Fe, Cu-Coordinated ZIF-Derived Carbon Framework for Efficient Oxygen Reduction Reaction and Zinc-Air Batteries

2018 ◽  
Vol 28 (39) ◽  
pp. 1802596 ◽  
Author(s):  
Zhihao Wang ◽  
Huihui Jin ◽  
Tian Meng ◽  
Ke Liao ◽  
Wenqian Meng ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Carbon Framework ◽  
Zinc Air Batteries

N and S Co-doped Ordered Mesoporous Carbon: An Efficient Electrocatalyst for Oxygen Reduction Reaction in Microbial Fuel Cells

2020 ◽  
Vol 16 (4) ◽  
pp. 625-638
Author(s):  
Leila Samiee ◽  
Sedigheh Sadegh Hassani
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Microbial Fuel Cells ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Carbon Substrate ◽  
Promising Candidate ◽  
X Ray ◽  
Carbon Framework ◽  
Co Doped

Background: Porous carbon materials are promising candidate supports for various applications. In a number of these applications, doping of the carbon framework with heteroatoms provides a facile route to readily tune the carbon properties. The oxygen reduction reaction (ORR), where the reaction can be catalyzed without precious metals is one of the common applications for the heteroatom-doped carbons. Therefore, heteroatom doped catalysts might have a promising potential as a cathode in Microbial fuel cells (MFCs). MFCs have a good potential to produce electricity from biological oxidization of wastes at the anode and chemical reduction at the cathode. To the best of our knowledge, no studies have been yet reported on utilizing Sulfur trioxide pyridine (STP) and CMK-3 for the preparation of (N and S) doped ordered porous carbon materials. The presence of highly ordered mesostructured and the synergistic effect of N and S atoms with specific structures enhance the oxygen adsorption due to improving the electrocatalytic activity. So the optimal catalyst, with significant stability and excellent tolerance of methanol crossover can be a promising candidate for even other storage and conversion devices. Methods: The physico-chemical properties of the prepared samples were determined by Small Angle X-ray Diffraction (SAXRD), N2 sorption-desorption, Transmission Electron Microscopy (TEM), Field Emission Scanning Electron Microscopy (FESEM) and X-ray Photoelectron Spectroscopy (XPS). The prepared samples were further applied for oxygen reduction reaction (ORR) and the optimal cathode was tested with the Microbial Fuel Cell (MFC) system. Furthermore, according to structural analysis, The HRTEM, and SAXRD results confirmed the formation of well-ordered hexagonal (p6mm) arrays of mesopores in the direction of (100). The EDS and XPS approved that N and S were successfully doped into the CMK-3 carbon framework. Results: Among all the studied CMK-3 based catalysts, the catalyst prepared by STP precursor and pyrolysis at 900°C exhibited the highest ORR activity with the onset potential of 1.02 V vs. RHE and 4 electron transfer number per oxygen molecule in 0.1 M KOH. The high catalyst durability and fuel-crossover tolerance led to stable performance of the optimal cathode after 5000 s operation, while the Pt/C cathode-based was considerably degraded. Finally, the MFC system with the optimal cathode displayed 43.9 mW·m-2 peak power density showing even reasonable performance in comparison to a Pt/C 20 wt.%.cathode. Conclusions: The results revealed that the synergistic effect of nitrogen and sulfur co-doped on the carbon substrate structure leads to improvement in catalytic activity. Also, it was clearly observed that the porous structure and order level of the carbon substrate could considerably change the ORR performance.

Zinc–Air Batteries Catalyzed Using Co3O4 Nanorod-Supported N-Doped Entangled Graphene for Oxygen Reduction Reaction

2021 ◽  
Author(s):  
Narugopal Manna ◽  
Santosh K. Singh ◽  
Geeta Pandurang Kharabe ◽  
Arun Torris ◽  
Sreekumar Kurungot
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Zinc Air Batteries

B-site W ions doped La0.5Sr0.5Co1-xWxO3-δ perovskite nanofibers with defects as bifunctional oxygen catalysts for rechargeable zinc-air batteries

2021 ◽  
Author(s):  
Xin Yu Gao ◽  
Xingwei Sun ◽  
Jia Hui Guo ◽  
Ya Nan Teng ◽  
Lei Liu ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Oxygen Electrode ◽  
Reduction Reaction ◽  
Air Battery ◽  
Zinc Air Batteries

The exploration of bifunctional oxygen electrode towards oxygen evolution reaction (OER) activity and oxygen reduction reaction (ORR) is the bottlenecks for the development of rechargeable zinc-air battery as a clean...

In situ derived Fe/N/S-codoped carbon nanotubes from ZIF-8 crystals as efficient electrocatalysts for the oxygen reduction reaction and zinc–air batteries

2018 ◽  
Vol 6 (41) ◽  
pp. 20093-20099 ◽  
Author(s):  
Huihui Jin ◽  
Huang Zhou ◽  
Wenqiang Li ◽  
Zhihao Wang ◽  
Jinlong Yang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Oxygen Reduction Reaction ◽  
Hydrazine Hydrate ◽  
Oxygen Reduction ◽  
High Performance ◽  
Reduction Reaction ◽  
Zinc Air Batteries

Hydrazine hydrate was employed to prevent Fe agglomeration and sulphate ions were used as the S source, which together led to Fe/N/S-CNTs with high performance.

In situ anchoring of metal nanoparticles in the N-doped carbon framework derived from conjugated microporous polymers towards an efficient oxygen reduction reaction

2018 ◽  
Vol 8 (14) ◽  
pp. 3572-3579 ◽  
Author(s):  
Qiang Li ◽  
Qi Shao ◽  
Qiong Wu ◽  
Qian Duan ◽  
Yanhui Li ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Metal Nanoparticles ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Microporous Polymers ◽  
Carbon Framework ◽  
Orr Activity ◽  
Conjugated Microporous Polymers

A series of efficient catalysts derived from metallophthalocyanine based conjugated microporous polymers show superior ORR activity in Zn–air batteries.

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