Interface Engineering by Thiazolium Iodide Passivation Towards Reduced Thermal Diffusion and Performance Improvement in Perovskite Solar Cells

2020 ◽  
Vol 30 (14) ◽  
pp. 1910561 ◽  
Author(s):  
Manuel Salado ◽  
Michael Andresini ◽  
Peng Huang ◽  
Mohd Taukeer Khan ◽  
Fulvio Ciriaco ◽  
...  
Keyword(s):  
Solar Cells ◽  
Performance Improvement ◽  
Thermal Diffusion ◽  
Perovskite Solar Cells ◽  
Interface Engineering ◽  
And Performance

scholarly journals Interface Engineering by Thiazolium Iodide Passivation Towards Reduced Thermal Diffusion and Performance Improvement in Perovskite Solar Cells

2020 ◽  
Author(s):  
Manuel Salado ◽  
Michael Andresini ◽  
Peng Huang ◽  
Mohd Taukeer Khan ◽  
Fulvio Ciriaco ◽  
...  
Keyword(s):  
Solar Cells ◽  
Thermal Diffusion ◽  
Transient Absorption ◽  
Perovskite Solar Cells ◽  
Side Reaction ◽  
Interface Engineering ◽  
Perovskite Layer ◽  
Interfacial Layers ◽  
Long Term Stability ◽  
And Performance

<p>Interface engineering has become one of the facile and effective approach to improve solar cells performance, its long-term stability and retard unwanted side reaction. We have developed three passivating agents which can functionalize the surface and induce hydrophobicity by employing substituted thiazolium iodide (TMI) for perovskite solar cells fabrication. The role of TMI interfacial layers on microstructure and electro-optical properties was assessed for structural as well as transient absorption (TA) measurements. TMI treatment resulted into <i>V</i><sub>OC</sub> and FF enhancement by reducing possible recombination paths at perovskite/HTM interface and by reducing the shallow as well as deep traps. These in turn allowed to achieve higher performance as compared to the pristine surface. Additionally, TMI passivated perovskite layer reduces considerably CH<sub>3</sub>NH<sub>3</sub><sup>+</sup> thermal diffusion and degradation induced by humidity. The un-encapsulated perovskite solar cells employing TMI exhibited a remarkable stability under moisture levels (~50% RH) retaining ~95% of initial PCE after 800 h of fabrication, paving potential scalable endeavour. </p>

scholarly journals Interface Engineering by Thiazolium Iodide Passivation Towards Reduced Thermal Diffusion and Performance Improvement in Perovskite Solar Cells

2020 ◽  
Author(s):  
Manuel Salado ◽  
Michael Andresini ◽  
Peng Huang ◽  
Mohd Taukeer Khan ◽  
Fulvio Ciriaco ◽  
...  
Keyword(s):  
Solar Cells ◽  
Thermal Diffusion ◽  
Transient Absorption ◽  
Perovskite Solar Cells ◽  
Side Reaction ◽  
Interface Engineering ◽  
Perovskite Layer ◽  
Interfacial Layers ◽  
Long Term Stability ◽  
And Performance

<p>Interface engineering has become one of the facile and effective approach to improve solar cells performance, its long-term stability and retard unwanted side reaction. We have developed three passivating agents which can functionalize the surface and induce hydrophobicity by employing substituted thiazolium iodide (TMI) for perovskite solar cells fabrication. The role of TMI interfacial layers on microstructure and electro-optical properties was assessed for structural as well as transient absorption (TA) measurements. TMI treatment resulted into <i>V</i><sub>OC</sub> and FF enhancement by reducing possible recombination paths at perovskite/HTM interface and by reducing the shallow as well as deep traps. These in turn allowed to achieve higher performance as compared to the pristine surface. Additionally, TMI passivated perovskite layer reduces considerably CH<sub>3</sub>NH<sub>3</sub><sup>+</sup> thermal diffusion and degradation induced by humidity. The un-encapsulated perovskite solar cells employing TMI exhibited a remarkable stability under moisture levels (~50% RH) retaining ~95% of initial PCE after 800 h of fabrication, paving potential scalable endeavour. </p>

SnO2-Based Perovskite Solar Cells: Configuration Design and Performance Improvement

Solar RRL ◽  
2019 ◽  
Vol 3 (2) ◽  
pp. 1800292 ◽  
Author(s):  
Detao Liu ◽  
Yafei Wang ◽  
Hao Xu ◽  
Hualin Zheng ◽  
Ting Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Performance Improvement ◽  
Perovskite Solar Cells ◽  
Configuration Design ◽  
And Performance

Improving Photovoltaic Stability and Performance of Perovskite Solar Cells by Molecular Interface Engineering

2018 ◽  
Vol 123 (2) ◽  
pp. 1219-1225 ◽  
Author(s):  
Linan Meng ◽  
Fan Zhang ◽  
Wei Ma ◽  
Yu Zhao ◽  
Peng Zhao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Interface Engineering ◽  
And Performance

Performance improvement of inverted two-dimensional perovskite solar cells using a non-fullerene acceptor as the trap passivator

2021 ◽  
Author(s):  
Eun-Cheol Lee ◽  
Zhihai Liu
Keyword(s):  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Performance Improvement ◽  
High Power ◽  
Power Conversion ◽  
Perovskite Solar Cells ◽  
Two Dimensional ◽  
High Power Conversion Efficiency ◽  
Long Term Stability

Recently, Ruddlesden–Popper two-dimensional (2D) perovskite solar cells (PSCs) have been intensively studied, owing to their high power conversion efficiency (PCE) and excellent long-term stability. In this work, we improved the...

scholarly journals Composition and Interface Engineering for Efficient and Thermally Stable Pb-Sn Mixed Low-Bandgap Perovskite Solar Cells

2018 ◽  
Vol 28 (51) ◽  
pp. 1804603 ◽  
Author(s):  
Dan Chi ◽  
Shihua Huang ◽  
Meiying Zhang ◽  
Shaiqiang Mu ◽  
Yang Zhao ◽  
...  
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Thermally Stable ◽  
Interface Engineering ◽  
Low Bandgap
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