Comment on “Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-order Nonlinear Optical Properties of Triphenylamine-cored Alkynylruthenium Dendrimers” - Increasing the Nonlinear Optical Response by Two Orders of Magnitude

2011 ◽  
Vol 23 (12) ◽  
pp. 1428-1432 ◽  
Author(s):  
Javier Pérez-Moreno ◽  
Mark G. Kuzyk
Keyword(s):  
Optical Properties ◽  
Nonlinear Optics ◽  
Nonlinear Optical ◽  
Optical Response ◽  
Nonlinear Optical Properties ◽  
Organometallic Complexes ◽  
Nonlinear Optical Response ◽  
Third Order ◽  
The Third

Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-Order Nonlinear Optical Properties of Triphenylamine-Cored Alkynylruthenium Dendrimers

2009 ◽  
Vol 21 (22) ◽  
pp. 2318-2322 ◽  
Author(s):  
Rachel L. Roberts ◽  
Torsten Schwich ◽  
T. Christopher Corkery ◽  
Marie P. Cifuentes ◽  
Katy A. Green ◽  
...  
Keyword(s):  
Optical Properties ◽  
Nonlinear Optics ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Organometallic Complexes ◽  
Third Order ◽  
The Third

SIZE EFFECT OF ENCASED ATOM ON ABSORPTION AND NONLINEAR OPTICAL PROPERTIES OF EMBEDDED METALLOFULLERENES M@C82 (M = Sc, Y, La)

2008 ◽  
Vol 07 (04) ◽  
pp. 737-749 ◽  
Author(s):  
HUI HU ◽  
WEN-DAN CHENG ◽  
SHU-PING HUANG ◽  
ZHI XIE ◽  
HAO ZHANG
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Atomic Radius ◽  
Optical Response ◽  
Nonlinear Optical Properties ◽  
Nonlinear Optical Response ◽  
Photon Absorption ◽  
Absorption Bands ◽  
Third Order ◽  
Linear Absorption

The linear absorption spectra and third-order nonlinear optical properties of M@ C 82 (M = Sc , Y , La ) nanostructural materials, whose configurations were optimized at the unrestricted open shell UB3LYP level, are simulated by the sum-over-states combined with the time-dependent UB3LYP methods. The obtained results show that the electronic absorption bands have redshifts, and the values of third-order nonlinear optical polarizabilities and two-photon absorption cross sections increase for M@ C 82 fullerenes (M = Sc , Y , La ) as the atomic radius of encased metal M increase in the order of Sc → Y → La . It is indicated that the electron-donating ability from the encased M atom to cage C 82 decreases or the electron-accepting ability from C 82 to M atom increases as the atomic radius of M increases, which results in third-order nonlinear optical response enhancement in the order of Sc @ C 82 < Y @ C 82 < La @ C 82. This gives a clue to design the nanostructural materials of encased fullerenes having a large nonlinear optical response.

Organometallic Complexes for Nonlinear Optics. 39.1Syntheses and Third-Order Nonlinear Optical Properties of First-Generation Peripherally Metalated Arylalkynyl Dendrimers

2007 ◽  
Vol 26 (18) ◽  
pp. 4456-4463 ◽  
Author(s):  
Clem E. Powell ◽  
Stephanie K. Hurst ◽  
Joseph P. Morrall ◽  
Marie P. Cifuentes ◽  
Rachel L. Roberts ◽  
...  
Keyword(s):  
Optical Properties ◽  
Nonlinear Optics ◽  
Nonlinear Optical ◽  
First Generation ◽  
Nonlinear Optical Properties ◽  
Organometallic Complexes ◽  
Third Order

Organometallic complexes for nonlinear optics. 37: Synthesis and third-order nonlinear optical properties of a hexarutheniumtriplatinum dendrimer

Polyhedron ◽  
2007 ◽  
Vol 26 (2) ◽  
pp. 284-289 ◽  
Author(s):  
Clem E. Powell ◽  
Marie P. Cifuentes ◽  
Mark G. Humphrey ◽  
Anthony C. Willis ◽  
Joseph P. Morrall ◽  
...  
Keyword(s):  
Optical Properties ◽  
Nonlinear Optics ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Organometallic Complexes ◽  
Third Order

Physical origin of the third-order nonlinear optical properties of polyenes

2005 ◽  
Vol 52 (14) ◽  
pp. 1933-1945 ◽  
Author(s):  
I. Fuks-Janczarek ◽  
I. V. Kityk * ◽  
J. Berdowski ◽  
B. Sahraoui ◽  
C. Andraud
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Physical Origin ◽  
Third Order ◽  
The Third

Theoretical aspects on the evaluation and interpretation of the third-order nonlinear optical properties of diradical compounds

2012 ◽  
Author(s):  
Benoı̂t Champagne ◽  
Edith Botek ◽  
Akihiro Shimizu ◽  
Takashi Kubo ◽  
Kenji Kamada ◽  
...  
Keyword(s):  
Optical Properties ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Third Order ◽  
The Third

Investigation of the third-order nonlinear optical properties in porphyrin solutions in the picosecond regime

2015 ◽  
Vol 24 (03) ◽  
pp. 1550030 ◽  
Author(s):  
M. Chniti ◽  
C. Cassagne ◽  
J. L. Godet ◽  
G. Boudebs
Keyword(s):  
Refractive Index ◽  
Optical Properties ◽  
Time Dependence ◽  
Nonlinear Optical ◽  
Optical Response ◽  
Spectral Width ◽  
Incident Laser ◽  
Third Order ◽  
The Third ◽  
532 Nm

The D4σ-Z-scan technique is used to evaluate the sign and the magnitude of the nonlinear (NL) refractive index and the NL absorption (NLA) coefficient with a laser delivering single pulses in the picosecond regime at 355 nm, 532 nm and 1064 nm. The NL optical response of the zinc porphyrins (Pph) has been found to be significantly enhanced. The study of the NLA and refraction is performed, taking into account the time dependence and the spectral width of the incident laser. The variations of the NL coefficients as a function of the intensity and the concentration are provided and are found to be linear.

Sign in / Sign up

Export Citation Format

Share Document