Breaking the Limits of Ionic Liquid-Based Supercapacitors: Mesoporous Carbon Electrodes Functionalized with Manganese Oxide Nanosplotches for Dense, Stable, and Wide-Temperature Energy Storage

2018 ◽  
Vol 28 (36) ◽  
pp. 1801298 ◽  
Author(s):  
Feili Lai ◽  
Jianrui Feng ◽  
Runyu Yan ◽  
Gui-Chang Wang ◽  
Markus Antonietti ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Energy Storage ◽  
Manganese Oxide ◽  
Mesoporous Carbon ◽  
Carbon Electrodes

Engineered Carbon Electrodes for High Performance Capacitive and Hybrid Energy Storage

2021 ◽  
Vol 35 ◽  
pp. 102340
Author(s):  
Vishnu Surendran ◽  
Raveendran S. Arya ◽  
Thazhe Veettil Vineesh ◽  
Binson Babu ◽  
Manikoth M. Shaijumon
Keyword(s):  
Energy Storage ◽  
High Performance ◽  
Carbon Electrodes ◽  
Hybrid Energy ◽  
Hybrid Energy Storage

scholarly journals Ionic Liquid Electrolytes for Electrochemical Energy Storage Devices

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 4000
Author(s):  
Eunhwan Kim ◽  
Juyeon Han ◽  
Seokgyu Ryu ◽  
Youngkyu Choi ◽  
Jeeyoung Yoo
Keyword(s):  
Ionic Liquid ◽  
Energy Storage ◽  
Lithium Ion ◽  
Electrochemical Energy Storage ◽  
Storage Device ◽  
Energy Storage Device ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Storage Ability ◽  
Electrochemical Energy

For decades, improvements in electrolytes and electrodes have driven the development of electrochemical energy storage devices. Generally, electrodes and electrolytes should not be developed separately due to the importance of the interaction at their interface. The energy storage ability and safety of energy storage devices are in fact determined by the arrangement of ions and electrons between the electrode and the electrolyte. In this paper, the physicochemical and electrochemical properties of lithium-ion batteries and supercapacitors using ionic liquids (ILs) as an electrolyte are reviewed. Additionally, the energy storage device ILs developed over the last decade are introduced.

scholarly journals A Novel Iron Chloride Red-Ox Concentration Flow Cell Battery (ICFB) Concept; Power and Electrode Optimization

Energies ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1109
Author(s):  
Robert Bock ◽  
Björn Kleinsteinberg ◽  
Bjørn Selnes-Volseth ◽  
Odne Stokke Burheim
Keyword(s):  
Energy Storage ◽  
Large Scale ◽  
Fossil Fuels ◽  
Flow Cell ◽  
Iron Chloride ◽  
Carbon Electrodes ◽  
Concentration Difference ◽  
Term Energy ◽  
Short And Long Term

For renewable energies to succeed in replacing fossil fuels, large-scale and affordable solutions are needed for short and long-term energy storage. A potentially inexpensive approach of storing large amounts of energy is through the use of a concentration flow cell that is based on cheap and abundant materials. Here, we propose to use aqueous iron chloride as a reacting solvent on carbon electrodes. We suggest to use it in a red-ox concentration flow cell with two compartments separated by a hydrocarbon-based membrane. In both compartments the red-ox couple of iron II and III reacts, oxidation at the anode and reduction at the cathode. When charging, a concentration difference between the two species grows. When discharging, this concentration difference between iron II and iron III is used to drive the reaction. In this respect it is a concentration driven flow cell redox battery using iron chloride in both solutions. Here, we investigate material combinations, power, and concentration relations.

scholarly journals Controlled Nanostructuration of Cobalt Oxyhydroxide Electrode Material for Hybrid Supercapacitors

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2325
Author(s):  
Ronan Invernizzi ◽  
Liliane Guerlou-Demourgues ◽  
François Weill ◽  
Alexia Lemoine ◽  
Marie-Anne Dourges ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Energy Storage ◽  
Specific Surface ◽  
Electrode Materials ◽  
Specific Capacity ◽  
Hybrid Supercapacitors ◽  
Cobalt Oxyhydroxide ◽  
Precipitation Medium ◽  
The Impact

Nanostructuration is one of the most promising strategies to develop performant electrode materials for energy storage devices, such as hybrid supercapacitors. In this work, we studied the influence of precipitation medium and the use of a series of 1-alkyl-3-methylimidazolium bromide ionic liquids for the nanostructuration of β(III) cobalt oxyhydroxides. Then, the effect of the nanostructuration and the impact of the different ionic liquids used during synthesis were investigated in terms of energy storage performances. First, we demonstrated that forward precipitation, in a cobalt-rich medium, leads to smaller particles with higher specific surface areas (SSA) and an enhanced mesoporosity. Introduction of ionic liquids (ILs) in the precipitation medium further strongly increased the specific surface area and the mesoporosity to achieve well-nanostructured materials with a very high SSA of 265 m2/g and porosity of 0.43 cm3/g. Additionally, we showed that ILs used as surfactant and template also functionalize the nanomaterial surface, leading to a beneficial synergy between the highly ionic conductive IL and the cobalt oxyhydroxide, which lowers the resistance charge transfer and improves the specific capacity. The nature of the ionic liquid had an important influence on the final electrochemical properties and the best performances were reached with the ionic liquid containing the longest alkyl chain.

Correction to Anomalous Pseudocapacitive Behavior of a Nanostructured, Mixed-Valent Manganese Oxide Film for Electrical Energy Storage

Nano Letters ◽  
2012 ◽  
Vol 12 (8) ◽  
pp. 4416-4416 ◽  
Author(s):  
Min-Kyu Song ◽  
Shuang Cheng ◽  
Haiyan Chen ◽  
Wentao Qin ◽  
Kyung-Wan Nam ◽  
...  
Keyword(s):  
Energy Storage ◽  
Oxide Film ◽  
Manganese Oxide ◽  
Electrical Energy ◽  
Electrical Energy Storage ◽  
Pseudocapacitive Behavior

High-energy green supercapacitor driven by ionic liquid electrolytes as an ultra-high stable next-generation energy storage device

2018 ◽  
Vol 383 ◽  
pp. 102-109 ◽  
Author(s):  
Ranjith Thangavel ◽  
Aravindaraj G. Kannan ◽  
Rubha Ponraj ◽  
Vigneysh Thangavel ◽  
Dong-Won Kim ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Energy Storage ◽  
High Energy ◽  
Storage Device ◽  
Energy Storage Device ◽  
Next Generation ◽  
Liquid Electrolytes
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