Patterning: Spatially Modulating Interfacial Properties of Transparent Conductive Oxides: Patterning Work Function with Phosphonic Acid Self-Assembled Monolayers (Adv. Mater. 5/2012)

2012 ◽  
Vol 24 (5) ◽  
pp. 570-570 ◽  
Author(s):  
Kristina M. Knesting ◽  
Peter J. Hotchkiss ◽  
Bradley A. MacLeod ◽  
Seth R. Marder ◽  
David S. Ginger
Keyword(s):  
Work Function ◽  
Phosphonic Acid ◽  
Interfacial Properties ◽  
Self Assembled Monolayers ◽  
Transparent Conductive Oxides ◽  
Assembled Monolayers ◽  
Self Assembled

Tuning the Work Function of Polar Zinc Oxide Surfaces using Modified Phosphonic Acid Self‐Assembled Monolayers

2014 ◽  
Vol 24 (44) ◽  
pp. 7014-7024 ◽  
Author(s):  
Ilja Lange ◽  
Sina Reiter ◽  
Michael Pätzel ◽  
Anton Zykov ◽  
Alexei Nefedov ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Work Function ◽  
Phosphonic Acid ◽  
Self Assembled Monolayers ◽  
Oxide Surfaces ◽  
Assembled Monolayers ◽  
Self Assembled

Preparation and Interfacial Properties of Phosphonic Acid-Terminated Self-Assembled Monolayers on Gold Surface

2009 ◽  
Vol 113 (11) ◽  
pp. 4515-4521 ◽  
Author(s):  
Yu Chen ◽  
Xiao-Jing Yang ◽  
Bo Jin ◽  
Li-Rong Guo ◽  
Li-Min Zheng ◽  
...  
Keyword(s):  
Phosphonic Acid ◽  
Gold Surface ◽  
Interfacial Properties ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Self-Assembled Monolayers of 12-Mercaptododecylphosphonic Acid on Titania Particles; Application to the Extraction of Heavy Metals

2004 ◽  
Vol 847 ◽  
Author(s):  
Sébastien Anthérieu ◽  
Florence Brodard-Séverac ◽  
Gilles Guerrero ◽  
P. Hubert Mutin
Keyword(s):  
Heavy Metals ◽  
Chemical Analysis ◽  
Phosphonic Acid ◽  
Metal Extraction ◽  
Self Assembled Monolayers ◽  
Extraction Ability ◽  
Self Assembled Monolayer ◽  
Inorganic Hybrid ◽  
Assembled Monolayers ◽  
Self Assembled

ABSTRACTTitania particles (P25 DEGUSSA AG) were treated by a solution of 12-mercaptododecyl-phosphonic acid (MDPA) in toluene to obtain an organic-inorganic hybrid material with thiol functions at the surface. This material was characterized by chemical analysis, solid state 31P MAS NMR and FTIR spectroscopies, and XPS. Reaction of the phosphonic acid end of MDPA with the TiO2 surface led to the formation of a relatively dense and well-ordered self-assembled monolayer (SAM), with a density of about 3.9 SH functions per nm2. This material was tested for the extraction of mercury in water at pH 7, 9, and 11. Chemical analysis indicated no loss of SH functionality, even at pH 11. The best extraction results were obtained at pH 9 and 11, with a metal extraction ability between 85 and 90%.

Bonding and Penetration at Metal/Self-Assembled Organic Monolayer Interfaces

1995 ◽  
Vol 385 ◽  
Author(s):  
D. R. Jung ◽  
A. W. Czanderna ◽  
G. C. Herdt
Keyword(s):  
Metal Oxide ◽  
Environmental Conditions ◽  
Interfacial Properties ◽  
Self Assembled Monolayers ◽  
Organic Substrates ◽  
Research Results ◽  
Organic Monolayer ◽  
Organic Interfaces ◽  
Assembled Monolayers ◽  
Self Assembled

ABSTRACTThe purpose of research on metals (M) deposited onto self-assembled monolayers (SAMs) is to understand the interactions between the metal and eventually metal oxide overlayers on well-ordered organic substrates. Applications of M/SAM and inorganic/SAM research results to the understanding of real inorganic/organic interfaces in vacuum and under environmental conditions can potentially play a key role in the development of advanced devices with stable interfacial properties. The results of selected M/SAM studies to date are reviewed, and MISAM combinations ranked according to reactivity and penetration. Specific examples of reactive interfaces (Cu/COOH, Cr/several groups) and nonreactive interfaces with penetration (Ag/CH3, Ag/COOH) are used to illustrate the extremes.

Synthesis, Characterization, and Formation of Self-Assembled Monolayers of a Phosphonic Acid Bearing a Vinylene-Bridged Fluoroalkyl Chain

2021 ◽  
pp. 151959
Author(s):  
Tomohiro Shirai ◽  
Satoshi Yamauchi ◽  
Hikari Kikuchi ◽  
Hiroki Fukumoto ◽  
Hiroto Tsukada ◽  
...  
Keyword(s):  
Phosphonic Acid ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Imaging Photoelectron Transmission through Self-Assembled Monolayers:  The Work-Function of Alkanethiols Coated Gold

Langmuir ◽  
2007 ◽  
Vol 23 (11) ◽  
pp. 6156-6162 ◽  
Author(s):  
Despina Fragouli ◽  
Theofanis N. Kitsopoulos ◽  
Letizia Chiodo ◽  
Fabio Della Sala ◽  
Roberto Cingolani ◽  
...  
Keyword(s):  
Work Function ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111)

Nanoscale ◽  
2014 ◽  
Vol 6 (15) ◽  
pp. 8969-8977 ◽  
Author(s):  
Appan Merari Masillamani ◽  
Silvio Osella ◽  
Andrea Liscio ◽  
Oliver Fenwick ◽  
Federica Reinders ◽  
...  
Keyword(s):  
Work Function ◽  
Optical Switch ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Reversible Modification ◽  
Self Assembled

Self-assembled monolayers of fluorinated azobenzene molecules on gold display an optical switch of the work function with magnitude 220 meV.

scholarly journals Controlling Interfacial Properties of Lithium-Ion Battery Cathodes with Alkylphosphonate Self-Assembled Monolayers

2018 ◽  
Vol 5 (10) ◽  
pp. 1701292 ◽  
Author(s):  
Bruno G. Nicolau ◽  
Aaron Petronico ◽  
Kendra Letchworth-Weaver ◽  
Yasaman Ghadar ◽  
Richard T. Haasch ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Interfacial Properties ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled
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