scholarly journals Ionic Liquids: A New General Synthetic Strategy for Phase-Pure Complex Functional Materials (Adv. Mater. 42/2012)

2012 ◽  
Vol 24 (42) ◽  
pp. 5648-5648
Author(s):  
David C. Green ◽  
Stefan Glatzel ◽  
Andrew M. Collins ◽  
Avinash J. Patil ◽  
Simon R. Hall
ChemInform ◽  
2013 ◽  
Vol 44 (6) ◽  
pp. no-no
Author(s):  
David C. Green ◽  
Stefan Glatzel ◽  
Andrew M. Collins ◽  
Avinash J. Patil ◽  
Simon R. Hall

2012 ◽  
Vol 24 (42) ◽  
pp. 5767-5772 ◽  
Author(s):  
David C. Green ◽  
Stefan Glatzel ◽  
Andrew M. Collins ◽  
Avinash J. Patil ◽  
Simon R. Hall

Nanomaterials ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 800 ◽  
Author(s):  
Petia Atanasova ◽  
Vladimir Atanasov ◽  
Lisa Wittum ◽  
Alexander Southan ◽  
Eunjin Choi ◽  
...  

The robust, anisotropic tobacco mosaic virus (TMV) provides a monodisperse particle size and defined surface chemistry. Owing to these properties, it became an excellent bio-template for the synthesis of diverse nanostructured organic/inorganic functional materials. For selective mineralization of the bio-template, specific functional groups were introduced by means of different genetically encoded amino acids or peptide sequences into the polar virus surface. An alternative approach for TMV surface functionalization is chemical coupling of organic molecules. To achieve mineralization control in this work, we developed a synthetic strategy to manipulate the surface hydrophilicity of the virus through covalent coupling of polymer molecules. Three different types of polymers, namely the perfluorinated (poly(pentafluorostyrene) (PFS)), the thermo-responsive poly(propylene glycol) acrylate (PPGA), and the block-copolymer polyethylene-block-poly(ethylene glycol) were examined. We have demonstrated that covalent attachment of hydrophobic polymer molecules with proper features retains the integrity of the virus structure. In addition, it was found that the degree of the virus hydrophobicity, examined via a ZnS mineralization test, could be tuned by the polymer properties.


2007 ◽  
Vol 13 (18) ◽  
pp. 5048-5058 ◽  
Author(s):  
Takanori Fukushima ◽  
Takuzo Aida

2011 ◽  
Vol 284-286 ◽  
pp. 58-64 ◽  
Author(s):  
Xiang Ying Hao ◽  
Cui Zhang ◽  
Shuang Xi Liu ◽  
Hai Fu Guo

Zeolites mordenite (MOR) and β decorated with high dispersion degree and loading content of CuO composite (symbolized as CuO/zeolite) were prepared via a novel method-the stepped hydrothermal synthesis. The resultant composite were characterized with details by powder XRD, ICP-AES, H2-TPR and TEM techniques. Shown by experiment, the stepped hydrothermal synthetic method adopted in the present research using urea as alkali source as well as benefiting from the ultrasonic wash treatment hardly damages the zeolitic framework structure. Compared with ammonia, high dispersion degree and loading level of CuO are yielded as a consequence of the employment of urea as alkali source. Besides, the ultrasonic wash treatment not only removes some CuO precursors that deposit on the external surface of the porous support but also produces a uniform distribution of CuO particles with smaller dimension on the surface of zeolites: CuO are dispersed in nanoscale of about 4-8 nm on mordenite and 2-5 nm on zeolite β. The present synthetic strategy could be therefore applied as a novel general method for the manufacture of functional materials in a wide spectrum.


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