
Vol 30 (33) ◽  
pp. 1801878 ◽  
Author(s):  
Mingzhen Hu ◽  
Shu Zhao ◽  
Shoujie Liu ◽  
Chen Chen ◽  
Wenxing Chen ◽  
...  
Keyword(s):  
Selective Hydrogenation ◽  
High Performance ◽  
Selective Hydrogenation Of Acetylene ◽  
Ordered Intermetallic ◽  
Pdzn Nanoparticles

A carbonized cobalt catalyst supported by acid-activated clay for the selective hydrogenation of acetylene

2021 ◽  
Author(s):  
Aizat Aitugan ◽  
Sandugash Tanirbergenova ◽  
Yerbol Tileuberdi ◽  
Onuralp Yucel ◽  
Dildara Tugelbayeva ◽  
...  
Keyword(s):  
Selective Hydrogenation ◽  
Cobalt Catalyst ◽  
Selective Hydrogenation Of Acetylene ◽  
Acid Activated Clay

Variability of particle configurations achievable by 2-nozzle flame syntheses of the Au-Pd-TiO2 system and their catalytic behaviors in the selective hydrogenation of acetylene

2018 ◽  
Vol 549 ◽  
pp. 1-7 ◽  
Author(s):  
Boontida Pongthawornsakun ◽  
Okorn Mekasuwandumrong ◽  
Francisco J.Cadete Santos Aires ◽  
Robert Büchel ◽  
Alfons Baiker ◽  
...  
Keyword(s):  
Selective Hydrogenation ◽  
Selective Hydrogenation Of Acetylene

Fe/Fe2 O3 @N-dopped Porous Carbon: A High-Performance Catalyst for Selective Hydrogenation of Nitro Compounds

ChemCatChem ◽  
2018 ◽  
Vol 11 (2) ◽  
pp. 724-728 ◽  
Author(s):  
Ruirui Yun ◽  
Lirui Hong ◽  
Wanjiao Ma ◽  
Weiguo Jia ◽  
Shoujie Liu ◽  
...  
Keyword(s):  
Selective Hydrogenation ◽  
Porous Carbon ◽  
High Performance ◽  
Nitro Compounds

scholarly journals A study concerning the pretreatment of CNTs and its influence on the performance of NIB/CNTs amorphous catalyst

2006 ◽  
Vol 71 (11) ◽  
pp. 1153-1160 ◽  
Author(s):  
Chang Hu-Yuan ◽  
Feng Li ◽  
Li. Hua ◽  
Bin Zhang
Keyword(s):  
Selective Hydrogenation ◽  
Inductively Coupled Plasma ◽  
Acid Treatment ◽  
Chemical Reduction ◽  
X Ray Diffraction ◽  
Chemical Reduction Method ◽  
X Ray ◽  
Inductively Coupled ◽  
Selective Hydrogenation Of Acetylene ◽  
Transmission Electron

As prepared carbon nanotubes were pretreated with nitric acid (CNTs-HNO3) or ammonia (CNTs-NH3). Fourier transform infrared spectroscopy (FTIR) measurements showed that the surface of the nanotubes was functionalized with carboxylic and hydroxyl functional groups after the acid treatment and that basic groups containing nitrogen, such as N-H and C-N, were introduced to the surface of the nanotubes after the ammonia treatment. X-Ray diffraction analysis implied that the nickel residue in the CNTs was effectively removed by acid treatment. However, the nickel residue was only partially eliminated by ammonia pretreatment. NiB amorphous catalysts supported on CNTs-HNO3 and CNTs-NH3 were prepared by the impregnation-chemical reduction method and characterized by transmission electron microscopy (TEM), as well as inductively coupled plasma (ICP) spectroscopy and studied in the selective hydrogenation of acetylene. TEM measurements showed that a high density NiB particles of about 9 nm were homogeneously dispersed on the CNTs-NH3. However, NiB particles (13-23 nm)with amean size of 16 nm were scattered on the CNTs-HNO3.As a result, the activity and selectivity of NiB/CNTs-NH3 were higher than those of NiB/CNTs-HNO3 in the selective hydrogenation of acetylene.

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