High-mobility Ambipolar Transistors and High-gain Inverters from a Donor-Acceptor Copolymer Semiconductor

2010 ◽  
Vol 22 (4) ◽  
pp. 478-482 ◽  
Author(s):  
Felix Sunjoo Kim ◽  
Xugang Guo ◽  
Mark D. Watson ◽  
Samson A. Jenekhe
Keyword(s):  
High Mobility ◽  
High Gain ◽  
Donor Acceptor

Dual emissive bodipy–benzodithiophene–bodipy TICT triad with a remarkable Stokes shift of 194 nm

2018 ◽  
Vol 16 (12) ◽  
pp. 2033-2038 ◽  
Author(s):  
Sanchita Sengupta ◽  
Upendra K. Pandey
Keyword(s):  
Stokes Shift ◽  
High Mobility ◽  
Donor Acceptor

An acceptor–donor–acceptor (A–D–A) triad based on BODIPY and benzodithiophene exhibited a high Stokes shift of ∼194 nm, TICT and high mobility of 4.46 × 10−4 cm2 V−1 s−1.

Spectroscopic Study of Electron and Hole Polarons in a High-Mobility Donor–Acceptor Conjugated Copolymer

2013 ◽  
Vol 117 (13) ◽  
pp. 6835-6841 ◽  
Author(s):  
Haihua Xu ◽  
Yuqian Jiang ◽  
Jun Li ◽  
Beng S. Ong ◽  
Zhigang Shuai ◽  
...  
Keyword(s):  
Spectroscopic Study ◽  
High Mobility ◽  
Donor Acceptor ◽  
Conjugated Copolymer

scholarly journals Donor–acceptor stacking arrangements in bulk and thin-film high-mobility conjugated polymers characterized using molecular modelling and MAS and surface-enhanced solid-state NMR spectroscopy

2017 ◽  
Vol 8 (4) ◽  
pp. 3126-3136 ◽  
Author(s):  
Sachin R. Chaudhari ◽  
John M. Griffin ◽  
Katharina Broch ◽  
Anne Lesage ◽  
Vincent Lemaur ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Nmr Spectroscopy ◽  
Conjugated Polymers ◽  
Molecular Modelling ◽  
Solid State Nmr ◽  
High Mobility ◽  
Surface Enhanced ◽  
Donor Acceptor

DPP-DTT adopts a donor-on-acceptor stacking arrangement which is preserved in thin films.

scholarly journals Engineering Donor-Acceptor Conjugated Polymers for High-Performance and Fast-Response Organic Electrochemical Transistors

2020 ◽  
Author(s):  
Hanyu Jia ◽  
Zhen Huang ◽  
Peiyun Li ◽  
song zhang ◽  
yunfei wang ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
High Performance ◽  
High Mobility ◽  
Hole Mobility ◽  
Fast Response ◽  
Ion Diffusion ◽  
Order Of Magnitude ◽  
Donor Acceptor ◽  
Systematic Solution ◽  
Organic Electrochemical Transistors

To date, high-performance organic electrochemical transistors (OECTs) are all based on polythiophene systems. Donor-acceptor (D-A) conjugated polymers are expected to be promising materials for OECTs owing to their high mobility and comparatively low crystallinity (good for ion diffusion). However, the OECT performance of D-A polymers lags far behind that of the polythiophenes. Here we synergistically engineered the backbone, side chain of a series of diketopyrrolopyrrole (DPP)-based D-A polymers and found that redox potential, molecular weight, solution processability, and film microstructures are essential to their performance. Among the polymers, P(bgDPP-MeOT2) exhibited a figure-of-merit (μC*) of 225 F cm<sup>–1</sup> V<sup>–1</sup> s<sup>–1</sup>, <a>over one order of magnitude higher than previously reported D-A polymers. Besides, the DPP polymers exhibited high hole mobility over 2 cm<sup>2</sup> V</a><sup>−1</sup> s<sup>−1</sup>, significantly higher than all D-A polymers employed in OECTs, leading to fast response OECTs with a record low turn-off response time of 30 μs. <a>The polymer also exhibited better stability than polythiophene systems with current retention of 98.8% over 700 electrochemical switching cycles.</a> This work provides a systematic solution to unleash the high-performance and fast-response nature of D-A polymers in OECTs.

A pyridine-flanked diketopyrrolopyrrole (DPP)-based donor–acceptor polymer showing high mobility in ambipolar and n-channel organic thin film transistors

2015 ◽  
Vol 6 (6) ◽  
pp. 938-945 ◽  
Author(s):  
Bin Sun ◽  
Wei Hong ◽  
Hany Aziz ◽  
Yuning Li
Keyword(s):  
Thin Film ◽  
Thin Film Transistors ◽  
High Mobility ◽  
Organic Thin Film Transistors ◽  
Organic Thin Film ◽  
Donor Acceptor

A new donor–acceptor polymer based on pyridine-flanked diketopyrrolopyrrole shows high mobilities in both ambipolar and unipolar n-type organic thin film transistors.

Vinylidenedithiophenmethyleneoxindole: a centrosymmetric building block for donor–acceptor copolymers

2016 ◽  
Vol 7 (7) ◽  
pp. 1413-1421 ◽  
Author(s):  
Weifeng Zhang ◽  
Naihang Zheng ◽  
Congyuan Wei ◽  
Jianyao Huang ◽  
Dong Gao ◽  
...  
Keyword(s):  
Building Block ◽  
High Mobility ◽  
Donor Acceptor

A novel building block (VDTOI) was designed and synthesized. VDTOI-based copolymers exhibit a high mobility of 0.35 cm2 V−1 s−1.

scholarly journals Reduced exchange narrowing caused by gate-induced charge carriers in high-mobility donor–acceptor copolymers

2017 ◽  
Vol 95 (11) ◽  
Author(s):  
Jun'ya Tsutsumi ◽  
Satoshi Matsuoka ◽  
Itaru Osaka ◽  
Reiji Kumai ◽  
Tatsuo Hasegawa
Keyword(s):  
High Mobility ◽  
Charge Carriers ◽  
Donor Acceptor ◽  
Induced Charge ◽  
Exchange Narrowing

Molecular Doping of a High Mobility Diketopyrrolopyrrole–Dithienylthieno[3,2-b]thiophene Donor–Acceptor Copolymer with F6TCNNQ

2017 ◽  
Vol 50 (3) ◽  
pp. 914-926 ◽  
Author(s):  
Yevhen Karpov ◽  
Tim Erdmann ◽  
Manfred Stamm ◽  
Uwe Lappan ◽  
Olga Guskova ◽  
...  
Keyword(s):  
High Mobility ◽  
Donor Acceptor ◽  
Molecular Doping
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