The Unique Structural Evolution of the O3-Phase Na2/3Fe2/3Mn1/3O2during High Rate Charge/Discharge: A Sodium-Centred Perspective

2015 ◽  
Vol 25 (31) ◽  
pp. 4994-5005 ◽  
Author(s):  
Neeraj Sharma ◽  
Elena Gonzalo ◽  
James C. Pramudita ◽  
Man Huon Han ◽  
Helen E. A. Brand ◽  
...  
1999 ◽  
Vol 15 (3) ◽  
pp. 225-229 ◽  
Author(s):  
T. Takamura ◽  
J. Suzuki ◽  
C. Yamada ◽  
K. Sumiya ◽  
K. Sekine

Author(s):  
VENKATA RAMI REDDY BODDU ◽  
Manikandan Palanisamy ◽  
Lichchhavi Sinha ◽  
Subhash Yadav ◽  
Vilas Pol ◽  
...  

Despite multiple phase transitions occur during Na+ ion intercalation and deintercalation, enhanced charge-discharge rate, and long cycle life are achieved to hexagonal shaped P2-type NaCoO2 cathode for sodium-ion batteries (SIBs)....


2014 ◽  
Vol 1606 ◽  
Author(s):  
Teruaki Nomiyama ◽  
Kenta Sakamoto ◽  
Tomohito Yoshida ◽  
Akinori Kagiyama ◽  
Yuji Horie

ABSTRACTOne of promising photorechargeable electrode, which has two functions of photovoltaic and electrical energy storage, is a composite film of mesoporous TiO2 and conducting polymer polyaniline. Galvanostatic charge/discharge characteristics of the TiO2-polyaniline composite were examined to reveal how fast the film was charged. The film with a specific capacity 60-120 mAh g–1 was found to be fully charged at high charging rate 20 mA cm–2 which is comparable to high performance solar cells. Such high charging rate was achieved by the compact polyaniline layer covering the large specific surface area of mesoporous TiO2 film.


2015 ◽  
Vol 1773 ◽  
pp. 7-14
Author(s):  
Guofeng Ren ◽  
Zhaoyang Fan

ABSTRACT2D nanomaterials, when assembled into an ordered macrostructure, will present many great opportunities, including for Li-ion batteries (LIBs). We report densely-packed vertically-aligned VO2(B) nanobelts (NBs)-based forest structure synthesized on edge-oriented graphene (EOG) network. Using a EOG/Ni foam as a 3D scaffold, aligned VO2(B) NBs can be further synthesized into a folded 3D forest structure to construct a freestanding electrode for LIBs. Electrochemical studies found that such a freestanding VO2(B)/EOG electrode, which combines the unique merits of 2D VO2(B) NBs and 2D graphene sheets, has excellent charge-discharge rate performance. A discharge capacity of 178 mAh g-1 at a rate of 59 C and 100 mAh g-1 at 300 C was measured. A good charge-discharge cycling stability under a high current density was also demonstrated. The results indicate VO2(B)/EOG forest based freestanding electrode is very promising for developing high-rate LIBs.


2016 ◽  
Vol 309 ◽  
pp. 122-126 ◽  
Author(s):  
Ikuma Takahashi ◽  
Takuya Mori ◽  
Takahiro Yoshinari ◽  
Yuki Orikasa ◽  
Yukinori Koyama ◽  
...  

2006 ◽  
Vol 301 ◽  
pp. 159-162
Author(s):  
Akira Kuwahara ◽  
Shinya Suzuki ◽  
Masaru Miyayama

The charge/discharge properties of V2O5/carbon composites with controlled microstructures were investigated to achieve a high-rate lithium electrode performance. Composite electrodes were synthesized by mixing a V2O5 sol, carbon and a surfactant, followed by drying. V2O5/AB (acetylene black) and V2O5/VGCF (vapor-grown carbon fiber) composite electrodes showed high-rate charge/discharge properties only when they had very high carbon contents. V2O5/ (AB and VGCF) composite electrodes with controlled microstructures exhibited a discharge capacity of 245 mA·h·g-1 at a high current density of 40 A·g-1, which was approximately 70% of that at a low current density of 100 mA·g-1. The improvement in the high-rate charge/discharge properties was attributed to the short lithium ion diffusion distance, large reaction area and high electronic conductivity of those composite electrodes.


2010 ◽  
Vol 158 ◽  
pp. 256-261 ◽  
Author(s):  
Dong Yun Zhang ◽  
Juan Yi ◽  
Qun Wei ◽  
Kun Liu ◽  
Zhen Zhen Fan ◽  
...  

Ternary lithium-ion battery is currently one of the hot cathode materials. In this paper, with acetate of nickel, manganese and cobalt as raw materials and lithium hydroxide as precipitation agent, LiCo1/3Mn1/3Ni1/3O2 was prepared by chemical coprecipitation method. LAND charge-discharge testing was used to study the electrochemical performance of materials at different rates (0.5C, 1C, 2C), and AC impedance spectroscopy was employed to study the rate performance and reasons of cyclical stability. The results showed that the stable SEM film formed under high rate was the main reason for the increased rate.


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