Versatile Molecular Functionalization for Inhibiting Concentration Quenching of Thermally Activated Delayed Fluorescence

2016 ◽  
Vol 29 (4) ◽  
pp. 1604856 ◽  
Author(s):  
Jiyoung Lee ◽  
Naoya Aizawa ◽  
Masaki Numata ◽  
Chihaya Adachi ◽  
Takuma Yasuda
Keyword(s):  
Delayed Fluorescence ◽  
Concentration Quenching ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated

Ester-functionalized thermally activated delayed fluorescence materials

2021 ◽  
Author(s):  
Hiroshi Tasaki ◽  
So Shikita ◽  
In Seob Park ◽  
Takuma Yasuda
Keyword(s):  
Delayed Fluorescence ◽  
Concentration Quenching ◽  
Thermally Activated Delayed Fluorescence ◽  
Quenching Effect ◽  
Thermally Activated ◽  
Concentration Quenching Effect ◽  
Neat Films

A family of thermally activated delayed fluorescence (TADF) materials functionalized with carboxylate esters is presented herein. Owing to their suppressed concentration-quenching effect in neat films, these ester-functionalized TADF emitters could...

scholarly journals Using fluorene to lock electronically active moieties in thermally activated delayed fluorescence emitters for high-performance non-doped organic light-emitting diodes with suppressed roll-off

2021 ◽  
Author(s):  
Lin Wu ◽  
Kai Wang ◽  
Cheng Wang ◽  
Xiao-Chun Fan ◽  
Yi-Zhong Shi ◽  
...  
Keyword(s):  
High Performance ◽  
Light Emitting Diodes ◽  
Delayed Fluorescence ◽  
Concentration Quenching ◽  
Organic Light Emitting Diodes ◽  
Thermally Activated Delayed Fluorescence ◽  
Light Emitting ◽  
Thermally Activated ◽  
Organic Light

Two TADF emitters were developed by modifying a reported less successful emitter BP-DPAC with fluorene to suppress concentration quenching. Their non-doped OLEDs displayed excellent EQEs of 22.8% and 21.3% with well-suppressed roll-off.

Solvent Dependence of Structural Dynamics and Spin-flip Processes in 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (ortho-3CzBN)

2020 ◽  
Author(s):  
Masaki Saigo ◽  
Kiyoshi Miyata ◽  
Hajime Nakanotani ◽  
Chihaya Adachi ◽  
Ken Onda
Keyword(s):  
Dft Calculations ◽  
Excited States ◽  
Structural Changes ◽  
Photophysical Properties ◽  
Delayed Fluorescence ◽  
Time Resolved ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Solvent Dependence ◽  
Acetonitrile Solutions

We have investigated the solvent-dependence of structural changes along with intersystem crossing of a thermally activated delayed fluorescence (TADF) molecule, 3,4,5-tri(9H-carbazole-9-yl)benzonitrile (o-3CzBN), in toluene, tetrahydrofuran, and acetonitrile solutions using time-resolved infrared (TR-IR) spectroscopy and DFT calculations. We found that the geometries of the S1 and T1 states are very similar in all solvents though the photophysical properties mostly depend on the solvent. In addition, the time-dependent DFT calculations based on these geometries suggested that the thermally activated delayed fluorescence process of o-3CzBN is governed more by the higher-lying excited states than by the structural changes in the excited states.<br>

New hole transport styrene polymers bearing highly π-extended conjugated side-chain moieties for high-performance solution-processable thermally activated delayed fluorescence OLEDs

2021 ◽  
Vol 12 (11) ◽  
pp. 1692-1699
Author(s):  
Ji Hye Lee ◽  
Jinhyo Hwang ◽  
Chai Won Kim ◽  
Amit Kumar Harit ◽  
Han Young Woo ◽  
...  
Keyword(s):  
High Performance ◽  
High Efficiency ◽  
Delayed Fluorescence ◽  
Hole Transport ◽  
Side Chain ◽  
Solution Processed ◽  
Thermally Activated Delayed Fluorescence ◽  
Thermally Activated ◽  
Turn On ◽  
Solution Processable

New polystyrene-based polymers with high π-extended hole transport pendants were synthesized to obtain a low turn-on voltage and high efficiency in solution-processed green TADF-OLEDs.

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