scholarly journals Water Splitting: Orienting Active Crystal Planes of New Class Lacunaris Fe2 PO5 Polyhedrons for Robust Water Oxidation in Alkaline and Neutral Media (Adv. Funct. Mater. 35/2018)

2018 ◽  
Vol 28 (35) ◽  
pp. 1870248 ◽  
Author(s):  
Yunzhen Wu ◽  
Yanan Meng ◽  
Jungang Hou ◽  
Shuyan Cao ◽  
Zhanming Gao ◽  
...  
Keyword(s):  
Water Splitting ◽  
Water Oxidation ◽  
Active Crystal ◽  
New Class ◽  
Neutral Media

Orienting Active Crystal Planes of New Class Lacunaris Fe2 PO5 Polyhedrons for Robust Water Oxidation in Alkaline and Neutral Media

2018 ◽  
Vol 28 (35) ◽  
pp. 1801397 ◽  
Author(s):  
Yunzhen Wu ◽  
Yanan Meng ◽  
Jungang Hou ◽  
Shuyan Cao ◽  
Zhanming Gao ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Active Crystal ◽  
New Class ◽  
Neutral Media

Water splitting in near-neutral media: using an Mn–Co-based nanowire array as a complementary electrocatalyst

2017 ◽  
Vol 5 (24) ◽  
pp. 12091-12095 ◽  
Author(s):  
Shuai Hao ◽  
Yingchun Yang
Keyword(s):  
Water Splitting ◽  
Water Oxidation ◽  
Nanowire Array ◽  
Carbon Cloth ◽  
Neutral Media

A Mn–Co–borate nanowire array on carbon cloth (Mn–Co–Bi/CC) acts as an efficient electrocatalyst for water oxidation with an overpotential of 366 mV to drive 10 mA cm−2 in 0.5 M K-Bi. The two-electrode electrolyser using Mn–Co–Bi/CC as the anode and MnCo2O4/CC as the cathode drives 10 mA cm−2 at 1.97 V.

Electrochemical and photoelectrochemical water splitting with a CoOx catalyst prepared by flame assisted deposition

2020 ◽  
Vol 49 (3) ◽  
pp. 588-592 ◽  
Author(s):  
Fusheng Li ◽  
Ziqi Zhao ◽  
Hao Yang ◽  
Dinghua Zhou ◽  
Yilong Zhao ◽  
...  
Keyword(s):  
Cobalt Oxide ◽  
Water Splitting ◽  
Water Oxidation ◽  
Oxide Catalyst ◽  
Photoelectrochemical Water Splitting ◽  
Deposition Method ◽  
Photoelectrochemical Water Oxidation

A cobalt oxide catalyst prepared by a flame-assisted deposition method on the surface of FTO and hematite for electrochemical and photoelectrochemical water oxidation, respectively.

scholarly journals Au decorated BiVO4 inverse opal for efficient visible light driven water oxidation

RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8751-8758
Author(s):  
Xiaonong Wang ◽  
Xiaoxia Li ◽  
Jingxiang Low
Keyword(s):  
Visible Light ◽  
Water Splitting ◽  
Water Oxidation ◽  
Inverse Opal ◽  
Photocatalytic Water Splitting ◽  
Visible Light Driven

Photocatalytic water splitting provides an effective way to prepare hydrogen and oxygen.

Iron and Nitrogen Co-doped CoSe2 Nanosheet Arrays for Robust Electrocatalytic Water Oxidation

2021 ◽  
Author(s):  
Di Li ◽  
Yingying Xing ◽  
Changjian Zhou ◽  
Yikai Lu ◽  
Shengjie Xu ◽  
...  
Keyword(s):  
Water Splitting ◽  
Water Oxidation ◽  
Energy Barrier ◽  
Large Scale ◽  
Scale Production ◽  
Reaction Energy ◽  
Large Scale Production ◽  
Nanosheet Arrays ◽  
Production Of Hydrogen ◽  
Co Doped

The high reaction energy barrier of the oxygen evolution reaction (OER) extremely reduces the efficiency of water splitting, which is not conducive to large-scale production of hydrogen. Due to the...

Visible light-driven novel g-C3N4/NiFe-LDH composite photocatalyst with enhanced photocatalytic activity towards water oxidation and reduction reaction

2015 ◽  
Vol 3 (36) ◽  
pp. 18622-18635 ◽  
Author(s):  
Susanginee Nayak ◽  
Lagnamayee Mohapatra ◽  
Kulamani Parida
Keyword(s):  
Photocatalytic Activity ◽  
Composite Materials ◽  
Visible Light ◽  
Water Splitting ◽  
Visible Light Irradiation ◽  
Water Oxidation ◽  
Reduction Reaction ◽  
Light Irradiation ◽  
Composite Photocatalyst ◽  
Visible Light Driven

Dispersion of exfoliated CN over the surface of exfoliated LDH composite materials, and its photocatalytic water splitting under visible-light irradiation.

scholarly journals Effect of alkaline pH on photosynthetic water oxidation and the association of extrinsic proteins with Photosystem Two

1989 ◽  
Vol 258 (2) ◽  
pp. 357-362 ◽  
Author(s):  
D J Chapman ◽  
J De Felice ◽  
K Davis ◽  
J Barber
Keyword(s):  
Water Splitting ◽  
Water Oxidation ◽  
Binding Sites ◽  
Partial Recovery ◽  
Alkaline Ph ◽  
Ph Values ◽  
Extrinsic Proteins ◽  
Reversible Phase ◽  
Photosynthetic Water Oxidation ◽  
Optimal Ph

Incubation of a membrane preparation enriched in Photosystem Two (PSII) at alkaline pH inhibited the water-splitting reactions in two distinct steps. Up to pH 8.5 the inhibition was reversible, whereas at higher alkalinities it was irreversible. It was shown that the reversible phase correlated with loss and rebinding of the 23 kDa extrinsic polypeptide. However, after mild alkaline treatments a partial recovery was possible without the binding of the 23 kDa polypeptide when the assay was at the optimal pH of 6.5 and in a medium containing excess Cl-. The irreversible phase was found to be closely linked with the removal of the 33 kDa extrinsic protein of PSII. Treatments with pH values above 8.5 not only caused the 33 kDa protein to be displaced from the PSII-enriched membranes, but also resulted in an irreversible modification of the binding sites such that the extrinsic 33 kDa protein could not reassociate with PSII when the pH was lowered to 6.5. The results obtained with these more extreme alkaline pH treatments support the notion that the 23 kDa protein cannot bind to PSII unless the 33 kDa protein is already bound. The differential effect of pH on the removal of the 23 kDa and 33 kDa proteins contrasted with the data of Kuwabara & Murata [(1983) Plant Cell Physiol. 24, 741-747], but this discrepancy was accounted for by the use of glycerol in the incubation media.

scholarly journals Nano-sized manganese oxides as biomimetic catalysts for water oxidation in artificial photosynthesis: a review

2012 ◽  
Vol 9 (75) ◽  
pp. 2383-2395 ◽  
Author(s):  
Mohammad Mahdi Najafpour ◽  
Fahimeh Rahimi ◽  
Eva-Mari Aro ◽  
Choon-Hwan Lee ◽  
Suleyman I. Allakhverdiev
Keyword(s):  
Hydrogen Production ◽  
Water Splitting ◽  
Water Oxidation ◽  
Active Sites ◽  
Manganese Oxides ◽  
Metal Compounds ◽  
Functional Models ◽  
Current Densities ◽  
Conversion Efficiencies ◽  
Manganese Compounds

There has been a tremendous surge in research on the synthesis of various metal compounds aimed at simulating the water-oxidizing complex (WOC) of photosystem II (PSII). This is crucial because the water oxidation half reaction is overwhelmingly rate-limiting and needs high over-voltage (approx. 1 V), which results in low conversion efficiencies when working at current densities required for hydrogen production via water splitting. Particular attention has been given to the manganese compounds not only because manganese has been used by nature to oxidize water but also because manganese is cheap and environmentally friendly. The manganese–calcium cluster in PSII has a dimension of about approximately 0.5 nm. Thus, nano-sized manganese compounds might be good structural and functional models for the cluster. As in the nanometre-size of the synthetic models, most of the active sites are at the surface, these compounds could be more efficient catalysts than micrometre (or bigger) particles. In this paper, we focus on nano-sized manganese oxides as functional and structural models of the WOC of PSII for hydrogen production via water splitting and review nano-sized manganese oxides used in water oxidation by some research groups.

CoOx/UiO-66 and NiO/UiO-66 Heterostructures with UiO-66 Frameworks for Enhanced Oxygen Evolution Reactions

2021 ◽  
Author(s):  
Guangjin Zhang ◽  
Victor Charles ◽  
Yong Yang ◽  
Menglei Yuan ◽  
Jitao Zhang ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Water Oxidation ◽  
Oxidation Reaction ◽  
Widespread Application ◽  
Coupled Process

Water oxidation reaction involves a four electron-proton coupled process that is kinetically sluggish and has hindered the widespread application of water-splitting technology. Metal-MOF-coupled heterostructures serve as good OER electrocatalysts due...

Two photon tandem photoanode with black phosphorous quantum dot sensitized BiVO4 for solar water splitting

2022 ◽  
Author(s):  
Bingjun Jin ◽  
Yoonjun Cho ◽  
Cheolwoo Park ◽  
Jeehun Jeong ◽  
Sungsoon Kim ◽  
...  
Keyword(s):  
Quantum Dot ◽  
Water Splitting ◽  
Water Oxidation ◽  
Oxidation Kinetics ◽  
Light Harvesting ◽  
Charge Recombination ◽  
Solar Water ◽  
Two Photon ◽  
Solar Water Splitting ◽  
Pec Water Splitting

The photoelectrochemical (PEC) water splitting efficiency is profoundly restricted by the limited light harvesting, rapid charge recombination, and sluggish water oxidation kinetics, in which the construction of a photoelectrode requires...

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